This chapter presents a self-contained introduction to some recent developments in nonequilibrium quantum statistical mechanics. In the elementary framework of finite dimensional quantum systems it introduces the concept of entropy production and discusses various generating functionals which encode the statistical properties of its fluctuations. It explores the physical interpretations of these functionals and their mathematical properties. In particular, it investigates their relations to linear response theory, full counting statistics, and quantum hypothesis testing. The chapter discusses very briefly more technical issues linked to the thermodynamic limit as well as to the large time limit. These two limits turn the elementary, finite time fluctuation theory into a powerful machinery, which yields important information on the asymptotic behaviour of infinitely extended quantum systems, e.g., open systems coupled to infinite reservoirs. An essential mathematical tool to deal with such a system is Tomita–Takesaki's modular theory of von Neumann algebras. The power of this theory is somewhat shadowed by its technical aspects. Finite dimensional quantum systems are special since all the structures and results of this machinery can be described by elementary tools.
This chapter presents a self-contained introduction to some recent developments in nonequilibrium quantum statistical mechanics. In the elementary framework of finite dimensional quantum systems it introduces the concept of entropy production and discusses various generating functionals which encode the statistical properties of its fluctuations. It explores the physical interpretations of these functionals and their mathematical properties. In particular, it investigates their relations to linear response theory, full counting statistics, and quantum hypothesis testing. The chapter discusses very briefly more technical issues linked to the thermodynamic limit as well as to the large time limit. These two limits turn the elementary, finite time fluctuation theory into a powerful machinery, which yields important information on the asymptotic behaviour of infinitely extended quantum systems, e.g., open systems coupled to infinite reservoirs. An essential mathematical tool to deal with such a system is Tomita–Takesaki's modular theory of von Neumann algebras. The power of this theory is somewhat shadowed by its technical aspects. Finite dimensional quantum systems are special since all the structures and results of this machinery can be described by elementary tools.
The celebrated Evans--Searles, respectively Gallavotti--Cohen, fluctuation theorem concerns certain universal statistical features of the entropy production rate of a classical system in a transient, respectively steady, state. In this paper, we review and compare several possible extensions of these fluctuation theorems to quantum systems. We present, in an introductory way, the approach proposed in a recent series of works [Lett. Math. Phys. 114, 32 (2024): doi:10.1007/s11005-024-01777-0], [Rev. Math. Phys 38, 2461006 (2026): doi:10.1142/S0129055X24610063], [Commun. Math. Phys. 406, 201 (2025): 10.1007/s00220-025-05360-z] and [J. Math. Phys. 67, 022101 (2026): doi:10.1063/5.0311182] including a previously missing extension of the Gallavotti--Cohen (steady state) version of the FT to two-time measurement entropy production in the algebraic setting of quantum dynamical systems. We focus on the open quantum systems, where a small system interacts with several (infinitely extended) reservoirs, and discuss the following approaches: naive, two-time measurement, phase space contraction and ancilla state tomography. We review the connection with modular theory. The latter provides a way to extend the classical notions to the quantum domain. We discuss the quantum version of the principle of regular entropic fluctuations, introduced in the classical context in [Nonlinearity 24, 699 (2011): doi:10.1088/0951-7715/24/3/003]. Finally, we relate the statistical properties of these various notions of entropy production to spectral resonances of quantum transfer operators and apply this approach to a paradigmatic model of non-equilibrium statistical mechanics: the spin-fermion model. The results presented here shed a new light on the nature of entropic fluctuations in quantum statistical mechanics.
After a historical introduction, the most important classical and quantum entropies are introduced as constructions in classical and quantum probability theory. Classical entropies are studied from large deviation theory, including theorems of Sanov, Cramér, Gärtner-Ellis, and Varadhan, and are illustrated in some applications to both Boltzmannian and Gibbsian statistical physics. Quantum entropies superficially connect to classical entropies at the formula level, but more deeply do so via the crucial role of entropy in statistical hypothesis testing. The classical (relative) Kullback-Leibler entropy, its quantum counterpart introduced by Umegaki, as well as their deformations proposed by Renyi all fit naturally in this context. Quantum entropy faces the new problem of defining and computing the relative entropy of a pair of states on a subsystem, here formalized as a von Neumann algebra. This requires modular (aka Tomita-Takesaki) theory, which provides the framework for the relative quantum entropies introduced by Araki and Uhlmann (these encompass both the Kullback-Leibler and Umegaki entropies as special cases). To (re)define and compute these entropies in terms of density operators and traces, further constructions are needed, namely Haagerup's noncommutative L^p spaces. Von Neumann algebras also provide the setting for the Connes-Stormer-Narnhofer-Thirring entropy, which is a quantum version of the Kolmogorov-Sinai entropy in dynamical systems and ergodic theory, to which we also provide an introduction. This course was originally inspired by, and should be relevant to, black hole thermodynamics, although we discuss neither this application nor the second law. The course tries to be both mathematically rigorous and interesting to theoretical physicists. Prerequisites are undergraduate probability theory, functional analysis, and quantum theory.
We presents a unified and concise exposition of key topics in the mathematical theory of open quantum systems, developed within the framework of operator algebras. The manuscript consolidates and extends a series of invited articles originally prepared for the Modern Encyclopedia of Mathematical Physics, combining foundational material with modern perspectives on non-equilibrium quantum statistical mechanics. After introducing the C*- and W*-algebraic formulation of quantum mechanics, the paper reviews quantum dynamical systems, KMS states, and Tomita-Takesaki modular theory, as well as CCR and CAR algebras for bosonic and fermionic systems. Particular emphasis is placed on infinite systems, non-equilibrium steady states, entropy production, and linear response theory. The later sections develop a systematic treatment of small systems coupled to reservoirs, open lattice quantum spin systems, culminating in a detailed discussion of competing notions of quantum entropy production. The presentation highlights structural insights, conceptual clarity, and connections between equilibrium and non-equilibrium phenomena, providing a self-contained reference for researchers and graduate students in mathematical physics.
We presents a unified and concise exposition of key topics in the mathematical theory of open quantum systems, developed within the framework of operator algebras. The manuscript consolidates and extends a series of invited articles originally prepared for the Modern Encyclopedia of Mathematical Physics, combining foundational material with modern perspectives on non-equilibrium quantum statistical mechanics. After introducing the C*- and W*-algebraic formulation of quantum mechanics, the paper reviews quantum dynamical systems, KMS states, and Tomita-Takesaki modular theory, as well as CCR and CAR algebras for bosonic and fermionic systems. Particular emphasis is placed on infinite systems, non-equilibrium steady states, entropy production, and linear response theory. The later sections develop a systematic treatment of small systems coupled to reservoirs, open lattice quantum spin systems, culminating in a detailed discussion of competing notions of quantum entropy production. The presentation highlights structural insights, conceptual clarity, and connections between equilibrium and non-equilibrium phenomena, providing a self-contained reference for researchers and graduate students in mathematical physics.
A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs’ relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in quantum mechanics. The general relation between system-reservoir interactions and an entropy change operator in an open quantum system, relying just on the framework of statistical mechanics and the definition of von Neumann entropy. By using this formula, we can obtain the correct entropy production in the linear response framework. The present derivation of entropy production is directly based on the first principle of microscopic time-evolution, while the previous standard argument is due to the thermodynamic energy balance.