The experimental achievement of Bose-Einstein condensation in cold alkali atomic gases in 1995 has started a period of fertile research at the intersection of atomic physics, quantum optics, and condensed matter. In this thesis, various tunneling effects in both bosonic and fermionic gases are investigated. The first part of this work deals with bosons in different Josephson-type experimental setups. After a brief general introduction we establish, in Chapter 2, a mapping between the phase and the Bogoliubov representation for the Josephson oscillations; in Chapter 3 we calculate the Josephson coupling constant for the condensate in the external Josephson effect. Chapter 4 deals with Josephson effects at the level of depletion: we describe in detail the oscillatory dynamics of the virtual quasiparticles. The next Chapter is a stability analysis for the formation of vortices in the Kibble-Zurek scenario. Finally, Chapter 6 contains a discussion on the time-evolution of the many-body states in the absence of tunneling. The second part of the thesis (Chapter 7- Chapter 9) deals with fermionic systems below the BCS critical temperature. The first two of these Chapters explore the possibility of driving transitions between hyperfine states with lasers. In Chapter 7 we show that these transitions could be used to investigate the coherence of the Cooper pairs. In Chapter 8 we imagine an internal Josephson experiment which uses a pair of lasers to drive transitions between two superfluids. Finally, in Chapter 9 we examine the properties of vortices formed in trapped Cooper-paired fermionic gases.
The experimental achievement of Bose-Einstein condensation in cold alkali atomic gases in 1995 has started a period of fertile research at the intersection of atomic physics, quantum optics, and condensed matter. In this thesis, various tunneling effects in both bosonic and fermionic gases are investigated. The first part of this work deals with bosons in different Josephson-type experimental setups. After a brief general introduction we establish, in Chapter 2, a mapping between the phase and the Bogoliubov representation for the Josephson oscillations; in Chapter 3 we calculate the Josephson coupling constant for the condensate in the external Josephson effect. Chapter 4 deals with Josephson effects at the level of depletion: we describe in detail the oscillatory dynamics of the virtual quasiparticles. The next Chapter is a stability analysis for the formation of vortices in the Kibble-Zurek scenario. Finally, Chapter 6 contains a discussion on the time-evolution of the many-body states in the absence of tunneling. The second part of the thesis (Chapter 7- Chapter 9) deals with fermionic systems below the BCS critical temperature. The first two of these Chapters explore the possibility of driving transitions between hyperfine states with lasers. In Chapter 7 we show that these transitions could be used to investigate the coherence of the Cooper pairs. In Chapter 8 we imagine an internal Josephson experiment which uses a pair of lasers to drive transitions between two superfluids. Finally, in Chapter 9 we examine the properties of vortices formed in trapped Cooper-paired fermionic gases.
This doctoral dissertation is concerned with the physics of strongly interacting cold alkali atoms at low temperatures near a Feshbach resonance. In Chapter 1, we establish a connection between superfluid 4He and the BCS theory of superconductivity, and cold alkali atoms. We give the history of cold atoms, describing the significant achievements, pitfalls and challenges. In Chapter 2, we explore the thermodynamics of strongly interacting Bosonic atoms. We explore the stability of atomic Bosonic condensates near a Feshbach resonance. We show that the experimentally attained atomic condensate is a saddle point of the free energy, but the kinetics of its decay is slow. We also show that there is a second, higher density condensate branch which has an Ising-like phase transition to a molecular (paired) condensate when ramped across the Feshbach resonance. We argue that due to the high density, inelastic 3-body processes possibly render this transition unobservable. In Chapter 3, we explore the thermodynamics of Fermionic atoms near a Feshbach resonance. We determine the zero-temperature (T less than/less than T sub(F) ) pair propagator for a spinimbalanced mixture of up and down spin Fermions, and use it to show that such a mixture becomes completely polarized at mu sub(down arrow)= -0.9 mu sub(up arrow) . We also determine