Hidden-order phases elude the conventional Ginzburg-Landau framework: although they spontaneously break symmetry, their order remains invisible to standard local two-point correlators. Instead, they are typically characterized by nonlocal (string) order parameters and are believed to underlie a range of exotic quantum states, such as symmetry-protected topological (SPT) phases. While hidden correlations have previously been detected through nonlocal observables in quantum gas microscope experiments, in realistic solid-state systems multipoint observables are typically inaccessible and the signatures of hidden order remain largely unexplored. In this work, we show that hidden order in doped spin chains can be directly probed through dynamical two-point response functions measurable by resonant inelastic X-ray scattering (RIXS) and neutron scattering. Focusing on a minimal model, we numerically identify clear spectral fingerprints of both the hidden-order phase, its associated hidden quantum critical point as well as a specific group of gapless SPT phases. Complementing our numerical results with analytical insights, we uncover the microscopic origin of these spectral signatures and demonstrate how they emerge from the interplay between spin and charge degrees of freedom. Together, our results establish spectroscopy as a practical probe of hidden order and gapless SPT phases and provide a unified understanding of the low-energy physics governing these unconventional quantum phases.
Hidden-order phases elude the conventional Ginzburg-Landau framework: although they spontaneously break symmetry, their order remains invisible to standard local two-point correlators. Instead, they are typically characterized by nonlocal (string) order parameters and are believed to underlie a range of exotic quantum states, such as symmetry-protected topological (SPT) phases. While hidden correlations have previously been detected through nonlocal observables in quantum gas microscope experiments, in realistic solid-state systems multipoint observables are typically inaccessible and the signatures of hidden order remain largely unexplored. In this work, we show that hidden order in doped spin chains can be directly probed through dynamical two-point response functions measurable by resonant inelastic X-ray scattering (RIXS) and neutron scattering. Focusing on a minimal model, we numerically identify clear spectral fingerprints of both the hidden-order phase, its associated hidden quantum critical point as well as a specific group of gapless SPT phases. Complementing our numerical results with analytical insights, we uncover the microscopic origin of these spectral signatures and demonstrate how they emerge from the interplay between spin and charge degrees of freedom. Together, our results establish spectroscopy as a practical probe of hidden order and gapless SPT phases and provide a unified understanding of the low-energy physics governing these unconventional quantum phases.
Since the discovery of phase transitions driven by topological defects, the classification of phases of matter has been significantly extended beyond Ginzburg and Landau's paradigm of spontaneous symmetry breaking (SSB). In particular, intrinsic and symmetry-protected topological (SPT) orders have been discovered in (mostly gapped) quantum many-body ground states. However, these are commonly viewed as zero-temperature phenomena, and their robustness in a gapless ground state or against thermal fluctuations remains challenging to tackle. Here we introduce an explicit construction for SPT-type states with hidden order associated with SSB: They feature (quasi-)long-range correlations along appropriate edges but short-range order in the bulk, ground state degeneracy associated with SSB, and nonlocal string order in the bulk. We apply our construction to predict two types of finite-temperature SPT transitions protected by 1-form symmetries in the Ising and BKT class, respectively, where the usual signs of criticality appear despite the absence of a diverging correlation length in the bulk. While the state featuring hidden Ising order is gapped, the other SPT state associated with the BKT-SPT transition has hidden U ( 1 ) or XY order and constitutes an intrinsically gapless SPT state, associated with a gapless Goldstone mode. Specifically, in this work we discuss spins with global Z 2 or U ( 1 ) symmetry coupled to link variables constituting a loop gas model with a 1-form symmetry. By mapping this system to an Ising-gauge theory, we demonstrate that one of the SPT phases we construct corresponds to the Higgs-SPT phase at T = 0 – which we show here to remain stable at finite temperature. Our work paves the way for a more systematic search for hidden order SPT phases, including in gapless systems, and raises the question if a natural (finite- T ) spin liquid candidate exists that realizes hidden order in the Higgs-SPT class.
