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Tuning entanglement in quantum computation and information

Zhen Huang

Published Jan 1, 2007• 0 citations
OpenAlex

Abstract

This thesis studies four related projects: tuning entanglement for spin systems, de-coherence and dynamics of entanglement, entanglement as measure of electron correlation in chemical systems and quantum algorithms to search for global minima. Chapter 1 presents a general introduction and the motivation for these research areas. It is composed of a brief review of the history and the future of modern computers and the state-of-art areas in quantum computation and information. Chapter 2 will be dedicated to introducing the concept of entanglement, its importance, quantification and applications. Then in Chapter 3, the properties of a set of localized spins, which are coupled to an external magnetic field through exchange interaction, are investigated. It is shown that entanglement can be controlled and tuned by varying the anisotropy parameter in the Hamiltonian, and by introducing impurities into the systems. Furthermore, the scheme for amplifying the internal entanglement by external interaction is also studied. In Chapter 4, the applications of the entanglement concept for de-coherence and dynamics is considered. In particular, the dynamics of entanglement for one-dimensional spin systems, which are coupled through nearest neighbor exchange interaction and subject to an external time-dependent magnetic field, is investigated. Using the two-site density matrix, the time-dependent entanglement of formation between nearest neighbor qubits is calculated. It is found that the entanglement can be localized between nearest neighbor qubits for certain values of the external time-dependent magnetic field. In quantum chemistry calculations, the correlation energy is defined as the difference between the Hartree-Fock limit energy and the exact solution of the non-relativistic Schrödinger equation. In Chapter 5, the application of entanglement as an alternative measure of the electron correlation in quantum chemistry calculations is proposed. Entanglement is directly observable and it is one of the most striking properties of quantum mechanics. Finally, Chapter 6 presents the latest research results in developing quantum algorithms for searching the global minima. In this Chapter, the modified Grover’s quantum algorithm using modest numbers of quantum bits to find a global minimum for real problems is demonstrated.

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This thesis contains four projects: entanglement and quantum phase transition in one-dimensional quantum dots system; entanglement and electron correlation in molecular systems; quantum teleportation in one-dimensional quantum dots system and simulation of molecular systems on a quantum computer. Chapter 1 presents a general introduction to quantum computing. A brief history and motivation for quantum computing is introduced. In Chapter 2, we studied the entanglement of an array of quantum dots system modeled by one-dimensional Hubbard Hamiltonian and the relation between quantum entanglement and quantum phase transition. In Chapter 3, entanglement in molecular systems is studied. It is proved that the full configuration interaction (FCI) wave function violates Bell’s inequality, thus it is entangled; while the Hartree-Fock (HF) wave function does not violate Bell’s inequality, so it is unentangled. Based on this, we studied the relation between quantum entanglement and electron correlation in molecular systems. We suggested that quantum entanglement might be used as an alternative way to measure electron correlation in molecular systems. The application of entanglement in an array of quantum dots system in quantum teleportation is studied in Chapter 4. We showed that the space-spin entanglement in the quantum dots system can be filtered to obtain pure spin (space) entanglement, and it can be used in quantum teleportation. We also showed that by selecting appropriate Hamiltonian for the C-NOT gate, the spin-based information can be transformed into charge-based information. The pulse sequence for realizing the C-NOT operation is given. In Chapter 5, we studied the simulation of molecular systems on a quantum computer. We proposed a quantum algorithm to solve the Schrödinger equation using the basis set method based on the multi-configuration self-consistent (MCSCF) wave function. By using this algorithm, the potential energy surfaces of molecules, even some complicated regions, can be studied more efficiently than if the simpler HF wave function was employed. This algorithm can give high success probability, almost deterministic results for ground state and excited states. A small increase in the number of configuration state functions in the MCSCF wave function can dramatically increase the success probability of the quantum algorithm. A multi-reference configuration interaction approach is suggested for the treatment of larger systems. We generalized this method to the finite element method and simulated a quantum system of one particle in Yukawa potential. We showed that numerical methods for solving differential equations can be implemented efficiently on a quantum computer.

