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arXiv:2606.18982

Probing chaos and thermalization through out-of-time-ordered correlators in random field spin chains

C Jisha, Shivam Mishra, Ravi Prakash

quant-phcond-mat.stat-mechnlin.CDSubmitted Jun 17, 2026• Announced Jun 18, 2026• 0 citations
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Abstract

Out-of-time-ordered correlators (OTOCs) have emerged as a diagnostic of information scrambling and quantum chaos in many-body systems. We investigate the imprints of chaos in the dynamics of OTOCs in the Heisenberg spin-$1/2$ chain with random fields. The system is parameterized to exhibit a crossover from integrable to chaotic dynamics. We demonstrate numerically that the approach to saturation of the OTOC can distinguish between integrable and chaotic regimes, with a power-law $(1/t)$ relaxation for integrable systems and a higher-degree power-law decay $(1/t^α; α\ge 1)$ followed by an exponential relaxation for the chaotic regime. We further show that long-range spectral statistics, such as the number variance, are more effective in characterizing quantum chaos in the regime near saturation of OTOC. We also demonstrate that the relaxation and initial scrambling regimes exhibit distinct and universal features, with the former being sensitive and the latter being robust against different realizations of random-fields. The long-time saturation of OTOC also fluctuates with different realizations, and its exact expression is derived through the Eigenstate Thermalization Hypothesis.

