A physics-oriented review is first given of wave equations: examples, the Cauchy problem, solutions in various coordinates, their symmetries, how to build a wave packet. Fourier analysis and dispersion relations are then introduced, and here the key tool is the symbol of differential operators, which makes it possible to study them in terms of algebraic polynomials involving cotangent-bundle variables. Further basic material deals with geometrical optics from the wave equation, phase and group velocity (and their dual relationship in momentum space), the Helmholtz equation and the eikonal approximation for the scalar wave equation. The Schrödinger equation is then derived with emphasis on the wave packet and its relation to classical behaviour in the light of the Einstein–de Broglie relation. For this purpose, it is shown that it is possible to build a wave packet for which the wave-like properties manifest themselves for distances of the order of atomic dimensions. The Fourier transform with respect to time of the wave packet obeys the stationary Schrödinger equation, while the wave function is found to obey a partial differential equation which is of first order in time. The wave equation The wave equation occurs in several branches of classical physics, e.g. the theory of sound, electromagnetic phenomena in vacuum and in material media, and elastic vibrations of material bodies. We consider first the simplest situation, i.e. the propagation of waves in a homogeneous, isotropic and stationary medium. Propagation is characterized by the refractive index n , a quantity that is independent of the point in space-time.
A physics-oriented review is first given of wave equations: examples, the Cauchy problem, solutions in various coordinates, their symmetries, how to build a wave packet. Fourier analysis and dispersion relations are then introduced, and here the key tool is the symbol of differential operators, which makes it possible to study them in terms of algebraic polynomials involving cotangent-bundle variables. Further basic material deals with geometrical optics from the wave equation, phase and group velocity (and their dual relationship in momentum space), the Helmholtz equation and the eikonal approximation for the scalar wave equation. The Schrödinger equation is then derived with emphasis on the wave packet and its relation to classical behaviour in the light of the Einstein–de Broglie relation. For this purpose, it is shown that it is possible to build a wave packet for which the wave-like properties manifest themselves for distances of the order of atomic dimensions. The Fourier transform with respect to time of the wave packet obeys the stationary Schrödinger equation, while the wave function is found to obey a partial differential equation which is of first order in time. The wave equation The wave equation occurs in several branches of classical physics, e.g. the theory of sound, electromagnetic phenomena in vacuum and in material media, and elastic vibrations of material bodies. We consider first the simplest situation, i.e. the propagation of waves in a homogeneous, isotropic and stationary medium. Propagation is characterized by the refractive index n , a quantity that is independent of the point in space-time.
Let us return from optics to mechanics and explore the analogy to its fullest extent. In optics the old system of mechanics corresponds to intellectually operating with isolated mutually independent light rays. The new undulatory mechanics corresponds to the wave theory of light . Erwin Schrödinger, Nobel lecture , 1933 In this chapter we shall see that electromagnetic waves and electrons feature a number of common properties under conditions of spatial confinement. Simple and familiar problems from introductory quantum mechanics and textbook wave optics are recalled in this chapter to emphasize the basic features of waves in spatially inhomogeneous media. Herewith we make a first step towards understanding the properties of electrons and electromagnetic waves in nanostructures and notice that these properties in many instances are counterparts. Different formulas and statements of this chapter can be found in handbooks on quantum mechanics and wave optics. A few textbooks on quantum mechanics do consider analogies of propagation and reflection phenomena in wave optics with those in wave mechanics. Isomorphism of the Schrödinger and Helmholtz equations In Chapter 2 we discussed that an electron in quantum mechanics is described by the wave function, the square of its absolute value giving the probability of finding an electron at a specific point in space. This function satisfies the Schrödinger equation (2.56) which is the second-order differential equation with respect to space and the first-order differential equation with respect to time.