the Thouless criterion for superfluidity in a spin-imbalanced Fermi mixture, and construct a phase diagram of such a system at zero temperature. We then compare our results with experiments performed by two different groups. We find that interaction modifications to the minority spin self-energy inferred from our analysis is roughly double those observed in experiments. This discrepancy is consistent with the expected accuracy of the theory. In Chapter 4, we extend our analysis of the preceding chapter to calculate the surface tension of an interface between spin-polarized Fermions in the normal and superfluid phases. We show that, as expected, this surface tension decreases with increasing temperature and vanishes at a tricritical temperature, above which the transition becomes continuous. We also calculate the thickness of the interface; at T = 0, this is a few interparticle spacings, but diverges at the tricritical temperature. To compare with a set of relevant experiments, we also develop a phenomenological model for surface tension, and conclude that experimental surface tensions are an order of magnitude higher than what our microscopic calculation yields. We hypothesize possible mechanisms. In Chapter 5, we calculate the finite temperature phase diagram of a Bose-Fermi mixture produced from a spin-imbalanced two-component Fermi gas deep in the BEC phase. We show that there is a discontinuous transition between the superfluid and normal phase, with an entropy of mixing sufficient to cool the system down. We detail the construction of such a cooling scheme to cool a Fermi system below what is possible evaporatively, and find that the cooling efficiency is comparable to typical evaporative schemes. In Chapter 6, we shift our focus from thermodynamics to dynamics. We calculate shifts in the energy spectrum of a spin-balanced Fermionic superfluid of Cooper pairs due to the presence of energetically close states coupled by a Feshbach resonance. These shifts manifest themselves as clock-shifts in the radio-frequency spectrum of the superfluid. In addition to a broad asymmetric peak coming from the break-up of Cooper pairs, we find (for certain parameter ranges) a sharp, symmetric "bound-bound" spectral line coming from the conversion of Cooper pairs in one channel to pairs or molecules in another channel. Our theory shows remarkable quantitative agreement with experiments performed by an experimental group.
Dilute atomic gases have become a powerful tool for studying many-body quantum mechanics. The best example of this is the achievement of Bose-Einstein condensation in 1995 in a gas of Bose atoms, a discovery which has invoked a confluence of ideas from condensed matter, atomic and nuclear physics. Now a concerted research effort is focused on creating and studying a BCS superfluid in an atomic Fermi gas. In the work presented here we study in detail pairing superfluidity in a Fermi gas of atoms, by self-consistently solving the Bogoliubov-de Gennes equations, both for bulk systems, and for atoms in a harmonic confining potential. A critical part of this work is the derivation of a regularized theory, which is formulated entirely in terms of physically measurable quantities, such that a quantitative comparison between theory and experiment is possible with no adjustable parameters. The resulting equations form a non-linear problem, and the accurate numerical solution of this poses a formidable challenge. A major component of this thesis is the development of efficient computational approaches to overcome these difficulties. Based on the linear response of the gas to a twisting of the order parameter phase, the superfluid density can be defined as a generalized elasticity of the system. Using finite temperature perturbation theory we calculate the superfluid density in an inhomogeneous system. We investigate the structure and thermodynamic properties of a singly quantized vortex line in a gas of superfluid fermionic atoms, making the first quantitative determination the critical rotation frequency for thermodynamic stability of the vortex state, and study the nature of the bound states in the vortex core. These excitations fill the core, making direct imaging of the vortex unlikely. Instead, we propose an experiment to indirectly probe the vortex density of states with laser fields, in a scheme analogous to Scanning Tunneling Microscopy. Furthermore, it is shown that the vortex state causes a shift of the superfluid transition temperature, which can be understood as a finite size effect.
