On the application of the generalized quantal Bohr–Sommerfeld quantization condition to single-well potentials with very steep walls

Abstract

This investigation concerns some model potentials with very steep walls, for which the quantal Bohr–Sommerfeld half-integer quantization condition, if necessary generalized to correspond to modified phase-integral approximations of arbitrary order, and used without or with higher-order corrections included, can be used for obtaining, very accurately, the energy eigenvalues of the bound states, apart possibly from the lowest ones. One of the cases treated is the potential proportional to cot2x, for which a modified Bohr–Sommerfeld half-integer quantization condition yields the energy eigenvalues exactly. That the Bohr–Sommerfeld half-integer quantization condition is applicable to potentials with very steep walls may at first sight seem surprising in view of the well-known fact that the energy eigenvalues of a square-well potential with infinitely high walls are obtained exactly from the Bohr–Sommerfeld integer quantization condition, i.e., the quantization condition obtained by replacing (s+1/2) π by (s+1) π in the right-hand member of the Bohr–Sommerfeld half-integer quantization condition. From the study of a potential with horizontal bottom and linearly rising walls, which goes over into a square well when the inclination of the walls tends to zero, it can easily be understood, why the half-integer quantization condition is appropriate when the steep walls have a finite slope.