Physical Review Letters
Wentzel-Kramers-Brillouin Quantization of Pseudospin Hamiltonians
Abraham Klein, Ching‐Teh Li
Abstract
A new method is proposed for studying the semiclassical limit for model Hamiltonians which are polynomials in the generators of the Lie algebra $\mathrm{SU}(n)$. The symmetric representation, characterized by a single independent Casimir invariant is mapped onto a subspace of a set of canonical coordinates, and a systematic expansion in the reciprocal of the Casimir invariant is carried out. WKB calculations for a specific example yield improved accuracy compared to previous work.