We investigate the properties of heat conduction in a network of harmonic oscillators interacting with heat baths, described by a generalized model of Brownian motion. This model includes noise and dissipation terms in both the momentum and position equations. This generalization is motivated by the requirement of consistency with the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) equation. Because standard definitions of heat current based on velocity become mathematically inconsistent in this framework, we derive an analytical expression for the steady-state heat flow based on an extended framework of stochastic energetics. We confirm that Fourier's law (linear thermal response) is satisfied and that the model naturally captures microscopic thermal boundary resistance, analogous to Kapitza resistance. This demonstrates that our generalized model functions as a valid phenomenological framework for simulating non-equilibrium processes, marking a crucial step toward a unified formulation of stochastic and quantum thermodynamics. Furthermore, we analyze the time evolution of heat conduction by numerically solving the corresponding differential equations for the correlation functions. Unlike standard Brownian motion, the generalized model generates continuous and nowhere differentiable trajectories for both momentum and position (as is characteristic of overdamped dynamics). Finally, we show that the heat current exhibits characteristic transient behavior when the inter-particle interaction is switched on. Specifically, an instantaneous heat flow emerges, whose direction is strictly governed by whether the interaction is attractive or repulsive, significantly differing from the predictions of the standard model.
We investigate the properties of heat conduction in a network of harmonic oscillators interacting with heat baths, described by a generalized model of Brownian motion. This model includes noise and dissipation terms in both the momentum and position equations. This generalization is motivated by the requirement of consistency with the Gorini-Kossakowski-Sudarshan-Lindblad (GKSL) equation. Because standard definitions of heat current based on velocity become mathematically inconsistent in this framework, we derive an analytical expression for the steady-state heat flow based on an extended framework of stochastic energetics. We confirm that Fourier's law (linear thermal response) is satisfied and that the model naturally captures microscopic thermal boundary resistance, analogous to Kapitza resistance. This demonstrates that our generalized model functions as a valid phenomenological framework for simulating non-equilibrium processes, marking a crucial step toward a unified formulation of stochastic and quantum thermodynamics. Furthermore, we analyze the time evolution of heat conduction by numerically solving the corresponding differential equations for the correlation functions. Unlike standard Brownian motion, the generalized model generates continuous and nowhere differentiable trajectories for both momentum and position (as is characteristic of overdamped dynamics). Finally, we show that the heat current exhibits characteristic transient behavior when the inter-particle interaction is switched on. Specifically, an instantaneous heat flow emerges, whose direction is strictly governed by whether the interaction is attractive or repulsive, significantly differing from the predictions of the standard model.
In Chapter I of this dissertation, we present a pedagogical introduction to the basic concepts of stochastic theory and review the progress made as well as the outstanding unsolved problems in the field. For the rest of this dissertation, we use a generalized quantum Langevin equation (GLE) approach to investigate various properties of quantum dissipative systems. In Chapter II, calculations for the displacement and random force correlation functions for Brownian motion are generalized to the case of an arbitrary heat bath for a damped harmonic quantum oscillator. The mean square displacement of such an oscillator is then evaluated for both Ohmic and blackbody radiation heat baths, to determine the effects of many parameters on the localization of the oscillator. In Chapter III, the formalism is extended to the Brownian motion of a charged particle in an external magnetic field as well as in a potential. The influence of the magnetic field on the memory function and random force is determined, with the blackbody radiation heat bath analyzed as a special case. For a charged harmonic oscillator, the generalized susceptibility is obtained, which enables us to derive the symmetrized position correlation functions using the fluctuation-dissipation theorem. In addition, we obtain the free energy of the system by generalizing the "remarkable formula" of Ford, Lewis, and O'Connell. Explicit calculations are performed for Ohmic and blackbody radiation heat baths. Furthermore, the effect of dissipation on the localization of the oscillator in an Ohmic heat bath at zero temperature is shown to differ qualitatively from that without the magnetic field. Finally, we formulate retarded Green's functions and symmetrized position correlation functions for the oscillator, reach some general conclusions, and make explicit calculations for the Ohmic heat bath. For the special case of Brownian motion at both zero and nonzero temperatures, we prove two general asymptotic relations between the retarded Green's functions and the displacement correlation functions, which we use to evaluate the long-time behaviors of the latter from those of the former, for both the Ohmic heat bath and a rather general class of heat baths discussed extensively in the literature.
We consider a model of non-Markovian quantum Brownian motion that consists of a harmonic oscillator bilinearly coupled to a thermal bath, both via its position and via its momentum operators. We derive the master equation for such a model, and we solve the equations of motion for a generic Gaussian system state. We then investigate the resulting evolution of the first and second moments for both an Ohmic and a super-Ohmic spectral density. In particular, we show that, irrespective of the specific form of the spectral density, the coupling with the momentum enhances the dissipation experienced by the system, accelerating its relaxation to the equilibrium as well as modifying the asymptotic state of the dynamics. Eventually, we characterize explicitly the non-Markovianity of the evolution using a general criterion which relies on the positivity of the master equation coefficients.
