Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

Molecular Physics

Wigner's phase space function and atomic structure

Jens Peder Dahl, Michael Springborg

Published Dec 10, 1982• 83 citations
Publisher

Abstract

We have constructed the Wigner function for the ground state of the hydrogen atom and analysed its variation over phase space. By means of the Weyl correspondence between operators and phase space functions we have then studied the description of angular momentum and resolved a dilemma in the comparison with early quantum mechanics. Finally we have discussed the introduction of local energy densities in coordinate space and demonstrated the validity of a local virial theorem.

DOI
10.1080/00268978200100752

Related papers

Wigner distribution for angle coordinates in quantum mechanics

Narasimhaiengar Mukunda

The method of Wigner distribution functions, and the Weyl correspondence between quantum and classical variables, are extended from the usual kind of canonically conjugate position and momentum operators to the case of an angle and angular momentum operator pair. The sense in which one has a description of quantum mechanics using classical phase-space language is much clarified by this extension.

American Journal of Physics•Feb 1, 1979•74 citations

Weyl–Wigner correspondence in two space dimensions

Joachim Dahl, Sándor Varró, A. Wolf +1 more

We consider Wigner functions in two space dimensions. In particular, we focus on Wigner functions corresponding to energy eigenstates of a non-relativistic particle moving in two dimensions in the absence of a potential. With the help of the Weyl–Wigner correspondence we first transform the eigenvalue equations for energy and angular momentum into phase space. As a result we arrive at partial differential equations in phase space which determine the corresponding Wigner function. We then solve the resulting equations using appropriate coordinates.

Journal of Modern Optics•Sep 10, 2007•1 citation

Wigner functions for angle and orbital angular momentum: Operators and dynamics

H.A. Kastrup

Recently a paper on the construction of consistent Wigner functions for cylindrical phase spaces ${\mathbb{S}}^{1}\ifmmode\times\else\texttimes\fi{}\mathbb{R}$, i.e., for the canonical pair angle and orbital angular momentum, was published [H. A. Kastrup, Phys. Rev. A 94, 062113 (2016)] in which the main properties of these functions are derived and discussed and their usefulness is illustrated with examples. The present paper is a continuation which compares the properties of the Wigner functions for cylindrical phase spaces with those of the well-known Wigner functions for planar phase spaces in more detail. Furthermore, the mutual (Weyl) correspondence between Hilbert space operators and their phase-space functions is discussed. The $\ensuremath{\star}$ product formalism is shown to be completely implementable. In addition, basic dynamical laws for Wigner and Moyal functions are derived as generalized Liouville and energy equations. They are very similar to those in the planar case but also show characteristic differences.

arXiv:1702.05615•Physical Review A•May 12, 2017•7 citations

Wigner functions for the pair angle and orbital angular momentum

H.A. Kastrup

The problem of constructing physically and mathematically well-defined Wigner functions for the canonical pair angle $\ensuremath{\theta}$ and angular momentum $p$ is solved. While a key element for the construction of Wigner functions for the planar phase space ${(q,p)\ensuremath{\in}{\mathbb{R}}^{2}}$ is the Heisenberg-Weyl group, the corresponding group for the cylindrical phase space ${(\ensuremath{\theta},p)\ensuremath{\in}{S}^{1}\ifmmode\times\else\texttimes\fi{}\mathbb{R}}$ is the Euclidean group $E(2)$ of the plane and its unitary representations. Here the angle $\ensuremath{\theta}$ is replaced by the pair $(cos\ensuremath{\theta},sin\ensuremath{\theta})$, which corresponds uniquely to the points on the unit circle. The main structural properties of the Wigner functions for the planar and the cylindrical phase spaces are strikingly similar. A crucial role is played by the $sinc$ function, which provides the interpolation for the discontinuous quantized angular momenta in terms of the continuous classical ones, in accordance with the famous Whittaker cardinal function well known from interpolation and sampling theories. The quantum mechanical marginal distributions for the angle (continuous) and angular momentum (discontinuous) are, as usual, uniquely obtained by appropriate integrations of the $(\ensuremath{\theta},p)$ Wigner function. Among the examples discussed is an elementary system of simple cat states.

arXiv:1601.02520•Physical Review A•Dec 15, 2016•29 citations

Hydrogen atom in phase space: the Wigner representation

Ludmiła Praxmeyer, Jan Mostowski, Krzysztof Wódkiewicz

The hydrogen atom is a fundamental exactly soluble system for which the Wigner function, being a quantum analogue of the joint probability distribution of position and momentum, is unknown. In this paper, we present an effective method of calculating the Wigner function, for all bound states of the nonrelativistic hydrogen atom. The formal similarity between the eigenfunctions of the nonrelativistic hydrogen atom in the momentum representation and the Klein–Gordon propagator has allowed the calculation of the Wigner function for an arbitrary bound state of the hydrogen atom, using a simple atomic integral as a generator. These Wigner functions for some low-lying states are depicted and discussed.

arXiv:quant-ph/0504038•Journal of Physics A Mathematical and General•Oct 24, 2006•26 citations

Weyl Transformation and the Classical Limit of Quantum Mechanics

Boris Leaf

The Weyl correspondence for obtaining quantum operators from functions of classical coordinates and momenta is known to be incorrect. To calculate quantum-mechanical expectation values as phase-space averages with the Wigner density function, one cannot use classical functions but must use Weyl transforms. These transforms are defined and their properties derived from quantum mechanics. Their properties are expressed in terms of a Hermitian operator Δ(Q, K) whose Weyl transform is a δ function. The Wigner function is the transform of the density operator. Every Weyl transform is exhibited as a difference of two functions which are nonnegative on the phase spece. Weyl transforms do not obey the algebra of classical functions. In the classical limit ℏ → 0, Weyl transforms become classical functions, the Wigner function becomes nonnegative throughout the phase space, and the Hilbert space is spanned by an orthonormal set of vectors which are simultaneous eigenkets of the commuting coordinate and momentum operators.

