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Oxford University Press eBooks

Maxwell’s Demon

Meir Hemmo, Orly Shenker

Published Mar 7, 2016• 36 citations
Publisher

Abstract

Demon, the famous thought experiment of James Clerk Maxwell, has been devised in 1867 as a counter example for the Second Law of thermodynamics. During the 140 years since the Demon was first suggested, numerous attempts have been made to counter Maxwell's argument. The attempts have been to show that Maxwell was wrong, since his Demon cannot work for one reason or another (see Leff and Rex 2003 for details and references). In this paper we show (following an argument by Albert 2000, Ch. 5.) that Maxwell was basically right, in the sense that his thought experiment is compatible with the laws of mechanics as well as with central principles of statistical mechanics. We then derive some (weak) restrictions on the Demon's efficiency. Finally, we prove that the Demon's cycle of operation can be completed (in particular, the Demon's memory can be erased) without increasing the total entropy of the universe. We draw some conclusions about the way to understand the meaning and role of probability in classical statistical mechanics

DOI
10.1093/oxfordhb/9780199935314.013.63

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Maxwell's Demon

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"Maxwell's Demon", the famous thought experiment of James Clerk Maxwell, has been devised in 1867 as a counter example for the Second Law of thermodynamics. During the 140 years since the Demon was first suggested, numerous attempts have been made to counter Maxwell's argument. The attempts have been to show that Maxwell was wrong, since his Demon cannot work for one reason or another (see Leff and Rex 2003 for details and references). In this paper we show (following an argument by Albert 2000, Ch. 5.) that Maxwell was basically right, in the sense that his thought experiment is compatible with the laws of mechanics as well as with central principles of statistical mechanics. We then derive some (weak) restrictions on the Demon's efficiency. Finally, we prove that the Demon's cycle of operation can be completed (in particular, the Demon's memory can be erased) without increasing the total entropy of the universe. We draw some conclusions about the way to understand the meaning and role of probability in classical statistical mechanics

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Maxwell’s demon emanates from a thought experiment proposed by James Clerk Maxwell in 1867 to illustrate the statistical nature of the second law of thermodynamics. Subsequently researchers wondered whether such a demon could in fact violate the second law. Leon Brillouin argued that the entropy produced during the demon’s measurement precluded such a violation. Years later Oliver Penrose and Charles Bennett observed (independently) that a Maxwell’s demon gathers information and stores it in a memory. Penrose showed that erasure of such a memory sends sufficient entropy to the environment to preclude violation of the second law. Notably this is so even when measurement produces arbitrarily little entropy. Bennett obtained the same result using Rolf Landauer’s seminal research on the thermodynamics of computation. The stunning shift in focus from measurement to erasure provided the impetus to better understand the role of information in quantum mechanics and thermodynamics. Indeed the linkage of information with physics is the principal legacy of Maxwell’s demon. Szilard’s one‐particle classical “gas” model and its quantum mechanical extension, together with postulated connections between entropy and algorithmic information, have provided useful insights. We review the long history of Maxwell’s demon and assess the current status of the second law in the context of the demon’s operations.

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Maxwell’s demon and the management of ignorance in stochastic thermodynamics

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It is nearly 150 years since Maxwell challenged the validity of the second law of thermodynamics by imagining a tiny creature who could sort the molecules of a gas in such a way that would decrease entropy without exerting any work. The demon has been discussed largely using thought experiments, but it has recently become possible to exert control over nanoscale systems, just as Maxwell imagined, and the status of the second law has become a more practical matter, raising the issue of how measurements manage our ignorance in a way that can be exploited. The framework of stochastic thermodynamics extends macroscopic concepts such as heat, work, entropy and irreversibility to small systems and allows us explore the matter. Some arguments against a successful demon imply a second law that can be suspended indefinitely until we dissipate energy in order to remove the records of his operations. In contrast, under stochastic thermodynamics, the demon fails because on average, more work is performed upfront in making a measurement than can be extracted by exploiting the outcome. This requires us to exclude systems and a demon that evolve under what might be termed self-sorting dynamics, and we reflect on the constraints on control that this implies while still working within a thermodynamic framework.

