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Springer advanced texts in chemistry

Vector Spaces and Linear Transformations

Ralph E. Christoffersen

Published Jan 1, 1989• 0 citations
Publisher
DOI
10.1007/978-1-4684-6360-6_2

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Representations of quantum state vectors by complex phase space amplitudes, complementing the description of the density operator by the Wigner function, have been defined by applying the Weyl–Wigner transform to dyadic operators, linear in the state vector and anti-linear in a fixed 'window state vector'. Here aspects of this construction are explored, and a connection is established with Gabor's 'windowed Fourier transform'. The amplitudes that arise for simple quantum states from various choices of windows are presented as illustrations. Generalized Bargmann representations of the state vector appear as special cases, associated with Gaussian windows. For every choice of window, amplitudes lie in a corresponding linear subspace of square-integrable functions on phase space. A generalized Born interpretation of amplitudes is described, with both the Wigner function and a generalized Husimi function appearing as quantities linear in an amplitude and anti-linear in its complex conjugate. Schrödinger's time-dependent and time-independent equations are represented on phase space amplitudes, and their solutions described in simple cases.

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Chapter 4

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Linear algebra is the natural mathematical language of quantum mechanics. For this reason, the present chapter starts with a review of Hilbert spaces for vectors and operators. We introduce vector and Hilbert spaces along with inner products and metrics. The Dirac notation is developed for the Euclidean vector spaces as a starting point for the concepts of complete orthonormal sets of vectors, closure, dual vector spaces, and adjoint operators. The Dirac delta function in various forms and the principal part is introduced in Appendix 5 as an essential tool. The chapter turns to the main use of Dirac notation for function spaces; the concepts of norm, inner product, and closure are discussed. Fourier, Cosine, and Sine series are discussed as examples of expansions in complete orthonormal sets of functions. Although Hilbert spaces are interesting mathematical objects with important physical applications, the study of linear algebra remains incomplete without a study of linear operators (i.e., linear transformations). In fact, the set of linear transformations itself forms a vector space and therefore has a basis set. The basis set for the operator is linked with the basis sets for the spaces that it operates between. The linear operator can be discussed as an abstract operator or through an isomorphism as a matrix or as a generalized expansion in operator space. A Hermitian (a.k.a., self-adjoint) operator produces a basis set within a Hilbert space. The basis set comes from the eigenvector equation for the particular operator. The fact that a Hermitian operator produces a complete set (of orthornomal vectors) has special importance for quantum mechanics. Observables such as energy or momentum correspond to Hermitian operators. Complete sets make it possible to represent every possible result of a measurement of the observable by an object (vector) in the theory. The Hermitian operators have real eigenvalues which represent the results of the measurement.

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Representations of quantum state vectors by complex phase space amplitudes, complementing the description of the density operator by the Wigner function, have been defined by applying the Weyl–Wigner transform to dyadic operators, linear in the state vector and anti-linear in a fixed 'window state vector'. Here aspects of this construction are explored, and a connection is established with Gabor's 'windowed Fourier transform'. The amplitudes that arise for simple quantum states from various choices of windows are presented as illustrations. Generalized Bargmann representations of the state vector appear as special cases, associated with Gaussian windows. For every choice of window, amplitudes lie in a corresponding linear subspace of square-integrable functions on phase space. A generalized Born interpretation of amplitudes is described, with both the Wigner function and a generalized Husimi function appearing as quantities linear in an amplitude and anti-linear in its complex conjugate. Schrödinger's time-dependent and time-independent equations are represented on phase space amplitudes, and their solutions described in simple cases.
This chapter discusses the linear transformations and shows how they can be represented by matrices. It introduces the terms ‘kernel’ and ‘image’ and a result known as the ‘dimension theorem’. Linear transformations are functions which have additional properties which mean that the vector space operations of vector addition and scalar multiplication are preserved. The chapter introduces general linear transformations and shows how they can be represented by matrices. It introduces the terms ‘kernel’ and ‘image’ and a result known as the ‘dimension theorem’. Linear operators are essential to the study of quantum computation because they represent physical observables and determine the time evolution of a quantum system.
Linear algebra is the natural mathematical language of quantum mechanics. For this reason, the present chapter starts with a review of Hilbert spaces for vectors and operators. We introduce vector and Hilbert spaces along with inner products and metrics. The Dirac notation is developed for the Euclidean vector spaces as a starting point for the concepts of complete orthonormal sets of vectors, closure, dual vector spaces, and adjoint operators. The Dirac delta function in various forms and the principal part is introduced in Appendix 5 as an essential tool. The chapter turns to the main use of Dirac notation for function spaces; the concepts of norm, inner product, and closure are discussed. Fourier, Cosine, and Sine series are discussed as examples of expansions in complete orthonormal sets of functions. Although Hilbert spaces are interesting mathematical objects with important physical applications, the study of linear algebra remains incomplete without a study of linear operators (i.e., linear transformations). In fact, the set of linear transformations itself forms a vector space and therefore has a basis set. The basis set for the operator is linked with the basis sets for the spaces that it operates between. The linear operator can be discussed as an abstract operator or through an isomorphism as a matrix or as a generalized expansion in operator space. A Hermitian (a.k.a., self-adjoint) operator produces a basis set within a Hilbert space. The basis set comes from the eigenvector equation for the particular operator. The fact that a Hermitian operator produces a complete set (of orthornomal vectors) has special importance for quantum mechanics. Observables such as energy or momentum correspond to Hermitian operators. Complete sets make it possible to represent every possible result of a measurement of the observable by an object (vector) in the theory. The Hermitian operators have real eigenvalues which represent the results of the measurement.