Quantum catalysts can overcome otherwise impossible quantum state transformations without being consumed, and allowing them to become correlated with the output makes this assistance substantially more powerful. This raises a fundamental question for entanglement theory: which limitations on state manipulation remain when such correlated catalysts are freely available? We answer this question in the positive-partial-transpose (PPT) resource theory, which allows a substantially broader class of operations than local operations and classical communication (LOCC). We identify general conditions under which regularized relative-entropy measures become strongly superadditive, and use them to construct monotones that constrain correlated catalytic PPT transformations without any knowledge of the catalyst. In particular, we prove that the regularized PPT relative entropy is fully additive and strongly superadditive, resolving an open problem in entanglement theory. Most importantly, these constraints show that even arbitrary correlated catalysts cannot restore asymptotic reversibility: for an explicit state, the optimal entanglement distillation rate remains strictly smaller than the entanglement cost. Thus, substantial catalytic assistance does not remove some of the fundamental limitations of mixed-state entanglement manipulation.
Quantum catalysts can overcome otherwise impossible quantum state transformations without being consumed, and allowing them to become correlated with the output makes this assistance substantially more powerful. This raises a fundamental question for entanglement theory: which limitations on state manipulation remain when such correlated catalysts are freely available? We answer this question in the positive-partial-transpose (PPT) resource theory, which allows a substantially broader class of operations than local operations and classical communication (LOCC). We identify general conditions under which regularized relative-entropy measures become strongly superadditive, and use them to construct monotones that constrain correlated catalytic PPT transformations without any knowledge of the catalyst. In particular, we prove that the regularized PPT relative entropy is fully additive and strongly superadditive, resolving an open problem in entanglement theory. Most importantly, these constraints show that even arbitrary correlated catalysts cannot restore asymptotic reversibility: for an explicit state, the optimal entanglement distillation rate remains strictly smaller than the entanglement cost. Thus, substantial catalytic assistance does not remove some of the fundamental limitations of mixed-state entanglement manipulation.
Entanglement is a fundamental resource in quantum information processing, yet understanding its manipulation and transformation remains a challenge. Many tasks rely on highly entangled pure states, but obtaining such states is often challenging due to the presence of noise. Typically, entanglement manipulation procedures involving asymptotically many copies of a state are considered to overcome this problem. These procedures allow for distilling highly entangled pure states from noisy states, which enables a wide range of applications, such as quantum teleportation and quantum cryptography. When it comes to manipulating entangled quantum systems on a single copy level, using entangled states as catalysts can significantly broaden the range of achievable transformations. Similar to the concept of catalysis in chemistry, the entangled catalyst is returned unchanged at the end of the state manipulation procedure. Our results demonstrate that despite the apparent conceptual differences between the asymptotic and catalytic settings, they are actually strongly connected and fully equivalent for all distillable states. Our methods rely on the analysis of many-copy entanglement manipulation procedures which may establish correlations between different copies. As an important consequence, we demonstrate that using an entangled catalyst cannot enhance the asymptotic singlet distillation rate of a distillable quantum state. Our findings provide a comprehensive understanding of the capabilities and limitations of both catalytic and asymptotic state transformations of entangled states, and highlight the importance of correlations in these processes.
We study entanglement distillation under operations that remain completely positive under partial-transpose conjugation, a.k.a. PPT channels, in the standard quantum Shannon theory regime of asymptotically vanishing but non-zero error. Our main results are: (a) a regularised formula for the PPT distillable entanglement in terms of a measured-relative-entropy-like quantity; and (b) two different single-letter converses, one based on operator quadratic forms and the other on Hirschman's strengthening of the Hadamard three-line theorem. As an immediate application of (b), we show that the PPT distillable entanglement can be strictly smaller than the regularised Rains bound, thereby resolving an open problem in the theory of entanglement manipulation [Regula et al., NJP 21:103017, 2019]. A gap appears already for 3×3 Werner states: at antisymmetric weight 25/26, a certified upper bound of 0.62107 ebits lies below the (regularised) Rains bound, which equals 2625log25−log23≈0.64766 ebits. On a different note, (a) implies a faithful lower bound on the PPT distillable entanglement in terms of the entanglement negativity, which provides a quantitative counterpart to the qualitatively known fact that any NPT state is PPT distillable [Eggeling et al., PRL 87:257902, 2001].
