We have observed the cold collision frequency shift of the
1S-
2S transition in trapped spin-polarized atomic hydrogen. We find $\ensuremath{\Delta}{\ensuremath{\nu}}_{1S\ensuremath{-}2S}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}\ensuremath{-}3.8\ifmmode\pm\else\textpm\fi{}0.8\ifmmode\times\else\texttimes\fi{}{10}^{\ensuremath{-}10}n\mathrm{Hz}{\mathrm{cm}}^{3}$, where
n is the sample density. From this we derive the
1S-
2S s-wave triplet scattering length, ${a}_{1S\ensuremath{-}2S}\phantom{\rule{0ex}{0ex}}=\phantom{\rule{0ex}{0ex}}\ensuremath{-}1.4\ifmmode\pm\else\textpm\fi{}0.3\mathrm{nm}$, which is in fair agreement with a recent calculation. The shift provides a valuable probe of the distribution of densities in a trapped sample.
We show that a correct formulation of the cold collision frequency shift for two photon spectroscopy of Bose-condensed and cold non-Bose-condensed hydrogen is consistent with experimental data. Our treatment includes transport and inhomogeneity into the theory of a non-condensed gas, which causes substantial changes in the cold collision frequency shift for the ordinary thermal gas, as a result of the very high frequency (3.9 kHz) of the transverse trap mode. For the condensed gas, we find substantial corrections arise from the inclusion of quasiparticles, whose number is very large because of the very low frequency (10.2 Hz) of the longitudinal trap mode. These two effects together account for the apparent absence of a `factor of two' between the two possibilities. Our treatment considers only the Doppler-free measurements, but could be extended to Doppler-sensitive measurements. For Bose-condensed hydrogen, we predict a characteristic `foot' extending into higher detunings than can arise from the condensate alone, as a result of a correct treatment of the statistics of thermal quasiparticles.
Atomic hydrogen has been loaded into a 1-K deep magnetic trap through the use of a dilution refrigerator. Evaporative cooling has been used to cool the trapped hydrogen into the submillikelvin temperature regime. These techniques have produced a sample with density of 8 × 1013 cm-3 at a temperature of 100 μK. At this density a transition to a Bose-Einstein condensate is predicted to occur at a temperature of 30 μK. These results have been obtained with a magnetic trap that has been constructed to accommodate upcoming experiments based on laser spectroscopy of the 1S-2S two photon transition in the trapped hydrogen. A frequency doubled narrow linewidth cw dye laser system has been constructed to excite the 1S-2S transition. The excitation will be detected by the observation of electric field-induced Lyman-alpha fluorescence. The optical detection system should yield improved sample density and temperature diagnostic capabilities that will facilitate a closer approach to the quantum degenerate regime. Additionally the cold, confined hydrogen gas offers the possibility of improving the level of resolution of Doppler-free hydrogen 1S-2S laser spectroscopy by several orders of magnitude.