We generalize the hidden symmetry-breaking picture of symmetry-protected topological (SPT) order developed by Kennedy and Tasaki in the context of the Haldane phase. Our generalization applies to a wide class of SPT phases in one-dimensional spin chains, protected by an on-site representation of a finite Abelian group. This generalization takes the form of a nonlocal unitary map that relates local symmetry-respecting Hamiltonians in an SPT phase to local Hamiltonians in a symmetry-broken phase. Using this unitary, we establish a relation between the two-point correlation functions that characterize fully symmetry-broken phases with the string-order correlation functions that characterize the SPT phases, therefore establishing the perspective in these systems that SPT phases are characterized by hidden symmetry breaking. Our generalization is also applied to systems with continuous symmetries, including SO(2k+1) and SU(k).
Decades of research have revealed a deep understanding of topological quantum matter with protected edge modes. We report that even richer physics emerges when tuning between two topological phases of matter whose respective edge modes are incompatible. The frustration at the edge leads to novel boundary physics, such as symmetry-breaking phases with exotic non-Landau transitions---even when the edge is zero-dimensional. As a minimal case study, we consider spin chains with ${\mathbb{Z}}_{3}\ifmmode\times\else\texttimes\fi{}{\mathbb{Z}}_{3}$ symmetry, exhibiting two nontrivial symmetry-protected topological (SPT) phases. At the bulk 1+1D critical transition between these SPT phases, we find two stable 0+1D boundary phases, each spontaneously breaking one of the Z3 symmetries. Furthermore, we find that a single boundary parameter tunes a non-Landau boundary critical transition between these two phases. This constitutes a 0+1D version of an exotic phenomenon driven by charged vortex condensation known as deconfined quantum criticality. This work highlights the rich unexplored physics of criticality between nontrivial topological phases and provides insights into the burgeoning field of gapless topological phases.
Symmetry-protected topological (SPT) phases extend the Landau paradigm of quantum matter by admitting distinct symmetry-preserving phases that lack any local order parameter. Demonstrating these phases at scale on programmable quantum processors is a key milestone in using quantum hardware to probe emergent many-body phenomena, yet it is impeded by the circuit depth normally required to capture non-trivial entanglement. Here we use a tensor network based approximate quantum compiling (AQC) protocol to construct shallow quantum circuits (18-39 CNOT depth), which prepare 100-site ground states of the spin-1/2 bond-alternating Heisenberg chain in both SPT phases, to 97.9-99.0% fidelity. Upon executing the circuits on IBM quantum hardware, the resulting states exhibit all defining signatures of SPT order including non-local string order for strings of up to length 20, characteristic degeneracies in the entanglement spectrum and clear evidence of symmetry-protected edge modes. The simultaneous observation of these independent diagnostics establishes current quantum computers as versatile platforms for large-scale studies of symmetry-protected quantum matter. More broadly, our results establish a practical foundation for probing non-equilibrium quench dynamics of such systems in regimes that challenge classical computational methods.
We analyzed quantum phase transitions in the antiferromagnetic dimerized spin-1/2 XY chain and two-leg ladders. Their gapped phases possess distinct nonlocal string order parameters (SOPs) and the hidden symmetry breaking in each phase is identified. After mapping of the original spin Hamiltonians onto the tight-binding models with Dirac or Majorana fermions and the mean-field approximation (for ladders), the essential physics of nonlocal orders can be grasped analytically. By utilizing duality transformations the calculation of SOPs is mapped onto the local order problem in some dual representation and done without further approximations. The phases with hidden orders can also be distinguished by topological winding numbers. The latter provide a complimentary description. Our main result is the framework to treat nonlocal orders and hidden symmetries which unifies the key elements of the Landau paradigm with the new concept of topological order. This unified framework can be straightforwardly applied for spin chain and ladders, topological insulators and superconductors. Applications of this theory to other systems are under way.