Determining whether a given state can be transformed into a target state using free operations is one of the fundamental questions in the study of resource theories. Free operations in resource theories can be enhanced by allowing for a catalyst system that assists the transformation and is returned unchanged, but potentially correlated, with the target state. While this has been an active area of recent research, very little is known about the necessary properties of such catalysts. Here, we prove fundamental limits applicable to a large class of correlated catalytic transformations by showing that a small residual correlation between a catalyst and target state implies that the catalyst needs to be highly resourceful. In fact, the resource required diverge in the limit of vanishing residual correlation. In addition, we establish that in imperfect catalysis a small error generally implies a highly resourceful embezzling catalyst. We develop our results in a general resource theory framework and discuss its implications for the resource theory of athermality, the resource theory of coherence, and entanglement theory.
Exact entanglement distillation converts a noisy bipartite state into a maximally entangled state with zero error. Under completely PPT-preserving operations, the additive min-Rains relative entropy provides a single-letter upper bound on the regularized distillation rate. An interesting problem in entanglement theory dating back to 2016 has been whether this bound is always tight. Here we resolve this question in the negative. The key is a tensor-stable rigidity absent from the min-Rains relaxation: every feasible exact-distillation effect must act as the identity on the support of the input state. We convert this constraint into a new single-letter upper bound using a generally non-Hermitian, range-supported witness. For a rank-three subspace, we show this upper bound lies strictly below the min-Rains relative entropy for every state with that support. Thus, the constraint discarded by the min-Rains relaxation remains relevant under arbitrary tensor powers. Our result rules out the min-Rains relative entropy as a closed-form formula for exact PPT distillable entanglement and reveals the subtle asymptotic structure of exact entanglement manipulation under PPT operations.
Quantum catalysis, the ability to enable previously impossible transformations by using auxiliary systems without degrading them, has emerged as a powerful tool in various resource theories. Although catalytically enabled state transformations have been formally characterized by the monotonic behavior of entropic quantifiers (e.g., the von Neumann entropy or nonequilibrium free energy), such characterizations often rely on unphysical assumptions, namely, the ability of using catalysts of infinitely large dimension. This approach offers very limited insights into the practical significance of using catalysis for quantum information processing. Here, we address this problem across a broad class of quantum resource theories. Leveraging quantum information tools beyond the asymptotic regime, we establish sufficient conditions for the existence of catalytic transformations with finite-size catalysts. We further unveil connections between finite-size catalysis and multicopy transformations. Notably, we discover a phenomenon of catalytic resonance: by carefully tailoring the catalysts's state, one can drastically reduce the required dimension of the catalyst, thus enabling efficient catalytic transformations with minimal resources. Finally, we illustrate our findings with examples from the resource theories of entanglement and thermodynamics, as well in the context of catalytic unitary transformations.
Understanding the fundamental limits of state convertibility is crucial for establishing the boundaries of quantum information processing and thermodynamic efficiency. While auxiliary systems, catalysts, can facilitate otherwise impossible transformations, standard catalysis rigidly requires the auxiliary system to return to its exact initial state. In this work, we investigate the power of flexible catalysis, where the catalyst evolves through a cycle of states, restoring its initial configuration only after a finite number of steps. Focusing on the regime of fixed, finite dimensions, we analyze the capabilities of flexible catalysis within the resource theories of entanglement and quantum thermodynamics. In the context of entanglement, we derive conditions limiting flexible catalysts, yet show that flexible catalysis can be strictly more powerful than same-dimensional standard catalysis: it enables deterministic transformations achievable by no standard catalyst of the same dimension, and it strictly increases the success probability of stochastic local operations and classical communication. A similar deterministic advantage arises in quantum thermodynamics, where flexible catalysis enables state transformations that are impossible with any standard catalyst of fixed dimension and Hamiltonian but become achievable via flexible catalysis.