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© 2016 Taylor & Francis It is nearly 150 years since Maxwell challenged the validity of the second law of thermodynamics by imagining a tiny creature who could sort the molecules of a gas in such a way that would decrease entropy without exerting any work. The demon has been discussed largely using thought experiments, but it has recently become possible to exert control over nanoscale systems, just as Maxwell imagined, and the status of the second law has become a more practical matter, raising the issue of how measurements manage our ignorance in a way that can be exploited. The framework of stochastic thermodynamics extends macroscopic concepts such as heat, work, entropy and irreversibility to small systems and allows us explore the matter. Some arguments against a successful demon imply a second law that can be suspended indefinitely until we dissipate energy in order to remove the records of his operations. In contrast, under stochastic thermodynamics, the demon fails because on average, more work is performed upfront in making a measurement than can be extracted by exploiting the outcome. This requires us to exclude systems and a demon that evolve under what might be termed self-sorting dynamics, and we reflect on the constraints on control that this implies while still working within a thermodynamic framework.

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Maxwell's Demon

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This work provides an overview of key historical developments in the formulation of the Second Law of Thermodynamics, focusing on the notorious challenge of ``Maxwell's Demon'', a hypothetical creature who could presumably violate that law. It begins by recalling Maxwell's challenge and discussing the apparent loophole in the Second Law that appears to make such a violation possible. An alternative formulation of the Demon challenge by Szilard is considered, along with his attempted defeat of the Demon through reference to measurement. A similar effort by Brillouin is also analyzed. The proposal of Bennett to defeat the Demon through the requirement of memory erasure is critically discussed. Finally, it is proposed that the Second Law gains a firm foundation through neglected features of quantum theory. In particular, an application of the Heisenberg Uncertainty Principle is shown to decisively defeat the Demon, as well as to serve as justification for Landauer's Principle, albeit in terms distinct from the usual computational formulation.