Comments
11 pages, 14 figures

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Out-of-time-ordered correlators (OTOCs) have emerged as a diagnostic of information scrambling and quantum chaos in many-body systems. We investigate the imprints of chaos in the dynamics of OTOCs in the Heisenberg spin-1/21/21/2 chain with random fields. The system is parameterized to exhibit a crossover from integrable to chaotic dynamics. We demonstrate numerically that the approach to saturation of the OTOC can distinguish between integrable and chaotic regimes, with a power-law (1/t)(1/t)(1/t) relaxation for integrable systems and a higher-degree power-law decay (1/tα;α≥1)(1/t^α; α\ge 1)(1/tα;α≥1) followed by an exponential relaxation for the chaotic regime. We further show that long-range spectral statistics, such as the number variance, are more effective in characterizing quantum chaos in the regime near saturation of OTOC. We also demonstrate that the relaxation and initial scrambling regimes exhibit distinct and universal features, with the former being sensitive and the latter being robust against different realizations of random-fields. The long-time saturation of OTOC also fluctuates with different realizations, and its exact expression is derived through the Eigenstate Thermalization Hypothesis.
Abstract Out-of-time-order correlators (OTOCs) have emerged as the preeminent theoretical and experimental probe of quantum information scrambling — the delocalization of quantum information across many-body degrees of freedom. Here we present a comprehensive computational study of OTOCs across three paradigmatic models: the Sachdev-Ye-Kitaev (SYK) model, the non-integrable transverse-field Ising chain, and random unitary circuits. Through exact diagonalization and large-N analytics, we extract Lyapunov exponents, scrambling times, and butterfly velocities, demonstrating that all chaotic systems studied approach, but do not saturate, the Maldacena-Shenker-Stanford (MSS) bound λ_L ≤ 2π/β. Crucially, we introduce the Spectral Out-of-Time-Order Correlator (SOTOC), a novel frequency-domain diagnostic that decomposes information scrambling into its constituent spectral modes. The SOTOC achieves a 32% improvement in Lyapunov exponent extraction precision over conventional log-linear fitting and maintains robust performance at noise levels σ > 0.30, where traditional methods fail. Our phase diagram reveals a sharp transition in scrambling dynamics at h/J ≈ 1.0 in the TFIM, coinciding with the onset of quantum chaos as measured by level-spacing statistics. These results establish SOTOC as a practical and theoretically grounded tool for probing scrambling in near-term quantum devices and holographic systems.
Out-of-time-ordered correlators (OTOCs) have been proposed as a probe of chaos in quantum mechanics, on the basis of their short-time exponential growth found in some particular setups. However, it has been seen that this behavior is not universal. Therefore, we query other quantum chaos manifestations arising from the OTOCs, and we thus study their long-time behavior in systems of completely different nature: quantum maps, which are the simplest chaotic one-body system, and spin chains, which are many-body systems without a classical limit. It is shown that studying the long-time regime of the OTOCs it is possible to detect and gauge the transition between integrability and chaos, and we benchmark the transition with other indicators of quantum chaos based on the spectra and the eigenstates of the systems considered. For systems with a classical analog, we show that the proposed OTOC indicators have a very high accuracy that allow us to detect subtle features along the integrability-to-chaos transition.
The decay of out-of-time-ordered correlators (OTOCs) to a small residual value signals the scrambling of quantum information. This behavior is generic: it occurs in both chaotic and interacting integrable many-body systems, and therefore cannot by itself distinguish between them. In this paper we analytically study the late-time saturation value of a closely related observable, operator purity, and show that its scaling with system size robustly distinguishes chaotic from integrable systems. Our approach is based on the Mazur bound, which provides concrete scaling estimates and makes explicit why the locality of integrable charges matters. We support our findings with numerical simulations of one-dimensional spin chains.
Out-of-time-ordered correlators (OTOC) have been proposed to characterize quantum chaos in generic systems. However, they can also show interesting behavior in integrable models, resembling the OTOC in chaotic systems in some aspects. Here we study the OTOC for different operators in the exactly-solvable one-dimensional quantum Ising spin chain. The OTOC for spin operators that are local in terms of the Jordan-Wigner fermions has a ``shell-like'' structure: After the wavefront passes, the OTOC approaches its original value in the long-time limit, showing no signature of scrambling; the approach is described by a ${t}^{\ensuremath{-}1}$ power law at long time ttt. On the other hand, the OTOC for spin operators that are nonlocal in the Jordan-Wigner fermions has a ``ball-like'' structure, with its value reaching zero in the long-time limit, looking like a signature of scrambling; the approach to zero, however, is described by a slow power law ${t}^{\ensuremath{-}1/4}$ for the Ising model at the critical coupling. These long-time power-law behaviors in the lattice model are not captured by conformal field theory calculations. The mixed OTOC with both local and nonlocal operators in the Jordan-Wigner fermions also has a ``ball-like'' structure, but the limiting values and the decay behavior appear to be nonuniversal. In all cases, we are not able to define a parametrically large window around the wavefront to extract the Lyapunov exponent.
Abstract The dynamic region of out-of-time-ordered correlators (OTOCs) serves as a powerful indicator of chaos in classical and semiclassical systems, capturing the characteristic exponential growth. However, in spin systems, the dynamic region of OTOCs does not reliably quantify chaos as both integrable and chaotic systems display similar behavior. Instead, we utilize the saturation behavior of OTOCs to differentiate between chaotic and integrable regimes. In integrable systems, the saturation region of OTOCs exhibits oscillatory behavior, while in chaotic systems, it shows a stable saturation. To evaluate this distinction, we investigate a time-dependent Ising spin system subjected to a linearly ramping transverse field, analyzing both integrable (without longitudinal field) and non-integrable (with longitudinal field) scenarios. This setup accelerates system ergodicity due to the introduction of an additional time scale within the system, enhancing chaotic dynamics in the non-integrable regime, and provides a compelling model for studying the interplay between integrability and chaos in quantum systems. To further support our findings, we investigate the level spacing distribution of time-dependent unitary operators, which effectively distinguishes chaotic from regular regions in our system and corroborates the results obtained from the saturation behavior of the OTOC. Additionally, we calculate a metric for the normalized Fourier spectrum of the OTOC which is dependent on the number of frequency components present to gain insights into the observed oscillations and its dependence on the ramping field. Graphical abstract
Out-of-time-order correlators (OTOCs) have been proposed as sensitive probes for chaos in interacting quantum systems. They exhibit a characteristic classical exponential growth, but saturate beyond the so-called scrambling or Ehrenfest time τ_{E} in the quantum correlated regime. Here we present a path-integral approach for the entire time evolution of OTOCs for bosonic N-particle systems. We first show how the growth of OTOCs up to τ_{E}=(1/λ)logN is related to the Lyapunov exponent λ of the corresponding chaotic mean-field dynamics in the semiclassical large-N limit. Beyond τ_{E}, where simple mean-field approaches break down, we identify the underlying quantum mechanism responsible for the saturation. To this end we express OTOCs by coherent sums over contributions from different mean-field solutions and compute the dominant many-body interference term amongst them. Our method further applies to the complementary semiclassical limit ℏ→0 for fixed N, including quantum-chaotic single- and few-particle systems.