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Letters in Mathematical Physics

Quantum Fisher Information and Uncertainty Relations

Shunlong Luo

Published Aug 1, 2000• 94 citations
Publisher
DOI
10.1023/a:1011080128419

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Uncertainty relations represent a foundational principle in quantum mechanics, imposing inherent limits on the precision with which \textit{mechanically} conjugate variables such as position and momentum can be simultaneously determined. This work establishes analogous relations for \textit{thermodynamically} conjugate variables -- specifically, a classical intensive parameter θθθ and its corresponding extensive quantum operator O^\hat{O}O^ -- in equilibrium states. We develop a framework to derive a rigorous thermodynamic uncertainty relation for such pairs, where the uncertainty of the classical parameter θθθ is quantified by its quantum Fisher information Fθ\mathcal{F}_θFθ​. The framework is based on an exact integral representation that relates Fθ\mathcal{F}_θFθ​ to the autocorrelation function of operator O^\hat{O}O^. From this representation, we derive a tight upper bound for the quantum Fisher information, which yields a thermodynamic uncertainty relation: Δθ ΔO‾≥kBTΔθ\,\overline{ΔO} \ge k_\text{B}TΔθΔO≥kB​T with ΔO‾≡∂θ⟨O^⟩ Δθ\overline{ΔO}\equiv\partial_θ\langle\hat{O}\rangle\,ΔθΔO≡∂θ​⟨O^⟩Δθ and TTT is the system temperature. The result establishes a fundamental precision limit for quantum sensing and metrology in thermal systems, directly connecting it to the thermodynamic properties of linear response and fluctuations.