Journal of Mathematical Physics•Jan 1, 1968•98 citations
We have constructed the Wigner function for the ground state of the hydrogen atom and analysed its variation over phase space. By means of the Weyl correspondence between operators and phase space functions we have then studied the description of angular momentum and resolved a dilemma in the comparison with early quantum mechanics. Finally we have discussed the introduction of local energy densities in coordinate space and demonstrated the validity of a local virial theorem.
We consider Wigner functions in two space dimensions. In particular, we focus on Wigner functions corresponding to energy eigenstates of a non-relativistic particle moving in two dimensions in the absence of a potential. With the help of the Weyl–Wigner correspondence we first transform the eigenvalue equations for energy and angular momentum into phase space. As a result we arrive at partial differential equations in phase space which determine the corresponding Wigner function. We then solve the resulting equations using appropriate coordinates.
Recently a paper on the construction of consistent Wigner functions for cylindrical phase spaces ${\mathbb{S}}^{1}\ifmmode\times\else\texttimes\fi{}\mathbb{R}$, i.e., for the canonical pair angle and orbital angular momentum, was published [H. A. Kastrup, Phys. Rev. A 94, 062113 (2016)] in which the main properties of these functions are derived and discussed and their usefulness is illustrated with examples. The present paper is a continuation which compares the properties of the Wigner functions for cylindrical phase spaces with those of the well-known Wigner functions for planar phase spaces in more detail. Furthermore, the mutual (Weyl) correspondence between Hilbert space operators and their phase-space functions is discussed. The $\ensuremath{\star}$ product formalism is shown to be completely implementable. In addition, basic dynamical laws for Wigner and Moyal functions are derived as generalized Liouville and energy equations. They are very similar to those in the planar case but also show characteristic differences.
The problem of constructing physically and mathematically well-defined Wigner functions for the canonical pair angle $\ensuremath{\theta}$ and angular momentum ppp is solved. While a key element for the construction of Wigner functions for the planar phase space ${(q,p)\ensuremath{\in}{\mathbb{R}}^{2}}$ is the Heisenberg-Weyl group, the corresponding group for the cylindrical phase space ${(\ensuremath{\theta},p)\ensuremath{\in}{S}^{1}\ifmmode\times\else\texttimes\fi{}\mathbb{R}}$ is the Euclidean group E(2)E(2)E(2) of the plane and its unitary representations. Here the angle $\ensuremath{\theta}$ is replaced by the pair $(cos\ensuremath{\theta},sin\ensuremath{\theta})$, which corresponds uniquely to the points on the unit circle. The main structural properties of the Wigner functions for the planar and the cylindrical phase spaces are strikingly similar. A crucial role is played by the sincsincsinc function, which provides the interpolation for the discontinuous quantized angular momenta in terms of the continuous classical ones, in accordance with the famous Whittaker cardinal function well known from interpolation and sampling theories. The quantum mechanical marginal distributions for the angle (continuous) and angular momentum (discontinuous) are, as usual, uniquely obtained by appropriate integrations of the $(\ensuremath{\theta},p)$ Wigner function. Among the examples discussed is an elementary system of simple cat states.
The hydrogen atom is a fundamental exactly soluble system for which the Wigner function, being a quantum analogue of the joint probability distribution of position and momentum, is unknown. In this paper, we present an effective method of calculating the Wigner function, for all bound states of the nonrelativistic hydrogen atom. The formal similarity between the eigenfunctions of the nonrelativistic hydrogen atom in the momentum representation and the Klein–Gordon propagator has allowed the calculation of the Wigner function for an arbitrary bound state of the hydrogen atom, using a simple atomic integral as a generator. These Wigner functions for some low-lying states are depicted and discussed.
The Weyl correspondence for obtaining quantum operators from functions of classical coordinates and momenta is known to be incorrect. To calculate quantum-mechanical expectation values as phase-space averages with the Wigner density function, one cannot use classical functions but must use Weyl transforms. These transforms are defined and their properties derived from quantum mechanics. Their properties are expressed in terms of a Hermitian operator Δ(Q, K) whose Weyl transform is a δ function. The Wigner function is the transform of the density operator. Every Weyl transform is exhibited as a difference of two functions which are nonnegative on the phase spece. Weyl transforms do not obey the algebra of classical functions. In the classical limit ℏ → 0, Weyl transforms become classical functions, the Wigner function becomes nonnegative throughout the phase space, and the Hilbert space is spanned by an orthonormal set of vectors which are simultaneous eigenkets of the commuting coordinate and momentum operators.