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Physica A Statistical Mechanics and its Applications

Calculation of free energy of a three-dimensional Ising-like system in an external field with the use of the model

Ihor V. Pylyuk, Mykhailo P. Kozlovskii

Published Aug 22, 2010• 4 citations
Publisher
DOI
10.1016/j.physa.2010.08.022

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Method of Calculating the Free Energy of Three-Dimensional Ising-Like System in an External Field with the Use of the ρ6ρ^6ρ6 Model
The microscopic approach to calculating the free energy of a three-dimensional Ising-like system in a homogeneous external field is developed in the higher non-Gaussian approximation (the ρ6ρ^6ρ6 model) at temperatures above the critical value of TcT_cTc​ (TcT_cTc​ is the phase-transition temperature in the absence of an external field). The free energy of the system is found by separating the contributions from the short- and long-wave spin-density oscillation modes taking into account both the temperature and field fluctuations of the order parameter. Our analytical calculations do not involve power series in the scaling variable and are valid in the whole field-temperature plane near the critical point including the region in the vicinity of the limiting field h~c\tilde h_ch~c​, which divides external fields into the weak and strong ones (i.e., the crossover region). In this region, the temperature and field effects on the system are equivalent, the scaling variable is of the order of unity, and power series are not efficient. The obtained expression for the free energy contains the leading terms and terms determining the temperature and field confluent corrections.
An analytic method for deriving the free energy of a three-dimensional Ising-like system near the critical point in a homogeneous external field is developed in the the ρ6 model approximation. The mathematical description proposed for temperatures T>Tc (Tc is the phase-transition temperature in the absence of an external field) is valid for fields near , where the scaling variable is of the order of unity and power series in this variable are not effective. At the limiting field , the temperature and field effects on the system in the vicinity of the critical point are equivalent. The total free energy is obtained as a function of temperature, field and microscopic parameters of the system without using series expansions in the scaling variable. In addition to leading terms, the expression for the free energy includes the terms determining the temperature and field confluent corrections.