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This thesis consists of six chapters. The first chapter gives an introduction to the field of low-dimensional magnetic and electronic systems and relevant numerical techniques. The recent developments in molecular magnets are highlighted. The numerical techniques are reviewed along with their advantages and disadvantages from the present perspective. Study of entanglement of a system can give a great insight into the system. At the last part of this chapter a general overview is given regarding entanglement, its measures and its significance in studying many-body systems. Chapter 2 deals with the technique that has been developed by us for the full symmetry adaptation of non-relativistic Hamiltonians. It is advantageous both computationally and physically/chemically to exploit both spin and spatial symmetries of a system. It has been a long-standing problem to target a state which has definite total spin and also belongs to a definite irreducible representation of a point group, particularly for non-Abelian point groups. A very general technique is discussed in this chapter which is a hybrid method based on valence-bond basis and the basis of the z-component of the total spin. This technique is not only applicable to a system with arbitrary site spins and belonging to any point group symmetry, it is also quite easy to implement computationally. To demonstrate the power of the method, it is applied to the molecular magnetic system, Cu6Fe8, with cubic symmetry. In chapter 3, the extension of the previous hybrid technique to electronic systems is discussed. The power of the method is illustrated by applying it to a model icosahedral half-filled electronic system. This model spans a huge Hilbert space (dimension 1,778,966) and is in the largest non-Abelian point group. All the eigenstates of the model are obtained using our technique. Chapter 4 deals with the thermodynamic properties of an important class of single-chain magnets (SCMs). This class of SCMs has alternate isotropic spin-1/2 units and anisotropic high spin units with the anisotropy axes being non-collinear. Here anisotropy is assumed to be large and negative, as a result, anisotropic units behave like canted spins at low temperatures; but even then simple Ising-type model does not capture the essential physics of the system due to quantum mechanical nature of the isotropic units. A transfer matrix (TM) method is developed to study statistical behavior of this class of SCMs. For the first time, it is also discussed in detail that how weak inter-chain interactions can be treated by a TM method. The finite size effect is also discussed which becomes important for low temperature dynamics. This technique is applied to a real helical chain magnet, which has been studied experimentally. In the fifth chapter a bipartite entanglement entropy of finite systems is studied using exact diagonalization techniques to examine how the entanglement changes in the presence of long-range interactions. The PariserParrPople model with long-range interactions is used for this…

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In this thesis I present the work done during my PhD in the area of low dimensional quantum gases. The chapters of this thesis are self contained and represent individual projects which have been peer reviewed and accepted for publication in respected international journals. Various systems are considered, the first of which is a two particle model which possesses an exact analytical solution. I investigate the non-classical correlations that exist between the particles as a function of the tunable properties of the system. In the second work I consider the coherences and out of equilibrium dynamics of a one-dimensional Tonks-Girardeau gas. I show how the coherence of the gas can be inferred from various properties of the reduced state and how this may be observed in experiments. I then present a model which can be used to probe a one-dimensional Fermi gas by performing a measurement on an impurity which interacts with the gas. I show how this system can be used to observe the so-called orthogonality catastrophe using modern interferometry techniques. In the next chapter I present a simple scheme to create superposition states of particles with special emphasis on the NOON state. I explore the effect of inter-particle interactions in the process and then characterise the usefulness of these states for interferometry. Finally I present my contribution to a project on long distance entanglement generation in ion chains. I show how carefully tuning the environment can create decoherence-free subspaces which allows one to create and preserve entanglement.

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DYNAMICS OF ENTANGLEMENT FOR ONE-DIMENSIONAL SPIN SYSTEMS IN AN EXTERNAL TIME-DEPENDENT MAGNETIC FIELD

Zhen Huang, Sabre Kais

We study the dynamics of entanglement for the XY-model, one-dimensional spin systems coupled through the nearest neighbor exchange interaction and subject to an external time-dependent magnetic field. Using the two-site density matrix, we calculate the time-dependent entanglement of formation between nearest neighbor qubits. We investigate the effect of varying the temperature, the anisotropy parameter and the external time-dependent magnetic field on the entanglement. We have found that the entanglement can be localized between nearest neighbor qubits for certain values of the external time-dependent magnetic field. Moreover, as known for the magnetization of this model, the entanglement shows nonergodic behavior, it does not approach its equilibrium value at the infinite time limit.

