A laser-atom interaction simulator derived from quantum electrodynamics (LASED) is presented, which has been developed in the python programming language. LASED allows a user to calculate the time evolution of a laser-excited atomic system. The model allows for any laser polarization, a Gaussian laser beam profile, a rotation of the reference frame chosen to define the states, and an averaging over the Doppler profile of an atomic beam. Examples of simulations using LASED are presented for excitation of calcium from the
41S0 state to the
41P1 state, for excitation from the helium
31D2 state excited by electron impact to the
101P1 state, and for laser excitation of caesium via the
D2 line.
Atomic states may be embedded in the continuum by dressing the atom by an intense laser field. This is often referred to as a laser induced continuum structure (LICS) [1]. This continuum, in general, also has a natural structure due to the doubly excited states, or autoionizing states, of the atom. We have considered the situation in which a complex atom or ion is subjected to an intense laser field such that the LICS states and autoionizing states occur simultaneously. We have have found that, by tuning the frequency and intensity of the field, the states can become degenerate, i.e. have the same position and width.
An atom or molecule illuminated by a laser has its states modified by the laser. A set of laser-distorted states is defined and the equation for the amplitude of the wavefunction for change of population of these states obtained. The state equation is solved approximately in a novel gauge in the limit where the laser frequency is high, and the utility of this gauge is discussed. The equation is also investigated in the limit of intense fields where the effect of the laser is to make the internal interactions of the atom non-local. The effect of this non-locality is investigated at large distances.