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Demon, the famous thought experiment of James Clerk Maxwell, has been devised in 1867 as a counter example for the Second Law of thermodynamics. During the 140 years since the Demon was first suggested, numerous attempts have been made to counter Maxwell's argument. The attempts have been to show that Maxwell was wrong, since his Demon cannot work for one reason or another (see Leff and Rex 2003 for details and references). In this paper we show (following an argument by Albert 2000, Ch. 5.) that Maxwell was basically right, in the sense that his thought experiment is compatible with the laws of mechanics as well as with central principles of statistical mechanics. We then derive some (weak) restrictions on the Demon's efficiency. Finally, we prove that the Demon's cycle of operation can be completed (in particular, the Demon's memory can be erased) without increasing the total entropy of the universe. We draw some conclusions about the way to understand the meaning and role of probability in classical statistical mechanics
"Maxwell's Demon", the famous thought experiment of James Clerk Maxwell, has been devised in 1867 as a counter example for the Second Law of thermodynamics. During the 140 years since the Demon was first suggested, numerous attempts have been made to counter Maxwell's argument. The attempts have been to show that Maxwell was wrong, since his Demon cannot work for one reason or another (see Leff and Rex 2003 for details and references). In this paper we show (following an argument by Albert 2000, Ch. 5.) that Maxwell was basically right, in the sense that his thought experiment is compatible with the laws of mechanics as well as with central principles of statistical mechanics. We then derive some (weak) restrictions on the Demon's efficiency. Finally, we prove that the Demon's cycle of operation can be completed (in particular, the Demon's memory can be erased) without increasing the total entropy of the universe. We draw some conclusions about the way to understand the meaning and role of probability in classical statistical mechanics
Maxwell's Demon is a thought experiment devised by J. C. Maxwell in 1867 in order to show that the Second Law of thermodynamics is not universal, since it has a counter-example. Since the Second Law is taken by many to provide an arrow of time, the threat to its universality threatens the account of temporal directionality as well. Various attempts to "exorcise" the Demon, by proving that it is impossible for one reason or another, have been made throughout the years, but none of them were successful. We have shown (in a number of publications) by a general state-space argument that Maxwell's Demon is compatible with classical mechanics, and that the most recent solutions, based on Landauer's thesis, are not general. In this paper we demonstrate that Maxwell's Demon is also compatible with quantum mechanics. We do so by analyzing a particular (but highly idealized) experimental setup and proving that it violates the Second Law. Our discussion is in the framework of standard quantum mechanics; we give two separate arguments in the framework of quantum mechanics with and without the projection postulate. We address in our analysis the connection between measurement and erasure interactions and we show how these notions are applicable in the microscopic quantum mechanical structure. We discuss what might be the quantum mechanical counterpart of the classical notion of "macrostates", thus explaining why our Quantum Demon setup works not only at the micro level but also at the macro level, properly understood. One implication of our analysis is that the Second Law cannot provide a universal lawlike basis for an account of the arrow of time; this account has to be sought elsewhere.
Maxwell’s demon emanates from a thought experiment proposed by James Clerk Maxwell in 1867 to illustrate the statistical nature of the second law of thermodynamics. Subsequently researchers wondered whether such a demon could in fact violate the second law. Leon Brillouin argued that the entropy produced during the demon’s measurement precluded such a violation. Years later Oliver Penrose and Charles Bennett observed (independently) that a Maxwell’s demon gathers information and stores it in a memory. Penrose showed that erasure of such a memory sends sufficient entropy to the environment to preclude violation of the second law. Notably this is so even when measurement produces arbitrarily little entropy. Bennett obtained the same result using Rolf Landauer’s seminal research on the thermodynamics of computation. The stunning shift in focus from measurement to erasure provided the impetus to better understand the role of information in quantum mechanics and thermodynamics. Indeed the linkage of information with physics is the principal legacy of Maxwell’s demon. Szilard’s one‐particle classical “gas” model and its quantum mechanical extension, together with postulated connections between entropy and algorithmic information, have provided useful insights. We review the long history of Maxwell’s demon and assess the current status of the second law in the context of the demon’s operations.
It is nearly 150 years since Maxwell challenged the validity of the second law of thermodynamics by imagining a tiny creature who could sort the molecules of a gas in such a way that would decrease entropy without exerting any work. The demon has been discussed largely using thought experiments, but it has recently become possible to exert control over nanoscale systems, just as Maxwell imagined, and the status of the second law has become a more practical matter, raising the issue of how measurements manage our ignorance in a way that can be exploited. The framework of stochastic thermodynamics extends macroscopic concepts such as heat, work, entropy and irreversibility to small systems and allows us explore the matter. Some arguments against a successful demon imply a second law that can be suspended indefinitely until we dissipate energy in order to remove the records of his operations. In contrast, under stochastic thermodynamics, the demon fails because on average, more work is performed upfront in making a measurement than can be extracted by exploiting the outcome. This requires us to exclude systems and a demon that evolve under what might be termed self-sorting dynamics, and we reflect on the constraints on control that this implies while still working within a thermodynamic framework.
© 2016 Taylor & Francis It is nearly 150 years since Maxwell challenged the validity of the second law of thermodynamics by imagining a tiny creature who could sort the molecules of a gas in such a way that would decrease entropy without exerting any work. The demon has been discussed largely using thought experiments, but it has recently become possible to exert control over nanoscale systems, just as Maxwell imagined, and the status of the second law has become a more practical matter, raising the issue of how measurements manage our ignorance in a way that can be exploited. The framework of stochastic thermodynamics extends macroscopic concepts such as heat, work, entropy and irreversibility to small systems and allows us explore the matter. Some arguments against a successful demon imply a second law that can be suspended indefinitely until we dissipate energy in order to remove the records of his operations. In contrast, under stochastic thermodynamics, the demon fails because on average, more work is performed upfront in making a measurement than can be extracted by exploiting the outcome. This requires us to exclude systems and a demon that evolve under what might be termed self-sorting dynamics, and we reflect on the constraints on control that this implies while still working within a thermodynamic framework.
This work provides an overview of key historical developments in the formulation of the Second Law of Thermodynamics, focusing on the notorious challenge of ``Maxwell's Demon'', a hypothetical creature who could presumably violate that law. It begins by recalling Maxwell's challenge and discussing the apparent loophole in the Second Law that appears to make such a violation possible. An alternative formulation of the Demon challenge by Szilard is considered, along with his attempted defeat of the Demon through reference to measurement. A similar effort by Brillouin is also analyzed. The proposal of Bennett to defeat the Demon through the requirement of memory erasure is critically discussed. Finally, it is proposed that the Second Law gains a firm foundation through neglected features of quantum theory. In particular, an application of the Heisenberg Uncertainty Principle is shown to decisively defeat the Demon, as well as to serve as justification for Landauer's Principle, albeit in terms distinct from the usual computational formulation.