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Zeitschrift für Physik D Atoms Molecules and Clusters

Collisional de-excitation of the metastableD-states of Ba+ by He, Ne, N2 and H2

A. Hermanni, Günther Werth

Published Dec 1, 1989• 16 citations
Publisher
DOI
10.1007/bf01438503

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Collisional relaxation and fine-structure mixing rate constants have been measured for the metastable DDD doublet (3D3/2,{(3D}_{3/2},(3D3/2​, 3D5/2){3D}_{5/2})3D5/2​) of Ca+{\mathrm{Ca}}^{+}Ca+ ions in the presence of different neutral gases completing a previous work. Experimental results are given for He, Ne, Ar, H2,{\mathrm{H}}_{2},H2​, N2,{\mathrm{N}}_{2},N2​, and CH4.{\mathrm{CH}}_{4}.CH4​. These data have been obtained with a cloud of approximately 105{10}^{5}105 Ca+{\mathrm{Ca}}^{+}Ca+ ions stored in a Paul trap at kinetic energies of around 1 eV. The investigated levels were populated by direct excitation of the corresponding $4S\ensuremath{-}3D$ transitions. The involved time constants were determined from the temporal evolution of the fluorescence of one of the resonance transitions, following the optical pumping of the PPP level from the DDD component. Comparison of our data with other similar experimental and theoretical work is finally presented.