arXiv:quant-ph/0505101•International Journal of Quantum Information•Sep 1, 2005•19 citations
This thesis studies four related projects: tuning entanglement for spin systems, de-coherence and dynamics of entanglement, entanglement as measure of electron correlation in chemical systems and quantum algorithms to search for global minima. Chapter 1 presents a general introduction and the motivation for these research areas. It is composed of a brief review of the history and the future of modern computers and the state-of-art areas in quantum computation and information. Chapter 2 will be dedicated to introducing the concept of entanglement, its importance, quantification and applications. Then in Chapter 3, the properties of a set of localized spins, which are coupled to an external magnetic field through exchange interaction, are investigated. It is shown that entanglement can be controlled and tuned by varying the anisotropy parameter in the Hamiltonian, and by introducing impurities into the systems. Furthermore, the scheme for amplifying the internal entanglement by external interaction is also studied. In Chapter 4, the applications of the entanglement concept for de-coherence and dynamics is considered. In particular, the dynamics of entanglement for one-dimensional spin systems, which are coupled through nearest neighbor exchange interaction and subject to an external time-dependent magnetic field, is investigated. Using the two-site density matrix, the time-dependent entanglement of formation between nearest neighbor qubits is calculated. It is found that the entanglement can be localized between nearest neighbor qubits for certain values of the external time-dependent magnetic field. In quantum chemistry calculations, the correlation energy is defined as the difference between the Hartree-Fock limit energy and the exact solution of the non-relativistic Schrödinger equation. In Chapter 5, the application of entanglement as an alternative measure of the electron correlation in quantum chemistry calculations is proposed. Entanglement is directly observable and it is one of the most striking properties of quantum mechanics. Finally, Chapter 6 presents the latest research results in developing quantum algorithms for searching the global minima. In this Chapter, the modified Grover’s quantum algorithm using modest numbers of quantum bits to find a global minimum for real problems is demonstrated.
This thesis contains four projects: entanglement and quantum phase transition in one-dimensional quantum dots system; entanglement and electron correlation in molecular systems; quantum teleportation in one-dimensional quantum dots system and simulation of molecular systems on a quantum computer. Chapter 1 presents a general introduction to quantum computing. A brief history and motivation for quantum computing is introduced. In Chapter 2, we studied the entanglement of an array of quantum dots system modeled by one-dimensional Hubbard Hamiltonian and the relation between quantum entanglement and quantum phase transition. In Chapter 3, entanglement in molecular systems is studied. It is proved that the full configuration interaction (FCI) wave function violates Bell’s inequality, thus it is entangled; while the Hartree-Fock (HF) wave function does not violate Bell’s inequality, so it is unentangled. Based on this, we studied the relation between quantum entanglement and electron correlation in molecular systems. We suggested that quantum entanglement might be used as an alternative way to measure electron correlation in molecular systems. The application of entanglement in an array of quantum dots system in quantum teleportation is studied in Chapter 4. We showed that the space-spin entanglement in the quantum dots system can be filtered to obtain pure spin (space) entanglement, and it can be used in quantum teleportation. We also showed that by selecting appropriate Hamiltonian for the C-NOT gate, the spin-based information can be transformed into charge-based information. The pulse sequence for realizing the C-NOT operation is given. In Chapter 5, we studied the simulation of molecular systems on a quantum computer. We proposed a quantum algorithm to solve the Schrödinger equation using the basis set method based on the multi-configuration self-consistent (MCSCF) wave function. By using this algorithm, the potential energy surfaces of molecules, even some complicated regions, can be studied more efficiently than if the simpler HF wave function was employed. This algorithm can give high success probability, almost deterministic results for ground state and excited states. A small increase in the number of configuration state functions in the MCSCF wave function can dramatically increase the success probability of the quantum algorithm. A multi-reference configuration interaction approach is suggested for the treatment of larger systems. We generalized this method to the finite element method and simulated a quantum system of one particle in Yukawa potential. We showed that numerical methods for solving differential equations can be implemented efficiently on a quantum computer.
