Projected ensembles---the collections of conditional pure states induced on a system by measuring an entangled environment---have become central objects in quantum science, underlying deep thermalization, quantum state designs, the emergence of classicality, and exhibiting interesting phase transitions. Here we develop a general and exact theory of their dynamics, yielding a systematic approach to their dynamics and equilibrium and non-equilibrium stationary states. We derive an exact continuity equation on quantum state space for the projected ensemble, together with microscopic kinetic equations and analytical expressions for the probability flux and source terms generated by the system-environment interaction. The resulting dynamics admits a classical representation: isolated systems obey Hamiltonian transport and Liouville's theorem, while open systems are described by a kinetic theory of probability transport. The stationary continuity equation provides a general characterization of equilibrium and non-equilibrium stationary projected ensembles, which can be analyzed through the method of characteristics. The theory provides an analytical framework for studying the emergence, structure, and timescales of equilibrium and non-equilibrium stationary projected ensembles, with applications ranging from deep thermalization and the emergence of classicality to random quantum-state generation and quantum device benchmarking.
Projected ensembles---the collections of conditional pure states induced on a system by measuring an entangled environment---have become central objects in quantum science, underlying deep thermalization, quantum state designs, the emergence of classicality, and exhibiting interesting phase transitions. Here we develop a general and exact theory of their dynamics, yielding a systematic approach to their dynamics and equilibrium and non-equilibrium stationary states. We derive an exact continuity equation on quantum state space for the projected ensemble, together with microscopic kinetic equations and analytical expressions for the probability flux and source terms generated by the system-environment interaction. The resulting dynamics admits a classical representation: isolated systems obey Hamiltonian transport and Liouville's theorem, while open systems are described by a kinetic theory of probability transport. The stationary continuity equation provides a general characterization of equilibrium and non-equilibrium stationary projected ensembles, which can be analyzed through the method of characteristics. The theory provides an analytical framework for studying the emergence, structure, and timescales of equilibrium and non-equilibrium stationary projected ensembles, with applications ranging from deep thermalization and the emergence of classicality to random quantum-state generation and quantum device benchmarking.
We explore some aspects of nonequilibrium statistical mechanics of classical and quantum systems. Two chapters are devoted to fluctuation theorems which were originally derived for classical systems. The main challenge in formulating them in quantum mechanics is the fact that fundamental quantities of interest, like work, are defined via the classical concept of a phase space trajectory. We utilize the decoherent histories conceptual framework, in which classical trajectories emerge in quantum mechanics as a result of coarse graining, and provide a first-principles analysis of the nonequilibrium work relation of Jarzynski and Crooks's fluctuation theorem for a quantum system interacting with a general environment based on the quantum Brownian motion (QBM) model. We indicate a parameter range at low temperatures where the theorems might fail in their original form. Fluctuation theorems of Jarzynski and Crooks for systems obeying classical Hamiltonian dynamics are derived under the assumption that the initial conditions are sampled from a canonical ensemble, even though the equilibrium state of an isolated system is typically associated with the microcanonical ensemble. We address this issue through an exact analysis of the classical Brownian motion model. We argue that a stronger form of ensemble equivalence than usually discussed in equilibrium statistical mechanics is required for these theorems to hold in the infinite environment limit irrespective of the ensemble used, and proceed to prove it for this model. An exact expression for the probability distribution of work is obtained for finite environments. Intuitively one expects a system to relax to an equilibrium state when brought into contact with a thermal environment. Yet it is important to have rigorous results that provide conditions for equilibration and characterize the equilibrium state. We consider the dynamics of open quantum systems using the Langevin and master equations and rigorously show that under fairly general conditions quantum systems interacting with a heat bath relax to the equilibrium state defined as the reduced thermal state of the system plus environment, even in the strong coupling regime. Our proof is valid to second-order in interaction strength for general systems and exact for the linear QBM model, for which we also show the equivalence of multi-time correlations. In the final chapter we give a sampling of our investigations into macroscopic quantum phenomena. We work out in detail a specific example of how and under what conditions the center of mass (CoM) coordinate of a macroscopic object emerges as the relevant degree of freedom. Interaction patterns are studied in terms of the couplings they induce between the CoM and relative coordinates of two macroscopic objects. We discuss the implications of these interaction patterns on macroscopic entanglement.
