The Kramers-Wannier duality is the prototypical example of a non-invertible symmetry, yet little is known about its fate away from criticality and out of equilibrium. We introduce the Kramers-Wannier entanglement asymmetry, a quantum-information measure that quantifies the breaking of this non-invertible symmetry in the transverse-field Ising chain. We first investigate its equilibrium properties, showing that it exhibits a striking crossover between the ordered and disordered phases together with a pronounced dip at the critical point that becomes increasingly sharp with subsystem size. We then study quantum quenches from both gapped phases to criticality and show that the Kramers-Wannier entanglement asymmetry decays to zero, signaling the dynamical restoration of the non-invertible symmetry. Remarkably, we uncover the emergence of a quantum Mpemba effect: under suitable conditions, states initially farther from equilibrium restore the Kramers-Wannier symmetry faster than states prepared closer to it. We provide both analytical and numerical evidence for this phenomenon and identify the mechanism responsible for its occurrence. Our work establishes entanglement asymmetry as a powerful probe of non-invertible symmetries beyond equilibrium and opens new perspectives on the dynamics of dualities in quantum many-body systems.
The Kramers-Wannier duality is the prototypical example of a non-invertible symmetry, yet little is known about its fate away from criticality and out of equilibrium. We introduce the Kramers-Wannier entanglement asymmetry, a quantum-information measure that quantifies the breaking of this non-invertible symmetry in the transverse-field Ising chain. We first investigate its equilibrium properties, showing that it exhibits a striking crossover between the ordered and disordered phases together with a pronounced dip at the critical point that becomes increasingly sharp with subsystem size. We then study quantum quenches from both gapped phases to criticality and show that the Kramers-Wannier entanglement asymmetry decays to zero, signaling the dynamical restoration of the non-invertible symmetry. Remarkably, we uncover the emergence of a quantum Mpemba effect: under suitable conditions, states initially farther from equilibrium restore the Kramers-Wannier symmetry faster than states prepared closer to it. We provide both analytical and numerical evidence for this phenomenon and identify the mechanism responsible for its occurrence. Our work establishes entanglement asymmetry as a powerful probe of non-invertible symmetries beyond equilibrium and opens new perspectives on the dynamics of dualities in quantum many-body systems.
Symmetry and symmetry breaking are two pillars of modern quantum physics. Still, quantifying how much a symmetry is broken is an issue that has received little attention. In extended quantum systems, this problem is intrinsically bound to the subsystem of interest. Hence, in this work, we borrow methods from the theory of entanglement in many-body quantum systems to introduce a subsystem measure of symmetry breaking that we dub entanglement asymmetry. As a prototypical illustration, we study the entanglement asymmetry in a quantum quench of a spin chain in which an initially broken global U(1) symmetry is restored dynamically. We adapt the quasiparticle picture for entanglement evolution to the analytic determination of the entanglement asymmetry. We find, expectedly, that larger is the subsystem, slower is the restoration, but also the counterintuitive result that more the symmetry is initially broken, faster it is restored, a sort of quantum Mpemba effect, a phenomenon that we show to occur in a large variety of systems.
Abstract Entanglement asymmetry is a quantity recently introduced to measure how much a symmetry is broken in a part of an extended quantum system. It has been employed to analyze the non-equilibrium dynamics of a broken symmetry after a global quantum quench with a Hamiltonian that preserves it. In this work, we carry out a comprehensive analysis of the entanglement asymmetry at equilibrium taking the ground state of the XY spin chain, which breaks theU(1) particle number symmetry, and provide a physical interpretation of it in terms of superconducting Cooper pairs. We also consider quenches from this ground state to the XX spin chain, which preserves theU(1) symmetry. In this case, the entanglement asymmetry reveals that the more the symmetry is initially broken, the faster it may be restored in a subsystem, a surprising and counter-intuitive phenomenon that is a type of a quantum Mpemba effect. We obtain a quasi-particle picture for the entanglement asymmetry in terms of Cooper pairs, from which we derive the microscopic conditions to observe the quantum Mpemba effect in this system, giving further support to the criteria recently proposed for arbitrary integrable quantum systems. In addition, we find that the power law governing symmetry restoration depends discontinuously on whether the initial state is critical or not, leading to new forms of strong and weak Mpemba effects.
