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Lecture notes in chemistry

One-Particle Problems

Pekka Pyykkö

Published Jan 1, 1986• 0 citations
Publisher
DOI
10.1007/978-3-642-93345-5_2

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Many-particle Problems

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The statement is often made that the second quantized Hamiltonian for a system of noninteracting particles in an external weak electromagnetic field gives rise essentially to a one-particle problem, to which there corresponds a dressed vacuum different from the bare one. In this paper we implement that statement by explicitly constructing the dressed vacuum, together with the quasiparticle creation and annihilation operators associated with the one-particle problem. The process of diagonalizing the Hamiltonian is illustrated step by step in a simple model.
In this paper it is shown that several cases of one-dimensional N-body problems are exactly soluble. The first case describes the motion of three one-dimensional particles of arbitrary mass which interact with one another via infinite-strength, repulsive delta-function potentials. It is found in this case that the stationary-state solution of the scattering of the three particles is analogous to an electro-magnetic diffraction problem which has already been solved. The solution to this analogous electro-magnetic problem is interpreted in terms of particles. Next it is shown that the problem of three particles of equal mass interacting with each other via finite- but equal-strength delta-function potentials is exactly soluble. This example exhibits rearrangement and bound-state effects, but no inelastic processes occur. Finally it is shown that the problem of N particles of equal mass all interacting with one another via finite- but equal-strength delta functions is exactly soluble. Again no inelastic processes occur, but various types of rearrangements and an N-particle bound state do occur. These rearrangements and the N-particle bound state are illustrated by means of a series of sample calculations.
Similarly to the derivation of the Gibbs-Boltzmann distribution for structureless indistinguishable particles, we consider multi-particle systems some of which are contained (or delimited) inside others (Problem 1), as well as systems of particles delimited within other particles, which, in turn, are delimited yet inside another kind of particles (Problem 2). Under the natural assumptions concerning the conservation laws, such as the conservation of the total number of particles, total energy, etc, the problem of the most probable energy distributions is studied in a combinatorial formulation, with the obtained distributions treated as externally observable. For Problem 1, the particle distributions over maximal and minimal energies are also established and shown to coincide with the ones found in the framework of the original combinatorial treatment. The results for Problems 1 and 2 can be interpreted as a sorting of lower-level particles based on their statistical mechanics behavior observed in various experiments. An effective Pauli principle arises in a non-contradictory manner in one-particle observations for the complete probabilistic Problem 1 in the combinatorial formulation as well as in the problem of distributions over maximal and minimal energies. Several of the calculated distributions describe particles having no negative energy states.