Applications of the concepts of quantum information theory are usually related to the powerful and counter-intuitive quantum mechanical effects of superposition, interference and entanglement. In this thesis, I examine the role of coherence and entanglement in complex chemical systems. The research has focused mainly on two related projects: The first project is developing a theoretical model to explain the recent ultrafast experiments on excitonic migration in photosynthetic complexes that show long-lived coherence of the order of hundreds of femtoseconds and the second project developing the Grover algorithm for global optimization of complex systems. The first part can be divided into two sections. The first section is investigating the theoretical frame about the transfer of electronic excitation energy through the Fenna-Matthews-Olson (FMO) pigment-protein complex. The new developed modified scaled hierarchical equation of motion (HEOM) approach is employed for simulating the open quantum system. The second section is investigating the evolution of entanglement in the FMO complex based on the simulation result via scaled HEOM approach. We examine the role of multipartite entanglement in the FMO complex by direct computation of the convex roof optimization for a number of different measures, including pairwise, triplet, quadruple and quintuple sites entanglement. Our results support the hypothesis that multipartite entanglement is maximum primary along the two distinct electronic energy transfer pathways. The second part of this thesis can be separated into two sections. The first section demonstrated that a modified Grover's quantum algorithm can be applied to real problems of finding a global minimum using modest numbers of quantum bits. Calculations of the global minimum of simple test functions and Lennard-Jones clusters have been carried out on a quantum computer simulator using a modified Grover's algorithm. The second section is implementing the basic quantum logical gates upon arrays of trapped ultracold polar molecules as qubits for the quantum computer. Utilized herein is the Multi-Target Optimal Control Theory (MTOCT) as a means of manipulating the initial-to-target transition probability via external laser field. The detailed calculation is applied for the SrO molecule, an ideal candidate in proposed quantum computers using arrays of trapped ultra-cold polar molecules.
Entanglement, according to the physicist Erwin Schrdinger, the essence of Quantum Mechanics, has been known for a long time now to be the source of paradoxes. The most remarkable one is called non-locality and it is at the heart of the Einstein-Podolsky-Rosen (EPR) paradox and of the fact that Quantum Mechanics violates Bell’s inequalities. Recent years, entanglement has emerged as the resource that makes quantum information science so successful. Indeed, based on entanglement, various informational tasks become feasible while they would be impossible using classical physics. Following this new trend in quantum information science, a growing community of scientists has started to investigate the resource entanglement, quantum algorithms, and the possibility of building a quantum computer that perform the quantum algorithms. However, the issue of quantum state interacting with the environment causes errors in the process of quantum computation. These errors arise mainly from decoherence, or the tendency of a quantum computer to decay from a given quantum state into an incoherent state as it interacts with the adjacent state of the environment. These interactions between the environment and quantum bits are unavoidable, and induce the breakdown of information stored in the quantum computer, and thus ended up with errors in computation. In order for quantum computer to be used to solve problems, decoherence and other potential sources of error must be reduced to an acceptable level. In this thesis, we study the various measures for quantifying bipartite and multipartite quantum entanglement for pure and mixed states. We look into the implementation of a quantum network as a universal quantum estimator where its use for estimation of state purity and entanglement are discussed in the first two chapters. The following chapters focus on quantum information processing, where one of the most useful algorithms is discussed, namely the Grover search algorithm. Based on our understanding of various entanglement measures, we study how concurrence changes over Grover search iterations. We further explore the use of this algorithm and quantum Fourier algorithm for applications in the field of bioinformatics. We then review in chapter 5 the progress made in semiconductor quantum dots systems, which have been used in many implementation for quantum information processing. We look into two applications where double quantum dots system can be exploited in chapter 6, namely the quantum teleportation and quantum state transfer. We investigate the various entanglement measures in a double quantum dots system. By introducing decoherence, we identify settings where such system can be used with acceptable performance in these applications. We conclude that quantum teleportation and quantum state transfer remain possible for a large range of external magnetic field and interdot distance under mild decoherence conditions. In chapter 7, we further investigate the nearest neighbor (NN) and nextnearest neighbor (NNN) interactions in the quantum network of one dimension structure. We perform comprehensive numerical studies on the ground state concurrence of both Heisenberg XXX model and Heisenberg XX model with periodic boundary and open boundary conditions. We found that although next-nearest-neighbor interaction does not enhance entanglement in nearest-neighbor pair in Heisenberg XXX model with periodic boundary condition, for Heisenberg XXX model with open boundary condition, nearest neighbor entanglement could be enhanced by next-nearest-neighbor nteraction. This feature is also present in Heisenberg XX model both in periodic and open boundary conditions. In the last chapter, we conclude on our research and provide some outlooks into the future development of quantum network systems.
