We investigate the principles of autonomous quantized machines that may operate in a dual mode: as compression or absorption refrigerators. The operation mode is determined by the initial quantum state of the piston. Its coefficient of performance may surpass the classical bound, while adhering to the second law. These general results are illustrated for the minimal quantized model of a refrigerator comprised of a qubit coupled to a harmonic-oscillator piston and two spectrally separated baths.
We investigate the principles of autonomous quantized machines that may operate in a dual mode: as compression or absorption refrigerators. The operation mode is determined by the initial quantum state of the piston. Its coefficient of performance may surpass the classical bound, while adhering to the second law. These general results are illustrated for the minimal quantized model of a refrigerator comprised of a qubit coupled to a harmonic-oscillator piston and two spectrally separated baths.
Thermodynamics is a branch of science blessed by an unparalleled combination of generality of scope and formal simplicity. Based on few natural assumptions together with the four laws, it sets the boundaries between possible and impossible in macroscopic aggregates of matter. This triggered groundbreaking achievements in physics, chemistry and engineering over the last two centuries. Close analogues of those fundamental laws are now being established at the level of individual quantum systems, thus placing limits on the operation of quantum-mechanical devices. Here we study quantum absorption refrigerators, which are driven by heat rather than external work. We establish thermodynamic performance bounds for these machines and investigate their quantum origin. We also show how those bounds may be pushed beyond what is classically achievable, by suitably tailoring the environmental fluctuations via quantum reservoir engineering techniques. Such superefficient quantum-enhanced cooling realises a promising step towards the technological exploitation of autonomous quantum refrigerators.
The study of nanoscopic thermal devices attracts an increasing attention, not only because of their key role in understanding the emergence of thermodynamics from quantum theory, but also for the potential use of quantum-mechanical thermal cycles, especially refrigerators, in quantum technologies. This thesis, is devoted to the performance optimization of autonomous (heat-driven) refrigerators. For a quantum refrigerator, one has a full microscopic description of the simple system serving as a working medium, and of its interaction with the external heat baths. This enables a consistent `finite-time? thermodynamic analysis, not relying on any phenomenological assumptions about the leading sources of irreversibility, and allows to establish arguably general performance bounds, essential to benchmark the operation of realistic devices. In particular, tight and model-independent upper bounds for the coefficient of performance at maximum power, are derived here for a class of strongly coupled refrigerators, and seen to hold more generally for other types of heat and power-driven cycles. Remarkably, these ultimate limitations only depend on the particulars of the system-baths interaction at the interface with the object to be cooled. Strategies might be then defined so as to saturate those limits: It is shown how the working medium of the refrigerator may be, for instance, scaled up into a parallel multi-stage configuration, resembling that of macroscopic multi-effect absorption chillers, as a means to increase its cooling power. Similarly, by applying reservoir engineering techniques on selected transitions between the energy states of the working medium, one can mimic exploitable non-equilibrium fluctuations in the baths, capable of boosting the overall power and COP beyond what would be otherwise allowed by the second law of thermodynamics. In this way, heat-driven chillers could be set to compete on a equal footing with the best power-driven refrigerators.
Anti-Zeno enhancement of quantum heat machines has been established for working fluids driven by an external classical field, but whether the same quantum advantage survives when a quantized piston replaces the classical drive has remained open. Here we study an autonomous thermal machine in which a two-level working fluid is coupled to a quantized harmonic piston and to two spectrally separated reservoirs, without external modulation. We derive a finite-time master equation for the resulting carrier and sideband channels, whose rates interpolate between the Zeno, anti-Zeno, and Markovian regimes as the coupling time is varied. For an initially coherent piston, the machine charges the piston and generates more ergotropy than the Markovian reference in the anti-Zeno window. Reversing the same retained channels turns the device into a finite-resource refrigerator with enhanced cooling. The anti-Zeno effect therefore increases the rate of operation while leaving the underlying carrier and sideband energy ratios unchanged. These channel ratios remain consistent with the usual Carnot bounds over the operating regimes considered here. Our results establish finite-time reservoir sampling as a mechanism for enhancing autonomous thermal-machine operation with a quantized piston, without external modulation.
Abstract We propose a model of two identical autonomous quantum refrigerators that interact through their qubits coupled to cold thermal baths. We consider the same specific disposition for each refrigerator related to a three-level system coupled to different thermal baths and, in turn, to a qubit as the object to be cooled. By coupling the two systems, we show that under certain conditions on the model parameters, the devices can operate in the regime of an independent autonomous quantum refrigerator or be subject to an adjustment of the thermodynamic performances. We further investigate the correlations induced by the interaction between the two refrigerators, and illustrate their behavior with respect to their thermodynamic performances. We have found that adjusting the different interaction constants of the model can lead to an evolution of the quantum correlations of the two machines that is inversely related to the behavior of the thermodynamic quantities of both refrigerators. However, this is not necessarily the case when the temperatures of the model are considered as the reference parameters.
Thermodynamics is a branch of science blessed by an unparalleled combination of generality of scope and formal simplicity. Based on few natural assumptions together with the four laws, it sets the boundaries between possible and impossible in macroscopic aggregates of matter. This triggered groundbreaking achievements in physics, chemistry and engineering over the last two centuries. Close analogues of those fundamental laws are now being established at the level of individual quantum systems, thus placing limits on the operation of quantum-mechanical devices. Here we study quantum absorption refrigerators, which are driven by heat rather than external work. We establish thermodynamic performance bounds for these machines and investigate their quantum origin. We also show how those bounds may be pushed beyond what is classically achievable, by suitably tailoring the environmental fluctuations via quantum reservoir engineering techniques. Such superefficient quantum-enhanced cooling realises a promising step towards the technological exploitation of autonomous quantum refrigerators.
An implementation of quantum absorption chillers with three qubits has been recently proposed that is ideally able to reach the Carnot performance regime. Here we study the working efficiency of such self-contained refrigerators, adopting a consistent treatment of dissipation effects. We demonstrate that the coefficient of performance at maximum cooling power is upper bounded by 3/4 of the Carnot performance. The result is independent of the details of the system and the equilibrium temperatures of the external baths. We provide design prescriptions that saturate the bound in the limit of a large difference between the operating temperatures. Our study suggests that delocalized dissipation, which must be taken into account for a proper modeling of the machine-baths interaction, is a fundamental source of irreversibility which prevents the refrigerator from approaching the Carnot performance arbitrarily closely in practice. The potential role of quantum correlations in the operation of these machines is also investigated.