The motion of a free quantum particle in a thermal environment is usually described by the quantum Langevin equation, where the effect of the bath is encoded through a dissipative and a noise term, related to each other via the fluctuation dissipation theorem. The quantum Langevin equation can be derived starting from a microscopic model of the thermal bath as an infinite collection of harmonic oscillators prepared in an initial equilibrium state. The spectral properties of the bath oscillators and their coupling to the particle determine the specific form of the dissipation and noise. Here we investigate in detail the well-known Rubin bath model, which consists of a one-dimensional harmonic chain with the boundary bath particle coupled to the Brownian particle. We show how in the limit of infinite bath bandwidth, we get the Drude model, and a second limit of infinite system-bath coupling gives the Ohmic model. A detailed analysis of relevant equilibrium correlation functions, such as the mean squared displacement, velocity autocorrelation functions, and response function are presented, with the aim of understanding the various temporal regimes. In particular, we discuss the quantum-to-classical crossover time scales where the mean square displacement changes from a ∼lnt to a ∼t dependence. We relate our study to recent work using linear response theory to understand quantum Brownian motion.
This article discusses the numerical result predicted by the quantum Langevin equation of the generalized diffusion function of a Brownian particle immersed in an Ohmic quantum bath of harmonic oscillators. The time dependence of the standard deviation of the reduced Wigner function of the system, obtained by integrating the whole function in the momentum space, is determined as well. The complexity of the equations leads to resort to a much simpler calculation based in the position correlation function. They are done for the three possible regimes of the system, namely, periodic, aperiodic, and overdamped. It is found in the periodic case that the generalized diffusion is a discontinuous function exhibiting negative values during short time periods of time. This counterintuitive result, found theoretically in other systems and waiting for its experimental confirmation, can be perfectly explained in the framework of the quantum Langevin equation. Its oscillatory behavior is primordially due to the response to the external field while its quantum origin contributes only in its magnitude. The results are compared to those of the continuum limit which exhibits similar behavior.
We generalize the classical theory of Brownian motion so as to reckon with non-Markovian effects on both Klein-Kramers and Smoluchowski equations. For a free particle and a harmonic oscillator, it is shown that such non-Markovian effects account for the differentiability of the Brownian trajectories as well as the breakdown of the energy equipartition of statistical mechanics at short times in some physical situations. This non-Markovian approach is also extended to look at anomalous diffusion. Next, we bring in the dynamical-quantization method for investigating open quantum systems, which does consist in quantizing the classical Brownian motion starting directly from our non-Markovian Klein-Kramers and Smoluchowski equations, without alluding to any model Hamiltonian. Accordingly, quantizing our non-Markovian Klein-Kramers in phase space gives rise to a non-Markovian quantum master equation in configuration space, whereas quantizing our non-Markovian Smoluchowski equation in configuration space leads to a non-Markovian quantum Smoluchowski equation in phase space. In addition, it is worth noticing that non-Markovian quantum Brownian motion takes place in presence of a generic environment (e.g. a non-thermal quantum fluid). As far as the special case of a heat bath comprising of quantum harmonic oscillators is concerned, a non-Markovian Caldeira-Leggett master equation and a thermal quantum Smoluchowski equation are derived and extended to bosonic and fermionic heat baths valid for all temperatures.
Abstract This review provides a brief and quick introduction to the quantum Langevin equation for an oscillator, while focusing on the steady-state thermodynamic aspects. A derivation of the quantum Langevin equation is carefully outlined based on the microscopic model of the heat bath as a collection of a large number of independent quantum oscillators, the so-called independent-oscillator model. This is followed by a discussion on the relevant ‘weak-coupling’ limit. In the steady state, we analyze the quantum counterpart of energy equipartition theorem which has generated a considerable amount of interest in recent literature. The free energy, entropy, specific heat, and third law of thermodynamics are discussed for one-dimensional quantum Brownian motion in a harmonic well. Following this, we explore some aspects of dissipative diamagnetism in the context of quantum Brownian oscillators, emphasizing upon the role of confining potentials and also upon the environment-induced classical-quantum crossover. We discuss situations where the system-bath coupling is via the momentum variables by focusing on a gauge-invariant model of momentum-momentum coupling in the presence of a vector potential; for this problem, we derive the quantum Langevin equation and discuss quantum thermodynamic functions. Finally, the topic of fluctuation theorems is discussed (albeit, briefly) in the context of classical and quantum cyclotron motion of a particle coupled to a heat bath.