We establish a rigorous mathematical bridge from quantum many-body path integrals to the cusp catastrophe model by Lyapunov-Schmidt reduction, which provides a theoretical foundation for analyzing superconducting phase transition using the catastrophe theory. First, it is proved that, near the critical point the infinite-dimensional effective action is diffeomorphic to a finite-dimensional catastrophe. Secondly, starting from Ginzburg-Landau free energy functional, the Euler-Lagrange partial differential equation can be reduced to the cusp catastrophe model. Thirdly, the fermionic imaginary-time path integral to the cusp catastrophe is derived through the Hubbard-Stratonovich transformation, Matsubara frequency expansion, and Grassmann algebra. Furthermore, we connect this framework with the adsorption potential theory we proposed, elucidating the catastrophic topological nature of the electron pairing mechanism in high-temperature superconductivity. The precise microscopic derivation of the adsorption potential from first-principles electronic structure calculations would strengthen the predictive power of the theory.
We consider a lattice version of the ``negative-
U′′ Hubbard model in three dimensions, to study the crossover from a superconducting phase transition (dominated by phase fluctuation) to a regime where the amplitude of the superconducting order parameter controls the critical temperature. Starting from a fermionic Hamiltonian, we give a microscopic derivation of the effective action in terms of the relevant physical fields: the modulus and phase of the superconducting order parameter. Furthermore, by employing to the resulting coarse--grained quantum
XY model the phase fluctuation algebra between number and phase operators (given by the Euclidean group
E2), we map the ``phase-only'' action onto a solvable quantum spherical model. We establish the self--consistent theory (involving both fermionic and bosonic degrees of freedom), and calculate the superconducting phase coherence transition temperature
Tc as a function of the coupling strength
∣U∣, exhibiting a maximum where the behavior crosses over from BCS to Bose-Einstein (BE) condensation. We examine a pseudogap in the normal state which emerges naturally as a precursor of superconductivity at the second characteristic temperature
Tg due to a state with bound pairs but without long--range phase coherence. Furthermore, we demonstrate that the reduced gaps of the model $2{\ensuremath{\Delta}}_{0}{/k}_{B}{T}_{g}\ensuremath{\sim}4$ is almost independent on the pairing strength
∣U∣/t, whereas $2{\ensuremath{\Delta}}_{0}{/k}_{B}{T}_{c}$ increases with increasing
∣U∣---in striking analogy with the phenomenology of the high--temperature cuprate superconductors when interpreted in terms of the BCS-BC crossover scenario.
Starting from H. Fröhlich's second-quantized Hamiltonian for a
d-dimensional electron gas in interaction with lattice phonons describing the quantum vibrations of a metal, we present a rigorous mathematical derivation of the superconducting state, following the principles laid out originally in 1957 by J. Bardeen, L. Cooper and J. Schrieffer. As in the series of papers written on the subject in the 90es, of which the present paper is a continuation, the representation of ions as a uniform charge background allows for a
(1+d)-dimensional fermionic quantum-field theoretic reformulation of the model at equilibrium. For simplicity, we restrict in this article to
d=2 dimensions and zero temperature, and disregard effects due to electromagnetic interactions. Under these assumptions, we prove transition from a Fermi liquid state to a superconducting state made up of Cooper pairs of electrons at an energy level
Γϕ∼ℏωDe−π/mλ equal to the mass gap, expressed in terms of the Debye frequency
ωD, electron mass
m and coupling constant
λ. The dynamical
U(1)-symmetry breaking produces at energies lower than the energy gap
Γϕ a Goldstone boson, a non-massive particle described by an effective
(2+1)-dimensional non-linear sigma-model, whose parameters and correlations are computed. The proof relies on a mixture of general concepts and tools (multi-scale cluster expansions, Ward identities), adapted to this quantum many-body problem with its extended infra-red singularity located on the Fermi circle, and a specific
1/N-expansion giving the leading diagrams at intermediate energies. Ladder diagrams are proved to provide the leading behavior in the infra-red limit, in agreement with mean-field theory predictions.
