Bose-Einstein condensation (BEC) of 7Li has been investigated. Because the effective interaction between 7Li atoms is attractive, the condensate occupation number N 0 is limited to ∼ 1250 atoms, and when this limit is exceeded, the condensate becomes unstable with respect to mechanical collapse. The interplay of this limit and the natural growth of the condensate during BEC leads to complicated dynamical behavior, which has been studied both theoretically and experimentally. It has been modeled by solving the quantum Boltzmann equation, in conjunction with results from the nonlinear Schrodinger equation. It is found that N0 oscillates rapidly as the condensate alternately fills and collapses, and that the oscillations can persist for many cycles before the gas comes to equilibrium. Experimental evidence for these oscillations was obtained by repeatedly producing a condensate and measuring N 0. The results were seen to vary randomly from one measurement to the next, which is to be expected as the timing of the oscillations is intrinsically stochastic. The distribution of N0 values occurring was measured, and provides quantitative information on the condensate growth and collapse. The equilibration process itself was also observed, by quenching the gas into degeneracy and observing its relaxation.\nIn order to carry out these experiments, sensitive measurement and analysis techniques were developed which enabled N0 to be determined in situ with an accuracy of +/-20% and a precision of +/-60 atoms. The theoretical tools used to study quantum degenerate gases were also applied to the important experimental technique of evaporative cooling, which led to substantial optimization and improvements. As part of this study, the rate constant for dipolar relaxation was measured to be 1.05 +/- 0.1 x 10-14 cm3/s, in agreement with theoretical predictions.
The nature of Bose-Einstein condensation (BEC) in atomic vapours depends critically on the mean-field interaction of the atoms. When this interaction is attractive, the number of atoms in the condensate is limited. The interplay of this limit and the natural growth of the condensate during BEC leads to complicated dynamical behaviour. We develop a model for this behaviour based on the nonlinear Schrödinger equation and the quantum Boltzmann equation. The condensate occupation number is predicted to oscillate rapidly as the condensate alternately fills and collapses, and the oscillations are seen to persist for many cycles before the gas comes to equilibrium. Experimental evidence for these oscillations in the case of 7 Li is presented, along with details of the experimental apparatus and methods.
Bose-Einstein condensation of 7Li has been studied in a magnetically trapped gas. Because of the effectively attractive interactions between 7Li atoms, many-body quantum theory predicts that the occupation number of the condensate is limited to about 1400 atoms. We observe the condensate number to be limited to a maximum value between 650 and 1300 atoms. The measurements were made using a versatile phase-contrast imaging technique. We discuss our measurements, the current theoretical understanding of BEC in a gas with attractive interactions, and future experiments we hope to perform.
Bose-Einstein condensation (BEC) in ultra-cold magnetically-trapped
sp7Li vapor was experimentally observed and quantitative measurements of condensate number were made. Compared to other BEC experiments, lithium is unique due to its negative s-wave scattering length, corresponding to effectively attractive interactions. Due to this attraction, condensates are expected to undergo mechanical collapse if the condensate number exceeds a critical value. In this experiment, an upper limit of about 1000 condensate atoms is found, in agreement with theoretical predictions.\nIn the experiment, the atoms are confined by a set of six permanent magnets in the Ioffe configuration. Optical forces are used to slow and guide atoms from a thermal atomic beam into the magnetic trap. With about
10sp8 atoms loaded into the trap, the vapor is laser-cooled to near 200
muK and then evaporatively cooled by application of a resonantly-tuned microwave field. Evaporative cooling produces a million-fold increase in phase-space density, reaching quantum-degenerate conditions with about 10
sp5 atoms at temperatures near 300
muK. After cooling, the trapped atom distribution is observed by in situ imaging via an optical probe. Calculated atom distributions are fit to the image data.\nIn initial data, the imaging resolution was insufficient to see the spatially-narrow condensate peak, but as phase-space densities approached the expected phase transition, the images suddenly became distorted. Initial fits to the data suggested as many as 10
sp5 condensate atoms, in strong disagreement with theoretical predictions. An imaging model, accounting for imperfections in the imaging optics, shows that the sudden appearance of the distortions is a consequence of BEC, and that these distortions led to the initial over-estimation of cloud phase-space density and condensate number.\nImproved imaging was obtained using large probe detunings, a Phase-Contrast Polarization Imaging (PCPI) technique, and near-diffraction-limited imaging optics. The PCPI method exploits the birefringence of the trapped atoms. From the resulting images, quantitative estimates of condensate number are obtained and compared with theory.
We consider the dynamics of a quantum degenerate trapped gas of
7Li atoms. Because the atoms have a negative
s-wave scattering length, a Bose condensate of
7Li becomes mechanically unstable when the number of condensate atoms approaches a maximum value. We calculate the dynamics of the collapse that occurs when the unstable point is reached. In addition, we use the quantum Boltzmann equation to investigate the nonequilibrium kinetics of the atomic distribution during and after evaporative cooling. The condensate is found to undergo many cycles of growth and collapse before a stationary state is reached.
Bose-Einstein condensation (BEC) of atoms with attractive interactions is profoundly different from BEC of atoms with repulsive interactions. We describe experiments with Bose condensates of 7Li atoms, which are weakly attracting at ultralow temperature. We measure the distribution of condensate occupation numbers occurring in the gas using a near-resonant optical probe to image the atom cloud. This data shows that the number is limited and demonstrates the dynamics of condensate growth and collapse due to the attractive interactions.
This thesis presents studies of quantum degenerate atomic gases of fermionic 6Li and bosonic 7Li. Degeneracy is reached by evaporative cooling of 7Li in a strongly confining magnetic trap. Since at low temperatures direct evaporative cooling is not possible for a polarized fermionic gas, 6Li is sympathetically cooled by thermal contact with 7Li. In a first series of experiments both isotopes are trapped in their low-field seeking higher hyperfine states. A Fermi degeneracy of is achieved for 105 fermions. For more than ~300 atoms, the 7Li condensate collapses, due to the attractive interatomic interaction in this state. This limits the degeneracy reached for both species. To overcome this limit, in a second series of experiments 7Li and 6Li atoms are transferred to their low field seeking lower hyperfine states, where the boson-boson interaction is repulsive but weak. The inter-isotope collisions are used to thermalize the mixture. A 7Li Bose-Einstein condensate (BEC) of 104 atoms immersed in a Fermi sea is produced. The BEC is quasi-one-dimensional and the thermal fraction can be negligible. The measured degeneracies are . The temperature is measured using the bosonic thermal fraction, which vanishes at the lowest temperatures, limiting our measurement sensitivity. In a third series of experiments, the bosons are transferred into an optical trap and their internal state is changed to , the lowest energy state. A Feshbach resonance is detected and used to produce a BEC with tunable atomic interactions. When the effective interaction between atoms is tuned to be small and attractive, we observe the formation of a matter-wave bright soliton. Propagation of the soliton without spreading over a macroscopic distance of 1.1~mm is observed.