Physics of ultra cold atoms and molecules is one of the most rapidly developing areas of the modern atomic, molecular, optical physics and quantum optics.This area covers several sub-areas of diverse importance, but definitely two trends can be easily identifies: i) fundamental research on properties of ultra cold atoms and molecules, and in particular atomic and molecular condensates trapped and lattice gases; here the fundamental questions of nature and form of phase transitions in degenerate systems are being posed and studied; ii) more applications oriented research on ultracold atoms and molecules, involving in particular applications in precision measurements, atomic clocks, frequency standards, atom and molecule interferometry, quantum information, quantum engineering, "super" chemistry etc.This thesis concerns both of these major trends.The applications, or more specifically quantum engineering aspect are discussed in the first four chapters of the thesis, which deal with optical manipulations of ultra cold gases, in particular optical generation of vortices in Bose condensates, quasi-solitons in Fermi gases, and retarded dipole-dipole interactions in Bose, or Fermi gases.This thesis consists of four main chapters.Chapter 2, "Optical generation of vortices in Bose Einstein Condensates".In this chapter we study theoretically the generation of vortices by phase imprinting in trapped Bose-Einstein condensates.Phase imprinting is achieved by passing a short off-resonance laser pulse through an appropriately designed absorption plate, and impinging it on a condensate.We answer the fundamental question of how the circulation and the vortex are introduced into the system, and discuss the creation of vortex arrays.We discuss vortex dynamics and interactions in such configurations.Various methods of vortex detection based on interference combined with Bragg scattering are also analyzed.In Chapter 3, "Fermionic 'Solitons'" we investigate in detail the concept of low energy excitations of ultra cold Fermi gases.This excitations are generated using the same idea of phase imprinting as that employed in the generation of vortices in BEC.We address in this chapter some questions concerning the generation (via phase imprinting) of soliton-like solutions in a single-component Fermi gas of neutral atoms at zero and finite temperatures.By using both numerical and analytical calculations, we find the conditions under which it is possible to find in non-interacting Fermi gases, quasisolitons which resemble the properties of solitons in non-linear integrable equations.We present the results for both spatially homogeneous and trapped cases, and emphasize the importance of Fermi statistics and the absence of interactions for the existence of such solutions.In Chapter 4, "Generating Dipole Condensate" we keep studying the possibilities of optical manipulations of ultracold gases.In particular, we study two different ways to laser-induce dipole-dipole interactions in trapped Bose-Einstein condensates.The first one employs the fact that those atoms in high Rydberg states posses a large dipolar moment.We first analyze the idea of imposing the dipole moment as a time average over short stroboscopic pulses.These pulses are coherently transporting the atoms from the ground atomic state to some high Rydberg state and back.The second idea is based on the observation that in strong static or oscillatory electric fields, atoms polarize and acquire dipole moment.We analyze the possibilities and limitations of inducing such a high electric field using lasers of low frequency.In Chapter 5, "Dipolar BCS", we continue our study of trapped fermionic gases, with the analysis of the BCS transition in trapped dipolar fermionic gases.We find that the critical strength of the dipole-dipole interaction to achieve BCS pairing, depends on the trap geometry.We find the particular form of this dependence, and present the solutions for the order parameter.This first chapter is meant as a general introduction to the thesis.This introduction is by no means exhaustive, and should be rather treated as a collection of basic facts concerning ultra cold gases, without rigorous derivations.The last subsection of the introductory chapter, discusses very briefly the most important achievements and trends in the field and the current state of the art.
We study ultracold gases of alkali-metal atoms in the quantum degenerate regime. The interatomic interactions in these type of systems can be tuned using resonances induced by magnetic or electric fields. The tunability of the interactions, together with the possibility of confining the atoms with several kinds of external potentials, allows for a completely novel approach to study basic problems in many-body physics, and moreover, allows to enter regimes which have never been accessible in condensed matter or nuclear physics. For example, this has led to the experimental demonstration of an intimate relation between two types of superfluidity: the crossover from Bose-Einstein condensation of tightly bound molecules to the superfluid behavior related to weakly bound BCS-like pairs. Another experimental landmark was reached when the existence of universal Efimov three-body bound states was proven in experiments with ultracold bosonic cesium atoms. In this thesis, we study several aspects of these strongly interacting and ultracold atomic gases. We develop an analytical model that encapsulates all of the relevant scattering physics in atomic systems where open-channel shape resonances and closedchannel Feshbach resonances give rise to complicated and non-trivial scattering properties. This model provides lots of physical insight and is shown to describe important quantities, such as the molecular energies and scattering phase shifts, with a high level of accuracy. The model is compared to full numerical coupled-channel calculations in two atomic systems: rubidium and lithium. We study the BCS-BEC crossover using a many-body description of the ultracold gas that includes the non-trivial energy dependence of the scattering model. We show that it gives rise to superfluid behavior associated with the formation of BCS-like pairs while the low-energy interactions are repulsive in character. The energy dependence of the interactions is crucial, as it gives rise to attractive interactions at the Fermi energy, necessary for the formation of Cooper pairs. We demonstrate new ways of controlling the interatomic interactions using a combination of magnetic and electric fields. This leads to experimental control of, for instance, the three-body parameter in the context of Efimov physics and of non-universal behavior in the BCS-BEC crossover in fermionic gases. Using a four-body method based on first principles, we solve the molecule-molecule scattering problem to calculate several important properties of bosonic and fermionic Summary 145 molecules that consist of light and heavy atoms. These type of molecules are of current experimental interest, and we predict several exciting relations between three- and four-body observables in these type of systems.