Recently, the possibility of investigating single molecule, or single spin observables, as well as the necessity of a better understanding of the mechanisms underlying quantum dynamics in order to obtain nanoscale devices and nanostructered materials suitable for quantum computing tasks, have revived the interest in foundational aspects of quantum statistical mechanics. This thesis aims to give a contribution to this field by re-considering the statistical characterization of a quantum system at the light of some paradigmatic changes in our understanding of quantum theory which have taken place in the last two decades. In particular the impressive development of quantum information theory has changed the perceptions of quantum entanglement: for a long time it has been considered a somewhat paradoxical property of the matter at the atomic scale, but now it is regarded as an essential and ubiquitous phenomenon whose consequences are affecting the very macroscopic world that we experience. Still the decoherence program has brought out the importance of considering a quantum system together with its environment in order to clarify some key aspects of quantum dynamics. Thus, we start from the idea that quantum correlations are ubiquitous and somewhat uncontrollable in systems with many degrees of freedom which are typically considered in statistical mechanics. As a consequence we assume the standpoint that quantum statistical mechanics has not to be based on the underlying idea of a collection of many, independent quantum systems but rather it has to emerge at the level of a global wavefunction (pure state) which describes the system as well as its environment as a whole. In order to investigate the consequences of these assumptions we study the equilibrium distribution of an isolated quantum system. This is defined, in analogy with the ergodic foundations of classical statistical mechanics, on the basis of the time evolution of the quantum state. Then, we study the emergence of thermodynamic properties in a quantum system by studying the probability distribution of some function of interests, as the entropy and the equilibrium state of a subsystem, on Ensembles of Pure States. Such a probability distribution is derived from the geometry of the Hilbert space, and the theoretical tools suitable for its characterization are developed. On the one hand we perform a numerical sampling of the ensemble distributions by employing Monte Carlo techniques, on the other hand simpler analytical approximation of the geometrical distributions are derived by means of a maximum entropy principle. Model systems composed of an ensemble of spins are chosen to illustrate the salient features which emerge from the developed theoretical framework: the main point is that the Ensemble Distributions of “thermodynamic observables” (entropy or equilibrium state of a subsystem) are sharply peaked around a typical value. From the analysis it emerges that each of the overwhelming majority of the wavefunctions which has appreciable weight in the considered ensemble, is characterized by the same value of the “macroscopic” functions. This is a striking evidence of the “typicality” of these properties. In the essence, our impossibility to know the state of the system in detail does not matter, just for the remarkable fact that almost all quantum states behave essentially in the same way. By virtue of this typicality the study of the behaviour of the typical values of the thermodynamic function become meaningful. Notably, under certain conditions, one recovers the results of standard statistical mechanics, that is, the equilibrium average of the state of a subsystem can be cast in the Boltzmann canonical form at the temperature given by the usual thermodynamical relation . In the second part of the thesis we consider the dynamical aspects of the equilibrium state of a subsystem interacting with its environment. The fluctuations around the equilibrium average critically depends on the entanglement between the system and the environment and on the form of the interaction Hamiltonian. The connection between the dynamics of the fluctuations of an observable at the equilibrium and the relaxation toward the equilibrium from a “non typical” initial value is also investigated with the aid of simple model systems. The study presented in this thesis was partly motivated by a critical analysis of the statistical methods available for the theoretical modelling of magnetic resonance experiments. One of these, the Stochastic Liouville Equation, has been employed in a work completed during the first year of my Ph.D. program in order to interpret some feature of a two dimensional electron spin resonance experiment, [Fresch B., Frezzato D., Moro G. J., Kothe G., Freed J. H.; J. Phys. Chem. B., 110, 24238, (2006)].
Investigation on foundational aspects of quantum statistical mechanics recently entered a renaissance period due to novel intuitions from quantum information theory and to increasing attention on the dynamical aspects of single quantum systems. In the present contribution a simple but effective theoretical framework is introduced to clarify the connections between a purely mechanical description and the thermodynamic characterization of the equilibrium state of an isolated quantum system. A salient feature of our approach is the very transparent distinction between the statistical aspects and the dynamical aspects in the description of isolated quantum systems. Like in the classical statistical mechanics, the equilibrium distribution of any property is identified on the basis of the time evolution of the considered system. As a consequence equilibrium properties of quantum system appear to depend on the details of the initial state due to the abundance of constants of the motion in the Schrodinger dynamics. On the other hand the study of the probability distributions of some functions, such as the entropy or the equilibrium state of a subsystem, in statistical ensembles of pure states reveals the crucial role of typicality as the bridge between macroscopic thermodynamics and microscopic quantum dynamics. We shall consider two particular ensembles: the random pure state ensemble and the fixed expectation energy ensemble. The relation between the introduced ensembles, the properties of a given isolated system, and the standard quantum statistical description are discussed throughout the presentation. Finally we point out the conditions which should be satisfied by an ensemble in order to get meaningful thermodynamical characterization of an isolated quantum system.