One of the most powerful and prized concepts in physics is that of universal behaviour. Universality allows us to make predictions for entire classes of systems without requiring knowledge of the microscopics, and can be found in classical and quantum systems in both equilibrium and in their dynamics. Often in many-body systems, this universal behaviour is found in regimes where effects at macroscopic length scales dominate over microscopic fluctuations, which is particularly true at a phase transition. In this thesis, we will address universality in quantum many-body physics, and its connection to the branch of mathematics known as catastrophe theory (CT). In CT, singularities in a theory take on several universal forms, known as catastrophes, which can be shown to manifest themselves in classical mechanical trajectories. We extend the concept of catastrophes to their wave variants, known as diffraction integrals, and identify how these universal features appear in many-body wavefunctions and observables. Specifically, in Chapter 2, we examine how the wavefunction of a
δ-kicked Hamiltonian can be mapped exactly onto the Pearcey function, along with the effects of a phase transition on the diffraction. In Chapter 3, we examine the free-Fermion representation of the one-dimensional transverse-field Ising model in a similar vein, and identify the presence of catastrophes away from and through the critical point.
The collective behavior exhibited by a large number of microscopic quantum particles is at the heart of some of the most striking phenomena in condensed matter physics such as Bose-Einstein condensation and superconductivity. Physicists and mathematicians have made great progress in understanding when and how these collective phenomena emerge through the interplay of particle statistics, particle interaction and the value of thermodynamic parameters like the temperature or the chemical potential. Due to the extreme complexity of realistic many-body systems, it is natural to introduce appropriate simplifications to render their analysis feasible. Three examples of such simplifications which have proven themselves as viable starting points for a fruitful and mathematically rigorous analysis of many-body systems are the following: (a) the study of integrable models; (b) the derivation of effective theories, valid on a macroscopic scale, from more fundamental microscopic theories under appropriate coarse-graining; and (c) the use of quantum information theory to understand general connections between correlation, entanglement and particle statistics. In this thesis, we present mathematically rigorous results that were obtained in these three directions. (1) We prove anomalous quantum many-body transport in XY quantum spin chains for certain choices of the external magnetic field. The anomalous transport is described via new kinds of anomalous Lieb-Robinson bounds, including one of power-law type. We note that the XY spin chain is integrable as it can be mapped to free fermions via the non-local Jordan-Wigner transformation. (2) We derive effective macroscopic theories of Ginzburg-Landau type from the microscopic BCS theory of superconductivity in certain circumstances. We study the case of a multi-component order parameter for translation-invariant systems and the condensation of fermion pairs at zero temperature in a domain with a hard boundary. (3) We use techniques from quantum information-theory to derive bounds on the entropy of fermionic reduced density matrices, a measure of the entanglement inherent to a fermionic quantum state.
This thesis focuses on the study of the thermodynamics of fermionic systems on lattices, from the point of view of the C*-algebraic formulation of quantum mechanics, and on the application of the so-called "catastrophe theory" to the analysis of the phase diagram of an explicit fermionic model.The first chapter is devoted to the introduction of some of the basic and most important properties of C*-algebras, and also to the study of its representations and its set of states.The second chapter is devoted to the development of some important results of catastrophe theory.The results derived in the chapter allows one to analyze the behavior of the minima of members of a family of functions around a degenerate critical point, and they will be used to study the behavior of the thermodynamic pressure for a given fermionic lattice model.The third chapter presents some of the formalism developed in [4], that concerns the existence of the thermodynamics and equilibrium states of lattice fermi systems subject to a suitable set of long-range interactions (i.e., interactions containing mean-field terms).Finally, in the last chapter, using all the formalisms and results already studied in the previous chapters, the thermodynamics of an explicit BCS-like model is analyzed.With the help of catastrophe theory, it is shown that such model exhibits a coexistence of magnetic and superconducting phases for a suitable choice of parameters, and through a perturbative analysis it is also shown that the coexistence still holds when a small kinetic term is added into the model.
Abstract As charge carrier of the macroscopic superconductivity, the Cooper pair is a composite particle of two paired electrons, which has both center-of-mass and inner-pair degrees of freedom. In most cases, these two different degrees of freedom can be well described by the macroscopic Ginzburg-Landau theory and the microscopic Bardeen-Cooper-Schrieffer (BCS) theory, respectively. Near the superconducting phase transition where the Cooper pair is fragile and unstable because of the small binding energy, there are non-trivial couplings between these two different degrees of freedom due to such as finite energy and/or momentum transfer. The non-trivial couplings make the original derivation of the Ginzburg-Landau theory from the BCS theory fail in principle as where these two different degrees of freedom should not be decoupled. In this article, we will present a renormalization formalism for an extended Ginzburg-Landau action for the superconducting phase transition where there is finite energy transfer between the center-of-mass and the inner-pair degrees of freedom of Cooper pairs. This renormalization formalism will provide a theoretical tool to study the unusual dynamical effects of the inner-pair time-retarded physics on the superconducting phase transition.