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arXiv:2606.03272

How long can a non-spherical quantum object remain standing ? - a fundamental quantum question -

Takaharu Otsuka, Yusuke Tsunoda

Published Jun 2, 2026• 0 citations
arXivHTMLPDF

Abstract

An isolated quantum system generally exhibits rotational symmetry, i.e., conserved spin (angular momentum) in its eigenstates. Non-spherical quantum objects such as many of molecules and atomic nuclei are not exceptions. However, these objects are not rotationally invariant by definition. Such an object therefore restores, as a consequence of the action of Hamiltonian, the rotational symmetry by superposing states of the same object orienting in different directions, where each component represents one direction. We show the time evolution of an individual component of this superposition: this component remains almost unchanged for finite time, called standing time. This implies that if the object is found to be in this component, it basically remains so for the standing time. This feature is shown to be relevant in a variety of cases, such as atomic nuclei, polymers (proteins), and electron drops in atoms. The shapes of many nuclei are ellipsoids with variations. The "viewing" of the ellipsoidal shape is not straightforward, because this ellipsoid is not at rest. A "snapshot" of a nucleus is highly desired as a direct information. Recent experimental approaches with Relativistic Heavy-ion Collision (RHC) are promising for taking such a snapshot. The present work depicts that the standing time, some 10^{-23} sec for typical ellipsoidal nuclei, is much longer than the time scale of RHC, some 10^{-25} sec. This implies that an ellipsoidal nucleus remains practically unchanged for this critical period. As the standing time will be intimately related, through a relation like the energy-time uncertainty relation, to the energy scales involved, we can also explore this concept and its applications in a variety of physical cases such as fusion (tunneling process), fission, alpha-decay/emission, polymers and electron drop in atom.