This chapter begins by exploiting the Einstein–de Broglie relation and the notion of symbol, as defined in Eq. (3.6.6). The following steps are the local and global conservation laws associated to the Schrödinger equation, the probabilistic interpretation of the wave function, the spreading of wave packets and transformation properties of wave functions. The solution of the Schrödinger equation for a given initial condition is then studied. For this purpose, one first expands the initial condition in terms of eigenfunctions of the Hamiltonian operator. This is then ‘propagated’ to determine the evolution of the wave function. Thus, one is led to consider the Green kernel of the Schrödinger equation, and the boundary conditions on the wave function that lead to complete knowledge of stationary states. A dynamics involving an isometric non-unitary operator is also studied. The chapter ends with an elementary introduction to harmonic oscillators and to the JWKB method in wave mechanics, plus examples on the Bohr–Sommerfeld quantization. From classical to wave mechanics The correspondence between differential operators and polynomials in k relies on the notion of the symbol defined in Eq. (3.6.6). Now we are aiming to pass from a function on phase space, i.e. the classical Hamiltonian, to an operator which, by analogy, is called the Hamiltonian operator. Such a transition is non-trivial because the map from symbols to operators contains some ambiguity. Such a transition is always possible if polynomials in p have constant coefficients. When this is not the case, i.e. if the coefficients are functions on the configuration space, there is an obvious ambiguity in the association of an operator with xp or px , for instance.
In a previous paper, we showed that the Hamilton equations of motion of a quantum particle are obtained as group velocities of the wave packet describing this particle only if the time dependent phase of a particle wave is proportional to the Lagrangian, not to the Hamiltonian as in a solution of the conventional Schrodinger equation. When a Lagrangian of relativistic form is considered, the wave packet of a quantum particle takes a physical form, with a finite spectrum of a cut off velocity (c). Based on a relativistic quantum principle, asserting the invariance of the time dependent phase for an arbitrary change of coordinates, we obtained the relativistic kinematics and dynamics, the electromagnetic field equations, the spin and the electromagnetic and gravitational interactions. When the Lagrangian is considered as a function of the Hamiltonian, we obtain a Schrodinger type equation with an additional term depending on the velocity and the momentum operator. Based on this equation, we investigate the dynamics of a relativistic quantum particle. In this framework, such a particle is described as a continuous distribution of conservative matter, according to the general theory of relativity. In an electromagnetic field, any time dependent phase variation is modified with a term proportional to a vector potential conjugated to the spatial coordinates and a scalar potential conjugated to time. However, this classical description tells us nothing about the structure of the physical world. Only Quantum Mechanics tells us something about the structure of this world. Namely, that this world is composed of species of identical quantum particles. On one hand, experimentally, it has been found that these particles are of a wavy nature. On the other hand, one could find that the simplest way to define a quantum particle is by a wave packet, with momenta conjugated to coordinates and energy conjugated to time Consider a quantum particle as a wave packet, and find that the group velocities in the coordinate and momentum spaces are in agreement with the Hamilton equations only when the Lagrangian is considered in the time dependent phases, instead of the Hamiltonian in the conventional forms of these waves as solutions of the Schrodinger equation. We define a relativistic quantum principle, and derive a wave equation for a relativistic quantum particle, the relativistic kinematics and dynamics of the particle waves, the Maxwell equations and the Lorentz force of a field interacting with the particle waves, the relativistic transform of such a field, and the spin as a characteristic of the particle waves. We consider a quantum particle as a distribution of conservative matter propagating according to the General Theory of Relativity. We obtain the dynamics of this matter in a gravitational field, the propagation in plane waves perpendicular to geodesic tracks, and equations of conservation. We describe the matter dynamics as a positively defined density and show that, according to the general theory of relativity, such a distribution can be conceive only as of a fragment of matter with a finite mass equal to a mass , as a characteristic of the matter dynamics, – the matter quantization. The group velocities of the Fourier conjugate representations in the coordinate and momentum spaces describe the dynamics of a quantum particle in agreement with the Hamiltonian equations. Under the action of an external (non-gravitational) field, the acceleration of the quantum matter has two components: 1) A component perpendicular to the velocity, given by the relativistic mechanical component of the time dependent phase, and 2) A component given by the additional field terms of this phase. A free quantum particle is described by a non-dispersing wave function , contrary to the solution of the Schrodinger equation. A coherent electromagnetic field, in resonance with a system of active quantum particles in a Fabry-Perot cavity, has a wave vector approximately proportional to the metric elements, as the resonance frequency is approximately constant – a gravitational wave can be detected by the transmission characteristics of an active Fabry-Perot cavity. In a constant gravitational field, a quantum particle undertakes a velocity and an acceleration, which, at the boundary of a black hole are null – absorption and evaporation processes at the boundary of a black hole arise only by gravitational perturbations. Generally, a quantum particle is described by a time-space volume, called graviton, with a spin 2, and a distribution of a specific matter in this volume, with a half-integer spin for Fermions and an integer spin for Bosons. A graviton Lagrangian is obtained as a curvature integral on a graviton volume, and a Hamiltonian tensor is obtained for the gravitational coordinates and velocities. In a gravitational field, the time space coordinates are deformed. In such a field, any plane wave remains perpendicular geodesic, while an additional acceleration is possible in the wave plane.