This thesis is comprised of four separate parts: in the first we calculate the second and third virial coefficients of 3He and 4He at low temperatures with an empirical interatomic potential by Janzen and Aziz and using the Path Integral Monte Carlo (PIMC) technique. We show that, for the calculation of the second coefficient, the method is successful whereas for the third the particular implementation that we chose (free particle sampling) is not sufficient to produce reliable results at low temperatures. In the second part we consider the Josephson Effect between two spatially separated Bose-Einstein condensates of atoms each of which can be in two hyperfine states. We derive simple equations of motion for this system closely analogous to the Bloch equations. We also map the dynamics of the system onto those of a classical particle in a well. We find novel density and spin modes of oscillation and new stable equilibrium points of the motion. Finally we analyze the oscillation modes in the spin-1 (F = 1) case. In the third part of the thesis we propose a powerful method to study the time evolution of Bose condensed gases perturbed from an initial thermal equilibrium, based on the Wigner representation of the N-body density operator. We show how to generate an ensemble of random classical fields sampling the initial Wigner distribution in the number conserving Bogoliubov approximation. The fields are then evolved with the time dependent Gross-Pitaevskii equation. We illustrate the method with the damping of a collective excitation of a one dimensional Bose gas. The fourth part deals with inhomogeneous superconductivity in the presence of magnetic fields that couple only to the spin and not to the orbital motion. They induce a splitting of the Fermi surfaces of up and down spins. We start by considering a one dimensional system and explicitly write down the wavefunction that pairs states with unequal energies due to the splitting. Next we consider an extension to three dimensions and work out explicitly certain aspects of the crossover from one to two dimensions. We then discuss the relationship of this state with those of Fulde, Ferrell, Larkin and Ovchinnikov. Finally, we consider an extension to the case of a paired state which has a gap with a spherically symmetric spatial dependence.
The experimental achievement of Bose-Einstein condensation (BEC) in 1995 has aroused a large interest among the community of the physics of ultracold atomic gases.Recently new topics have attracted the attention of this very active field of research , in particular we could mention low dimensional systems, atoms in lattices, and classical and Fermi gases.As for the case of BEC, the study of the dynamical aspects of these systems provides a very valuable information.In particular time-of-flight experiments and measurements of collective excitations have been successfully realized providing a clear signature of the BEC and the regime of interaction.Following this line, in this thesis, we want to study some dynamical aspects of these new systems nowadays avaliable due to the remarkable development of the experimental techniques.In the first chapter we present the state of the art of the field, providing the historical path and the motivation for the work developed in the next chapters.In the second chapter, we discuss some general concepts in order to introduce the formalism and notation employed throughout the thesis, as well as those topics analyzed in more detail in the further chapters.In chapter three, we explain some general techniques which are useful to deal with one dimensional systems, and analyze in detail the expansion of a one dimensional Bose gas in a guide, which differs significantly from the expansion of a BEC.In particular we are able to predict the range of parameters for which the self-similarity of the expansion is violated.Chapter four is devoted to the physics of atoms in a periodic potential.We start, as in the previous chapter, introducing some general concepts and techniques employed further.First we discuss the physics of the superfluid case in a trap, showing that under certain conditions a three dimensional gas exhibits one dimensional properties.viii In particular, static properties and the lowest collective excitations differ significantly from those of a BEC.We extend the analysis to the insulating phase showing that correlation properties depend on the on-site one-dimensional regime.These correlations can be measured in current time of flight experiments.In the fifth chapter we analyze the dynamics of classical and Fermi gases.We show in detail how expansion and collective excitations depend on the interaction regime and the trap anisotropy.In particular, the expansion can be used to distinguish between a normal Fermi gas and a superfluid one.We summarize in the last chapter the new results presented in this thesis.