In classical mechanics the theory of non-linear dynamics provides a detailed framework for the distinction between near-integrable and chaotic systems. Quite in opposition, in quantum many-body theory no generic microscopic principle at the origin of complex dynamics is known. Here we show that the non-equilibrium dynamics of homogeneous Gaudin models can be fully described by underlying classical Hamiltonian equations of motion. The original Gaudin system remains fully quantum and thus cannot exhibit chaos, but the underlying classical description can be analyzed using the powerful tools of the classical theory of motion. We specifically apply this strategy to the Tavis-Cummings model for quantum photons interacting with an ensemble of two-level systems. We show that scattering in the classical phase space can drive the quantum model close to thermal equilibrium. Interestingly, this happens in the fully quantum regime, where physical observables do not show any dynamic chaotic behavior.
Recent advances in quantum simulators allow direct experimental access to ensembles of pure states generated by measuring part of an isolated quantum many-body system. These projected ensembles encode fine-grained information beyond thermal expectation values and provide a new window into quantum thermalization. In chaotic dynamics, projected ensembles exhibit universal statistics governed by maximum-entropy principles, known as deep thermalization. At infinite temperature this universality is characterized by Haar-random ensembles. More generally, physical constraints such as finite temperature or conservation laws lead to Scrooge ensembles, which are maximally entropic distributions of pure states consistent with these constraints. Here we introduce Scrooge k-designs, which approximate Scrooge ensembles, and use this framework to sharpen the conditions under which Scrooge-like behavior emerges. We first show that global Scrooge designs arise from long-time chaotic unitary dynamics alone, without measurements. Second, we show that measuring a complementary subsystem of a scrambled global state drawn from a global Scrooge 2k-design induces a local Scrooge k-design. Third, we show that a local Scrooge k-design arises from an arbitrary entangled state when the complementary system is measured in a scrambled basis induced by a unitary drawn from a Haar 2k-design. These results show that the resources required to generate approximate Scrooge ensembles scale only with the desired degree of approximation, enabling efficient implementations. Complementing our analytical results, numerical simulations identify coherence, entanglement, non-stabilizerness, and information scrambling as essential ingredients for the emergence of Scrooge-like behavior. Together, our findings advance theoretical explanations for maximally entropic, information-stingy randomness in quantum many-body systems.
Quantum thermalization in a many-body system is defined by the approach of local subsystems toward a universal form, describable as an ensemble of quantum states wherein observables acquire thermal expectation values.Recently, it has been demonstrated that the distribution of these quantum states can also exhibit universal statistics, upon associating each state with the outcome of a local projective measurement of the complementary subsystem.Specifically, this collection of pure quantum states-called the projected ensemble-can, under certain conditions, mimic the behavior of a maximally entropic uniformly random ensemble, i.e., form a quantum state design, representing a "deeper" form of quantum thermalization.In this work, we investigate the dynamical process underlying this novel emergent universality.Leveraging a space-time duality mapping for one-dimensional quantum circuits, we argue that the physics of dynamical purification, which arises in the context of monitored quantum systems, constrains the approach of the projected ensemble toward the uniform distribution.We prove that the absence of dynamical purification in the space-time dual dynamics (a condition realized in dual-unitary quantum circuits with appropriate initial states and final measurement bases) generically yields exact state designs for all moments k at the same time, extending previous rigorous results [Ho and Choi, Phys.Rev. Lett.128, 060601 (2022)].Conversely, we show that, departing from these conditions, dynamical purification can lead to a separation of time scales between the formation of a quantum state design for moment k = 1 (regular thermalization) and for high moments k 1 (deep thermalization).Our results suggest that the projected ensemble can probe nuanced features of quantum dynamics inaccessible to regular thermalization, such as quantum information scrambling.