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arXiv:2608.09455

A non-Markovian approach to spin-phonon coherence and the breakdown of the Markovian approximation

Mohamed Belhassen, Tim Schröder, Gregor Pieplow

quant-phSubmitted Aug 10, 2026• Announced Aug 11, 2026• 0 citations
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Abstract

Qubit coherence is an essential figure of merit for quantum information processing applications such as quantum computing, or quantum repeaters. Understanding the coherence properties of the underlying physical qubits that facilitate such applications is therefore are often limited by coupling to lattice phonons, which in turn constrains operation temperature. Here we study phonon induced electronic spin decoherence in group-IV vacancy centers in diamond. We begin by modeling the spin-phonon interaction and then employ the widely used Born-Markov approximation, highlighting its inconsistencies in this setting and its deviations from experimental observations. To close the gap between theoretical predictions and experimental results, we relax certain approximations, investigate their contributions to the predicted coherence times, and identify the dominant sources of discrepancy. We further demonstrate that experimentally measured electronic spin coherence dynamics are consistently captured within a non-Markovian framework, and we show how the magnetic field orientation influences the qubit coherence time.

Comments
12 pages, 7 figures

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