This thesis consists of six chapters. The first chapter gives an introduction to the field of low-dimensional magnetic and electronic systems and relevant numerical techniques. The recent developments in molecular magnets are highlighted. The numerical techniques are reviewed along with their advantages and disadvantages from the present perspective. Study of entanglement of a system can give a great insight into the system. At the last part of this chapter a general overview is given regarding entanglement, its measures and its significance in studying many-body systems. Chapter 2 deals with the technique that has been developed by us for the full symmetry adaptation of non-relativistic Hamiltonians. It is advantageous both computationally and physically/chemically to exploit both spin and spatial symmetries of a system. It has been a long-standing problem to target a state which has definite total spin and also belongs to a definite irreducible representation of a point group, particularly for non-Abelian point groups. A very general technique is discussed in this chapter which is a hybrid method based on valence-bond basis and the basis of the z-component of the total spin. This technique is not only applicable to a system with arbitrary site spins and belonging to any point group symmetry, it is also quite easy to implement computationally. To demonstrate the power of the method, it is applied to the molecular magnetic system, Cu6Fe8, with cubic symmetry. In chapter 3, the extension of the previous hybrid technique to electronic systems is discussed. The power of the method is illustrated by applying it to a model icosahedral half-filled electronic system. This model spans a huge Hilbert space (dimension 1,778,966) and is in the largest non-Abelian point group. All the eigenstates of the model are obtained using our technique. Chapter 4 deals with the thermodynamic properties of an important class of single-chain magnets (SCMs). This class of SCMs has alternate isotropic spin-1/2 units and anisotropic high spin units with the anisotropy axes being non-collinear. Here anisotropy is assumed to be large and negative, as a result, anisotropic units behave like canted spins at low temperatures; but even then simple Ising-type model does not capture the essential physics of the system due to quantum mechanical nature of the isotropic units. A transfer matrix (TM) method is developed to study statistical behavior of this class of SCMs. For the first time, it is also discussed in detail that how weak inter-chain interactions can be treated by a TM method. The finite size effect is also discussed which becomes important for low temperature dynamics. This technique is applied to a real helical chain magnet, which has been studied experimentally. In the fifth chapter a bipartite entanglement entropy of finite systems is studied using exact diagonalization techniques to examine how the entanglement changes in the presence of long-range interactions. The PariserParrPople model with long-range interactions is used for this…
In this thesis I present the work done during my PhD in the area of low dimensional quantum gases. The chapters of this thesis are self contained and represent individual projects which have been peer reviewed and accepted for publication in respected international journals. Various systems are considered, the first of which is a two particle model which possesses an exact analytical solution. I investigate the non-classical correlations that exist between the particles as a function of the tunable properties of the system. In the second work I consider the coherences and out of equilibrium dynamics of a one-dimensional Tonks-Girardeau gas. I show how the coherence of the gas can be inferred from various properties of the reduced state and how this may be observed in experiments. I then present a model which can be used to probe a one-dimensional Fermi gas by performing a measurement on an impurity which interacts with the gas. I show how this system can be used to observe the so-called orthogonality catastrophe using modern interferometry techniques. In the next chapter I present a simple scheme to create superposition states of particles with special emphasis on the NOON state. I explore the effect of inter-particle interactions in the process and then characterise the usefulness of these states for interferometry. Finally I present my contribution to a project on long distance entanglement generation in ion chains. I show how carefully tuning the environment can create decoherence-free subspaces which allows one to create and preserve entanglement.
We study the dynamics of entanglement for the XY-model, one-dimensional spin systems coupled through the nearest neighbor exchange interaction and subject to an external time-dependent magnetic field. Using the two-site density matrix, we calculate the time-dependent entanglement of formation between nearest neighbor qubits. We investigate the effect of varying the temperature, the anisotropy parameter and the external time-dependent magnetic field on the entanglement. We have found that the entanglement can be localized between nearest neighbor qubits for certain values of the external time-dependent magnetic field. Moreover, as known for the magnetization of this model, the entanglement shows nonergodic behavior, it does not approach its equilibrium value at the infinite time limit.