The physics of special relativity is applied to a wave-packet model of a particle without the usual de Broglie-like assumption of Planck's rule, E = hv. The velocity of the particle is equated to the group-velocity of the wave-packet to associate the particle with its wave-packet. With such an identification it is demonstrated using special relativity that the momentum four-vector, P = [p, E/c2] of the particle is parallel and proportional to a central wave-number four-vector, K0 = [k0. ω0/c2], of the particle's wave-packet. The constant of proportionality, relating these two four-vectors, has the dimension of action and by diffraction experiments it has the value h/2π where h is Planck's constant. This refinement of the de Broglie wave-like nature of a particle suggests that special relativity underlies quantum physics more deeply than heretofore believed. The above quantum rules are used to find the wave-packet function in the one-dimensional case of a non-relativistic free particle and a particle in a conservative force field of potential V (x). This wave-packet function is shown to satisfy an integral time-evolution equation which relates the wave function at time t0 to the function at a slightly later time t. The resulting integral equation is equivalent to the propagator equation or path-integral hypothesised by Feynman. This fact also demonstrates, using the method of Feynman, that the wave-packet function satisfies Schrödinger's partial differential equation. The wave-packet function of a particle in a force field is directly shown to satisfy a linear integral equation which relates the wave-packet at one instant of time to its values at all later times. The kernel or propagator of this integral equation is also equivalent to Feynman's path integral. A computation demonstrates that the position of a moving particle in a simple quadratic potential well does not become more uncertain with the passage of time. This contrasts with the behaviour of a moving free particle which as a function of time becomes more and more difficult to accurately locate.
Quantum mechanics is a theory to explain and predict the behavior of particles such as electrons, protons, neutrons, atomic nuclei, atoms, and molecules, as well as the photon–the particle associated with electromagnetic radiation or light. From quantum theory we obtain the laws of chemistry as well as explanations for the properties of materials, such as crystals, semiconductors, superconductors, and superfluids. Applications of quantum behavior give us transistors, computer chips, lasers, and masers. The relatively new field of molecular biology, which leads to our better understanding of biological structures and life processes, derives from quantum considerations. Thus, quantum behavior encompasses a large fraction of modern science and technology. Quantum theory was developed during the first half of the twentieth century through the efforts of many scientists. In 1926, E. Schrödinger interjected wave mechanics into the array of ideas, equations, explanations, and theories that were prevalent at the time to explain the growing accumulation of observations of quantum phenomena. His theory introduced the wave function and the differential wave equation that it obeys. Schrödinger's wave mechanics is now the backbone of our current conceptional understanding and our mathematical procedures for the study of quantum phenomena. Our presentation of the basic principles of quantum mechanics is contained in the first three chapters. Chapter 1 begins with a treatment of plane waves and wave packets, which serves as background material for the subsequent discussion of the wave function for a free particle.
For any kind of wave phenomenon one can find ways to derive the respective dispersion relation from experimental observations and measurements. This dispersion relation determines the structure of the wave equation and thus characterizes the dynamics of the respective wave. Different wave phenomena are thus governed by different differential equations. Here we want to emphasize the experimental approach to matter waves, but before doing so we will discuss and test the procedure for other types of waves, in particular water waves.