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AIP conference proceedings

Continuous Production of Cold KRb

Luís Gustavo Marcassa

Published Jan 1, 2005• 0 citations
Publisher

Abstract

In this paper we report the observation of translationally ultracold heteronuclear groundstate molecules in a two species magneto‐optical trap (MOT) containing 39K and 85Rb atoms. The KRb molecules are produced via photoassociation and detected by multiphoton ionization. Their temperature and formation rate constant were characterized. The two species MOTs may be used in the future as a reliable source of ultracold molecules to be captured by electrostatic, magnetic or optical traps. This possibility will certainly motivate further investigation of quantum collective effects as well as high‐resolution spectroscopy of the rovibrational level structure of cold heteronuclear molecular systems.

DOI
10.1063/1.1928851

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•Jan 1, 2014•2 citations
In this paper we report the observation of translationally ultracold heteronuclear groundstate molecules in a two species magneto‐optical trap (MOT) containing 39K and 85Rb atoms. The KRb molecules are produced via photoassociation and detected by multiphoton ionization. Their temperature and formation rate constant were characterized. The two species MOTs may be used in the future as a reliable source of ultracold molecules to be captured by electrostatic, magnetic or optical traps. This possibility will certainly motivate further investigation of quantum collective effects as well as high‐resolution spectroscopy of the rovibrational level structure of cold heteronuclear molecular systems.
We report the observation of translationally ultracold heteronuclear ground-state molecules in a two-species magneto-optical trap containing 39K and 85Rb atoms. The KRb molecules are produced via photoassociation and detected by multiphoton ionization. We had characterized their temperature and measured their formation rate constant. We believe that the two-species trap could be used as a reliable source of ultracold molecules to be captured by electrostatic, magnetic, or optical traps. This possibility will certainly motivate further investigation of quantum collective effects as well as high-resolution spectroscopy of the rovibrational level structure of cold heteronuclear molecular systems.
We have produced ultracold heteronuclear KRb molecules by the process of photoassociation in a two-species magneto-optical trap. Following decay of the photoassociated KRb*, the molecules are detected using two-photon ionization and time-of-flight mass spectroscopy of KRb+{\mathrm{K}\mathrm{R}\mathrm{b}}^{+}KRb+. A portion of the metastable triplet molecules thus formed are magnetically trapped. Photoassociative spectra down to $91\text{ }\text{ }{\mathrm{c}\mathrm{m}}^{\ensuremath{-}1}$ below the K(4s)+Rb(5p1/2)\mathrm{K}(4s)+\mathrm{R}\mathrm{b}(5{p}_{1/2})K(4s)+Rb(5p1/2​) asymptote have been obtained. We have made assignments to all eight of the attractive Hund's case (c) KRb* potential curves in this spectral region.
This thesis describes the spectroscopy work on ultracold 39K 85Rb molecules as part of our effort towards producing ground-state ultracold polar molecules. ^ The starting points of our experiment are laser cooled and trapped K and Rb atoms in dual-species MOTs and the molecule formation method is photoassociation (PA). A fraction of the PA-produced excited-state molecules can spontaneously emit to the two lowest electronic states, the X 1Σ + state and the a 3Σ + state, to form high vibrational level molecules. In order to develop a population transfer scheme to make deeply bound molecules, we have studied the spectroscopy of KRb in several steps. Besides the PA step, we have also carried out a state-selective detection experiment to study the population distribution of the high vibrational level molecules formed via spontaneous emission. The detection method is pulsed-laser based ion time-of-flight mass spectroscopy. Due to the linewidth limitations of the pulsed laser, this detection method can only resolve vibrational structures. A cw laser induced ion depletion spectroscopy technique has been developed in order to obtain rotational resolution. Using this ion depletion method, we have studied a possible stimulated Raman transfer scheme via the 3 1Σ+ state. To this end, we have obtained all the spectroscopic information required to produce deeply bound KRb molecules in a single vibrational and rotational level. ^ Several other spectroscopic studies using the high vibrational level ultracold molecules are also discussed. ^
We describe the experimental observation of ultracold NaCs+{\mathrm{NaCs}}^{+}NaCs+ molecular formation in a novel two-species magneto-optical trap. We interpret our observations in terms of a photoassociative ionization pathway similar to that observed in a sodium trap: $\mathrm{Na}+\mathrm{Cs}+\ensuremath{\Elzxh}{\ensuremath{\omega}}_{\mathrm{Na}}+\ensuremath{\Elzxh}{\ensuremath{\omega}}_{\mathrm{Cs}}\ensuremath{\rightarrow}{\mathrm{NaCs}}^{+}{+e}^{\ensuremath{-}}$. We have directly measured the NaCs+{\mathrm{NaCs}}^{+}NaCs+ production rate as a function of the excitation laser frequency and intensity elucidating the role of ground-state hyperfine levels. We have observed resonance structures in the frequency-dependent ion rate which we associate with the molecular character of the process.
We have produced ultracold heteronuclear ${\text{YbRb}}^{\ensuremath{\ast}}$ molecules in a combined magneto-optical trap by photoassociation. The formation of electronically excited molecules close to the dissociation limit was observed by the trap loss spectroscopy in mixtures of 87Rb^{87}\text{R}\text{b}87Rb with 174Yb^{174}\text{Y}\text{b}174Yb and 176Yb^{176}\text{Y}\text{b}176Yb. The molecules could be prepared in well-defined rovibrational levels, allowing for an experimental determination of the long-range potential in the electronically excited state.
We present spectroscopic studies of ultracold LiRb molecules using ionization detection. The molecules are created by cooling and trapping Li and Rb atoms in overlapping magneto-optical traps (MOTs) and using light resonant with a free-bound transition to create weakly bound excited state molecules in a process known as photoassociation (PA). We explore weakly bound vibrational levels of LiRb with PA spectroscopy using ionization detection and, where possible, compare our results with earlier measurements performed in our lab using trap-loss spectroscopy. In addition, we also probe vibrational levels of the ground triplet electronic state and excited electronic states using resonantly enhanced multiphoton ionization (REMPI) spectroscopy. We identify several vibrational levels of the α3Σ+, (3)3ΠΩ and (4)3Σ + states and compare our observations with theoretical calculations. As LiRb is one of the least studied heteronuclear diatomic molecules, these studies are aimed towards exploring the molecular structure. The spectroscopic work is also in line with the long-term project goals of transferring ultracold LiRb molecules into the lowest rotational and vibrational levels of the ground singlet electronic state. Molecules in this rovibronic ground state possess a large electric dipole moment, which is essential for application of ultracold molecules in various quantum computation schemes. The rovibronic ground state will also be an ideal starting point for investigating molecular entangled states.