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arXiv:2609.34713

Interactions and dynamics of metastable triplet-state helium dimer with Ne and Ar

Dibyendu Sardar, François Lique

Published Sep 28, 2026• 0 citations
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Abstract

Helium dimer in its metastable triplet electronic state, He$_2(a~^3Σ_u^+)$, is a promising candidate for direct laser cooling and precision measurements. Interactions and collisions involving He$_2(a~^3Σ_u^+)$ remain unexplored in ultracold and cold energy domains. Here, we present the first theoretical investigation of intermolecular interactions and collision dynamics of He$_2(a~^3Σ_u^+)$+Ne van der Waals complex. For the ground electronic state, $X~^3\mathrm{A}'$, we employ a spin-restricted coupled cluster method with single, double, and noniterative triple excitations. The resulting interaction potential exhibits an extremely shallow well with a depth of 4.612 cm$^{-1}$. We construct a three-dimensional vibrationally averaged potential energy surface. Using this surface, we perform full close-coupling calculations including fine-structure levels of He$_2(a~^3Σ_u^+)$ to investigate collisional excitation and quenching induced by Ne. We analyze the low-energy scattering dynamics and model resonant features associated with quasi-bound states supported by interaction potential. Propensity rule for fine-structure conserving transitions is established. We additionally consider He$_2$+Ar collisions and compare their energy dependence and resonance structure with those of He$_2$+Ne. The He$_2$+Ar system exhibits a richer resonance structure, highlighting the sensitivity of low-energy scattering to interaction potential and reduced mass. Calculated PES and scattering properties provide a reliable benchmark for description of He$_2$+Ne van der Waals complex and may be useful for interpretation of future experimental spectra and collision measurements.

DOI
10.48550/arxiv.2609.34713

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