Recently, a novel probe to study symmetry breaking, known as entanglement asymmetry, has emerged and has been utilized to explore how symmetry is dynamically restored following quantum quenches. Interestingly, it has been shown that, in certain scenarios, greater initial symmetry breaking leads to faster restoration, akin to a quantum Mpemba effect. This study focuses on investigating the effect of mixed initial states and nonunitary dynamics on symmetry restoration. The mixedness of a state can arise from different sources. We consider dephasing or dissipative processes affecting initial pure states or unitary dynamics of initially thermal states. In the former case, the stationary state after the quench is independent of the initial configuration, resembling the phenomenology of the classical Mpemba effect. Investigating the XY spin chain model, through a combination of analytical calculations and numerical simulations, we identify the conditions for the occurrence of the quantum Mpemba effect. It turns out that this phenomenon still occurs in the presence of dissipation or at finite temperature, even though it will be eventually suppressed as the state becomes more mixed.
The quantum Mpemba effect is the counterintuitive phenomenon whereby a quantum state initially farther from equilibrium relaxes faster than one initially closer to it. We demonstrate this effect in random Clifford circuits with a conserved U(1) charge, using the entanglement asymmetry to characterize relaxation through dynamical symmetry restoration. Exact numerical simulations show that an initially more asymmetric state can become locally more symmetric than an initially less asymmetric one. We explain this behavior by mapping the dynamics onto a charge-conserving quantum automaton, in which the decay of the entanglement asymmetry is controlled by the statistics of encounters between two particle species evolving according to a symmetric simple exclusion process. This mapping yields an analytic expression for the entanglement asymmetry and provides a simple microscopic mechanism for the quantum Mpemba effect: stronger initial symmetry breaking corresponds to a denser particle configuration, which enhances the frequency of particle encounters and thereby accelerates symmetry restoration.
The quantum Mpemba effect (QME) describes the counterintuitive phenomenon where a system initially further from equilibrium relaxes faster than one closer to it. Specifically, the QME associated with symmetry restoration has been extensively investigated across integrable, ergodic, and disordered localized systems. However, its fate in disorder-free ergodicity-breaking settings, such as the Stark many-body localized (Stark-MBL) phase, remains an open question. Here, we explore the dynamics of local U(1) symmetry restoration in a Stark-MBL XXZ spin-12 chain, using the Rényi-2 entanglement asymmetry (EA) as a probe. Using an analytical operator-string expansion supported by numerical simulations, we demonstrate that the QME transitions from an initial-state-dependent anomaly in the ergodic phase to a universal feature in the Stark-MBL regime. Moreover, the Mpemba time scales exponentially with the subsystem size, even in the absence of global transport, and is governed by high-order off-resonant processes. We attribute this robust inversion to a Stark-induced hierarchy of relaxation channels that fundamentally constrains the effective Hilbert space dimension. The findings pave the way for utilizing tunable potentials to engineer and control anomalous relaxation timescales in quantum technologies without reliance on quenched disorder.
In classical settings, the Mpemba effect occurs when a hotter system cools faster than an initially colder one. In quantum systems, this effect can be reinterpreted exploiting the concept of symmetries, with the asymmetry of a subsystem playing the role of temperature. A quantum Mpemba effect arises when a more asymmetric state restores the symmetry faster than a less asymmetric one. Previous work mainly focuses on closed systems characterized by thermal equilibration and Hamiltonian symmetries. In this paper, we analyze the dynamics of asymmetry in an open quantum many-body system featuring symmetry breaking and uncover dynamical behavior that appears to be unique to these settings. In the symmetric phase, we demonstrate the existence of a quantum Mpemba effect, which emerges as a direct consequence of a non-monotonic evolution of the asymmetry. In the broken-symmetry phase, we analyze the imbalance between the system's ability to increase or to decrease its asymmetry. Our results extend the notion of quantum Mpemba effects to open quantum many-body systems exhibiting symmetry-breaking phase transitions and establish them as a platform for observing and controlling anomalous relaxation phenomena.