The Schrödinger equation is nearly a century old, yet we are still in the midst of uncovering the remarkable phenomena emerging in many-body quantum systems. From superconductivity to anyonic quasiparticles, nature consistently surprises with its rich self-organization. To elucidate and grasp this variety, it is paramount to understand the phases of matter that can occur in many-body ground states, as well as their emergent collective excitations. Of particular interest are topological phases of matter, characterized by exotic excitations or edge phenomena. There exist by now several universal frameworks for gapped systems, i.e., those with an energy gap above the ground state. However, in the last decade, a multitude of gapless quantum wires---effectively one-dimensional systems---have been reported to be topologically non-trivial. A framework for their understanding and classification is missing. In addition to ground state order---topological or otherwise---a more complete picture involves the properties of excitations above the ground state. Alas, little is known about excitations beyond the universal low-energy regime. In part, this is due to a lack of analytical and numerical methods able to describe excitations at finite energies, especially in strongly-interacting systems beyond one dimension. In this thesis, we address these issues: firstly, we build a general understanding of topological phases in one dimension, including both gapped and gapless cases. In particular, we unify previously studied examples into a single framework. Secondly, we develop a novel numerical method for obtaining spectral functions in two dimensions---these give direct insight into the properties of excitations and are moreover experimentally measurable. Using this numerical method, we uncover a variety of robust properties of excitations at finite energies. Part I of this thesis concerns gapped and gapless topological phases in one dimension. In Chapter 2, we first treat the case of non-interacting fermions. Therein, we review the known classification of gapped phases before extending it to the gapless case, showing that exponentially-localized Majorana zero modes can still emerge at the edge when the bulk is gapless. Interacting gapped phases are discussed in Chapter 3, with a focus on symmetry-protected topological order. These have already been classified; our contribution is to provide a non-technical review of this classification as well as showing that many paradigmatic model Hamiltonians can be related to one another. Finally, Chapter 4 introduces the notion of symmetry-enriched quantum criticality, which we propose as a framework for classifying gapless phases. The key message is that in the presence of symmetries, a universality class can divide into distinct phases, characterized by the symmetry action on the low-energy scaling operators. This includes gapless topological phases, with examples hiding in plain sight; we clarify their stability and reinterpret previously studied examples. Part II studies the excitations above the ground states of two-dimensional quantum spin models. The main object of our study is the dynamic spin structure factor; this type of spectral function is reviewed in the first part of Chapter 5. The second part of this chapter introduces a novel matrix-product-state-based algorithm to efficiently compute it, opening a new window on the dynamics of two-dimensional quantum systems. We benchmark this numerical method in Chapter 6 on the exactly-solvable Kitaev model---a paradigmatic topological model realizing a quantum spin liquid. By adding non-integrable Heisenberg perturbations, we identify the first unequivocal theoretical realization of a proximate spin liquid: the ground state becomes conventionally ordered, yet the high-energy spectral properties are structurally similar to those of the nearby Kitaev spin liquid. The latter agrees with aspects of recent inelastic neutron scattering experiments on alpha-RuCl3. In Chapter 7, we turn to one of the oldest models in many-body quantum physics: the spin-1/2 Heisenberg antiferromagnet on the square lattice. Despite its venerable history, there is still disagreement about the physical origin of high-energy spectral features which low-order spin wave theory cannot account for. We provide a simple picture for this strongly-interacting-magnon feature by connecting it to a simple Ising limit. Lastly, Chapter 8 discusses the stability of quasiparticles---collective excitations behaving like a single emergent entity, of which magnons are a prime example. These are often known to be stable at the lowest energies and are presumed to decay whenever this is seemingly allowed by energy and momentum conservation. However, we show that strong interactions can prevent this from happening. We numerically confirm this principle of avoided decay in the (slightly-detuned) Heisenberg antiferromagnet on the triangular lattice. Moreover, we can even identify its fingerprints in existing experimental data on Ba3CoSb2O9 and superfluid helium. In this thesis, we thus enlarge our understanding of quantum phases and their excitations. The identification of the key principles of gapless topological phases in one dimension calls for direct analogues in higher dimensions, waiting to be uncovered. With regard to the robust properties of the excitations identified in this thesis, we are hopeful that these can be extended into a theory of quasiparticle properties away from the universal low-energy regime.