DOI
10.48550/arxiv.2606.03272

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An isolated quantum system generally exhibits rotational symmetry, i.e., conserved spin (angular momentum) in its eigenstates. Non-spherical quantum objects such as many of molecules and atomic nuclei are not exceptions. However, these objects are not rotationally invariant by definition. Such an object therefore restores, as a consequence of the action of Hamiltonian, the rotational symmetry by superposing states of the same object orienting in different directions, where each component represents one direction. We show the time evolution of an individual component of this superposition: this component remains almost unchanged for finite time, called standing time. This implies that if the object is found to be in this component, it basically remains so for the standing time. This feature is shown to be relevant in a variety of cases, such as atomic nuclei, polymers (proteins), and electron drops in atoms. The shapes of many nuclei are ellipsoids with variations. The "viewing" of the ellipsoidal shape is not straightforward, because this ellipsoid is not at rest. A "snapshot" of a nucleus is highly desired as a direct information. Recent experimental approaches with Relativistic Heavy-ion Collision (RHC) are promising for taking such a snapshot. The present work depicts that the standing time, some 10^{-23} sec for typical ellipsoidal nuclei, is much longer than the time scale of RHC, some 10^{-25} sec. This implies that an ellipsoidal nucleus remains practically unchanged for this critical period. As the standing time will be intimately related, through a relation like the energy-time uncertainty relation, to the energy scales involved, we can also explore this concept and its applications in a variety of physical cases such as fusion (tunneling process), fission, alpha-decay/emission, polymers and electron drop in atom.
Quantization of spin and orbital angular momenta in standard quantum mechanics is rooted in the fundamental rotational symmetry of space in conjunction with the results of experiments on atomic and subatomic particles conducted with the Stern-Gerlach apparatus. We explain some of the most important features of spin and orbital angular momenta as inescapable consequences of elementary Stern-Gerlach experiments viewed in light of the rotational symmetry of space. The rotation operator is first derived for spin-½ particles, then extended to spin-1 particles by treating the case of a hydrogen atom in its ground state, where the spin of the proton combines with that of the electron to create a spin-1 triplet state. Along the way, we examine the evolution of a particle’s spin state under an applied magnetic field, where the interaction energy arises from the existence of a magnetic dipole moment for each particle in proportion to its spin angular momentum. Whereas a constant magnetic field B0 causes the particle’s magnetic moment to gyrate around the direction of B0, it will be seen that the presence of a small oscillating magnetic field perpendicular to B0 brings about the so-called Rabi oscillations, which involve periodic flippings of the particle’s spin orientation. In the case of a hydrogen atom in its ground state, the interaction between the magnetic dipole moments of the proton and the electron splits the ground state between a lower energy singlet having a net angular momentum of zero (spin-0 state), and a higher energy triplet having a total angular momentum of ħ (spin-1 state). This hyperfine splitting is the source of the well-known 21-cm line observed in the spectrum of the hydrogen atom, which arises from transitions between the atom’s singlet and triplet states. In the final section, we put forward an argument (originally made by Richard Feynman) that ties the rotational symmetry of space to the conservation of angular momentum in quantum mechanics. The argument is, in fact, quite general, enabling one to deduce other conservation laws from various inherent symmetries of quantum mechanical systems.
This chapter focuses on the concept of rotational motion. It explains that energy and angular momentum for a particle rotating in two- or three-dimensions are quantized and satisfied cyclic boundary conditions, which imply the quantization of angular momentum's magnitude and z-component. The electronic structure of atoms showcases rotational motion because electrons orbit around nuclei and spin on their axis. The chapter details the solutions for the Schrödinger equation and the vector model of angular momentum. It also discusses the concept of space quantization revolving around the quantum mechanical result of a rotating body that may not take up an arbitrary orientation concerning some specified axis.
The quantum mechanics is most easily started from the experimentally observed discrete energy states of bound particles. The free particle may take on any energy whatever, which makes the quantum description of a free particle more awkward conceptually and mathematically than the quantum description of a bound particle. The construction of moving quantum spatial probabilities will require a superposition of stationary state wave functions of different energies. Any coherent superposition of energy eigen states for a particle represents a possible quantum state of that particle. The most important property of the spatial probability function for superposed energy states is that it changes with time. A moving probability that is limited spatially is called a packet and the corresponding quantum-mechanical description is called a packet state. The free-particle packet states examples satisfy the position-momentum uncertainty relation. Probably the most important application of the energy time uncertainty relation concerns the lifetimes of the excited states of atoms and nuclei.
The purpose of this contribution was to evaluate a recently published atom model for Helium, characterized by a double rotation of the electrons which exhibit perpendicular rotation axes. Thereby, each rotation is induced by the spin of one electron [1]. Hereto, a tangible mechanical model was used which facilitated to derive the mathematical formulae as the basics for two-dimensional projections, and—not least—for a digital animation yielding freeze images from different perspectives. The resulting shape of the electron shell turned out to be not spherical. In particular, the total velocity of the electrons is variable since the relative running direction may change—in contrast to the initial assumption—, even leading to an intermittent standstill, and implying a variable kinetic energy. Thus it can be concluded that this model describes a rotating rotor but not the Helium atom, and that it must be abandoned.
Following our preceding work on spherical and linear rotors [C. Stopera and J. A. Morales, J. Chem. Phys. 152, 134112 (2020)], we reformulate an earlier rotational coherent state (CS) set to obtain a temporally stable (TS) CS set for symmetric rotors. Being TS, the new CSs remain within its own set during dynamics by evolving exclusively through their parameters. The TS CS set is now appropriate to reconstruct quantum rotational properties from classical-mechanics simulations of chemical reactions. Following literature precedents, we enforce temporal stability by incorporating action-angle-related phase factors into two parameters of the original CS set. Proofs and final expressions of the symmetric-rotor CS turn out more intricate than those of its spherical-rotor counterpart. We demonstrate and examine the key properties of the new CS set: continuity, resolution of unity, temporal stability, action identity, minimum uncertainty relationships, and quasi-classical behavior. Regarding the last property, we demonstrate that the body-fixed z-component of the CS angular momentum average evolves exactly as its classical counterpart, and that the x- and y-components display an astonishing analogy with their classical counterparts in terms of functional form, precession angular velocities, amplitudes, and phases. We elucidate some of these properties via computer simulations of a rotating benzene molecule represented with the CS set. We discuss the utilization of this CS set to reconstruct quantum rotational properties of symmetric-rotor molecules from classical-mechanics simulations. The new CS set is appropriate to establish quantum-classical connections for rotational properties in chemical dynamics, statistical mechanics, spectroscopy, nuclear physics, and quantum computing.
A variational derivation of the Liouville-von Neumann equation of quantum-statistical mechanics is presented, in order to formulate mean~field approximations appropriate to mixed states. The Hartree-Fock and the RPA at finite temperatures are particular cases of the general formalism. A thennal boson expansion is defined, which allows us to describe anhannonic motion around a thennal excited state. In a numerical application on the basis of the Lipkin model, temperature-dependent phase transitions are observed. I. Introduction Studies of the decay of the compound nuclei formed in heavy-ion reactions have added a new dimension to the field of nuclear structure. The temperature of the compound nucleus at a given excitation energy rises from zero at the yrast state to a few MeV at angular momentum zero. Recently the decay of high-excited states above the yrast line, like the giant dipole resonance, has been observed 1,2). These measurements were carried out making use of sum-spectrometer multiplicity techniques, thus allowing to determine the average angular momentum of the system and from this knowledge the temperature of the nucleus. One can then study experimentally the nuclear structure at finite values of both the angular momentum and temperature, and the corresponding theoretical analysis of giant resonances above thermal excited states is now the object of intensive research 3-7). On the other hand, the observation of deep-inelastic reactions has been an important sourCe of information on the behaviour of nuclei under strong external fields. In these reactions the two interacting ions emerge after the collision with approximatley the same charge and mass, but having lost a large fraction of the energy and angular momentum of relative motion they had in the entrance channel (cf. e.g. ref. 8) and references therein). Different mechanisms play a role in these reactions, like the transfer of particles and the excitation of giant resonances (cf. ref. 9) and references therein). Because these vibrations have a damping width the energy and angular momentum absorbed through them into the nuclei lead to a finite temperature and to rigid rotation. This