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AIP conference proceedings

Quantum and Classical Description of H Atom Under Magnetic Field and Quadrupole Trap Potential

Jorge Mahecha, J. Pablo Salas

Published Jan 1, 2006• 0 citations
Publisher

Abstract

A discussion regarding the energy levels spectrum of quantum systems whose classical analogous has states of chaotic motion is presented. The chaotic dynamics of the classical underlying system has its manifestation in the wave functions (in the form of “scars”) and in the energy levels (in the form of “statistical repulsion” of the energy levels). The above mentioned signatures are named “quantum chaos”. A typical study of quantum chaos requires finding accurate energy eigenvalues of highly excited states, to calculate the nearest neighbors spacing between levels, to perform the “unfolding” of the spectrum in order to separate the fluctuations, and finally to find the probability distribution of the unfolded spectrum. This is exemplified by the hydrogen atom under uniform magnetic field and a quadrupole electric field.

DOI
10.1063/1.2406018

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A discussion regarding the energy levels spectrum of quantum systems whose classical analogous has states of chaotic motion is presented. The chaotic dynamics of the classical underlying system has its manifestation in the wave functions (in the form of “scars”) and in the energy levels (in the form of “statistical repulsion” of the energy levels). The above mentioned signatures are named “quantum chaos”. A typical study of quantum chaos requires finding accurate energy eigenvalues of highly excited states, to calculate the nearest neighbors spacing between levels, to perform the “unfolding” of the spectrum in order to separate the fluctuations, and finally to find the probability distribution of the unfolded spectrum. This is exemplified by the hydrogen atom under uniform magnetic field and a quadrupole electric field.
We introduce aspects of quantum chaos by analyzing the eigenvalues and the eigenstates of quantum many-body systems. The properties of quantum systems whose classical counterparts are chaotic differ from those whose classical counterparts are not chaotic. The spectrum of the first exhibits repulsion of the energy levels. This is one of the main signatures of quantum chaos. We show how level repulsion develops in one-dimensional systems of interacting spins 1/2 which are devoid of random elements and involve only two-body interactions. In addition to the statistics of the eigenvalues, we analyze how the structure of the eigenstates may indicate chaos. The programs used to obtain the data are available online.
We introduce aspects of quantum chaos by analyzing the eigenvalues and the eigenstates of quantum many-body systems. The properties of quantum systems whose classical counterparts are chaotic differ from those whose classical counterparts are not chaotic. The spectrum of the first exhibits repulsion of the energy levels, which is one of the main signatures of quantum chaos. We show how level repulsion develops in one-dimensional systems of interacting spins 1/2 which are devoid of random elements and involve only two-body interactions. In addition to the statistics of the eigenvalues, we analyze how the structure of the eigenstates may indicate chaos. The programs used to obtain the data are available online.
The dynamics of Rydberg states of a hydrogen atom subjected simultaneously to uniform static electric field and two microwave fields with commensurate frequencies is considered in the range of small field amplitudes. In the certain range of the parameters of the system the classical secular motion of the electronic ellipse reveals chaotic behavior. Quantum mechanically, when the fine structure of the atom is taken into account, the energy level statistics obey predictions appropriate for the symplectic Gaussian random matrix ensemble.
Statistics of tunneling rates in the presence of chaotic classical dynamics is discussed on a realistic example: a hydrogen atom placed in parallel, uniform, static electric, and magnetic fields, where tunneling is followed by ionization along the fields direction. Depending on the magnetic quantum number, one may observe either a standard Porter-Thomas distribution of tunneling rates or, for strong scarring by a periodic orbit parallel to the external fields, strong deviations from it. For the latter case, a simple model based on random matrix theory gives the correct distribution.
The emergence of chaos in an atom-field system is studied employing both semiclassical and numerical quantum techniques, taking advantage of the algebraic character of the Hamiltonian. A semiclassical Hamiltonian is obtained by considering the expectation value of the quantum Hamiltonian in Glauber (for the field) and Bloch (for the atoms) coherent states. Regular and chaotic regions are identified by looking at the Poincaré sections for different energies and parameter values. An analytical expression for the semiclassical energy density of states is obtained by integrating the available phase space, which provides an exact unfolding to extract the fluctuations in the level statistics. Quantum chaos is recognized in these fluctuations, as a function of the coupling strength, for different regions in the energy spectrum, evaluating the Anderson–Darling (A–D) parameter, which distinguishes the Wigner- or Poisson-like distributions. Peres lattices play a role similar to the Poincaré section for quantum states. They are calculated employing efficient numerical solutions and are a powerful visual tool to identify individual states belonging to a regular or chaotic region, classified by utilizing the Poincaré sections and the A–D parameter. Finally, the quantum Husimi function for selected excited states is shown to have a noticeable similitude with the Poincaré sections at the same energy.
How does the existence of chaos in classical dynamics affect the quantum spectrum of the system? The atom in a magnetic field is a prototype of systems where complete classical and quantal calculations are possible. Transition from regular to chaotic trajectories are linked quantally to the progressive breaking of some peculiar symmetries of the system. We propose a method and its experimental realization on lithium atom to clearly see a transition between regularity and chaos on a quantum spectrum by selecting the starting state of the excitation. In addition, experimental and calculated spectra on hydrogen shows a remarkably good agreement.