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arXiv:2606.00877

Topological Edge States from Molecular Chirality: A General Framework for Dimerized Dipolar Arrays

Muhammad Arsalan Ali Akbar, Mohsin Raza, Sabre Kais

quant-phcond-mat.mtrl-sciphysics.app-phphysics.atm-clusSubmitted May 30, 2026• Announced Jun 2, 2026
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Abstract

We establish a general theoretical framework for realizing topological edge states in dimerized arrays of chiral dipolar molecules and demonstrate that molecular handedness provides a natural and tunable route to SSH-like topology in an interacting one-dimensional setting. Starting from an effective spin-$\tfrac{1}{2}$ model generated by Stark-dressed chiral molecules, we introduce bond dimerization and show that the chirality-induced Dzyaloshinskii--Moriya interaction amplifies the effective hopping amplitudes and enlarges the bulk topological gap relative to an achiral chain of equivalent dipole strength. Using self-consistent mean-field theory with periodic- and open-boundary calculations, we map out the trivial, critical, and topological regimes through bulk spectra, complex-plane winding, and boundary-localized probability densities. A central result is that the two in-gap boundary modes carry \emph{opposite molecular chirality}: the left edge state localizes on a left-handed molecule and the right edge state on a right-handed molecule, a stereochemical labeling with no analogue in conventional SSH implementations. The two-leg ladder extension supports a richer four-band bulk structure and a rung-split edge sector whose robustness is characterized by a continuous sweep of the interchain coupling. All results are expressed in dimensionless units of the reference hopping scale $t_0$, making the framework directly applicable to any dipolar molecular platform -- from bialkali polar molecules at MHz coupling scales to future arrays of ultracold chiral polyatomic species. These findings establish dimerized chiral molecular arrays as a controllable and chirality-addressable platform for quasi-one-dimensional topological quantum matter.

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Topological edge states at Floquet quantum criticality

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Topologically protected edge states exactly at topological phase boundaries challenge the conventional belief that topological states must be associated with a bulk energy gap. Because periodically driven (Floquet) systems host unusually intricate topological phase boundaries, topological edge states can be prolific at such Floquet quantum criticality. Working on a class of chiral-symmetric, Floquet-driven Majorana fermion chains, we analytically and computationally show that the precise boundaries between different Floquet topological gapped phases can accommodate topological edge modes, including the so-called critical Majorana π modes. We also identify a general bulk-edge correspondence formula to predict and understand the emergence of topological edge modes at Floquet quantum criticality. Of direct interest to quantum simulation experiments, our work opens an avenue for exploring topological physics intrinsic to nonequilibrium phase boundaries. The authors develop a theoretical framework to characterize the topology and edge states at the nonequilibrium critical points of periodically driven (Floquet) quantum systems. The rule of bulk-edge correspondence applicable to both gapped and gapless Floquet topological phases in 1D chiral symmetric driven systems is proposed.

arXiv:2410.15395•Communications Physics•May 22, 2025•22 citations
We establish a general theoretical framework for realizing topological edge states in dimerized arrays of chiral dipolar molecules and demonstrate that molecular handedness provides a natural and tunable route to SSH-like topology in an interacting one-dimensional setting. Starting from an effective spin-12\tfrac{1}{2}21​ model generated by Stark-dressed chiral molecules, we introduce bond dimerization and show that the chirality-induced Dzyaloshinskii--Moriya interaction amplifies the effective hopping amplitudes and enlarges the bulk topological gap relative to an achiral chain of equivalent dipole strength. Using self-consistent mean-field theory with periodic- and open-boundary calculations, we map out the trivial, critical, and topological regimes through bulk spectra, complex-plane winding, and boundary-localized probability densities. A central result is that the two in-gap boundary modes carry \emph{opposite molecular chirality}: the left edge state localizes on a left-handed molecule and the right edge state on a right-handed molecule, a stereochemical labeling with no analogue in conventional SSH implementations. The two-leg ladder extension supports a richer four-band bulk structure and a rung-split edge sector whose robustness is characterized by a continuous sweep of the interchain coupling. All results are expressed in dimensionless units of the reference hopping scale t0t_0t0​, making the framework directly applicable to any dipolar molecular platform -- from bialkali polar molecules at MHz coupling scales to future arrays of ultracold chiral polyatomic species. These findings establish dimerized chiral molecular arrays as a controllable and chirality-addressable platform for quasi-one-dimensional topological quantum matter.
We propose a robust platform for simulating chiral quantum magnetism using linear arrays of trapped asymmetric top molecules, specifically 1,2-propanediol (C3H8O2\mathrm{C_{3}H_{8}O_{2}}C3​H8​O2​). By mapping the Stark-dressed rotational states onto an effective spin-1/21/21/2 subspace, we rigorously derive a generalized XXZXXZXXZ Heisenberg Hamiltonian governing the underlying many-body dynamics. Unlike standard solid-state models where the topological Dzyaloshinskii-Moriya Interaction (DMI) is introduced phenomenologically, we demonstrate that DMI emerges \textit{ab initio} from the molecular stereochemistry. Specifically, the interference between the transition dipole moments of heterochiral enantiomer pairs (L-R), which breaks inversion symmetry, generates a tunable DMI that stabilizes a Chiral Luttinger Liquid phase. Through a comprehensive phase-diagram analysis, we identify an optimal experimental regime characterized by intermolecular separations of r≈1.5 nm r \approx 1.5~\mathrm{nm} r≈1.5 nm and intermediate electric-field strengths dε/B≈2.5 d\varepsilon/B \approx 2.5 dε/B≈2.5. In this window, the system is protected from trivial field-polarized phases and exhibits a robust gapless spin-spiral texture. Our results establish 1,2-propanediol arrays as a versatile quantum simulator, providing a direct microscopic link between molecular chirality and topological many-body phases.
The recent experimental realization of optical tweezer arrays of ultracold molecules provides a versatile platform for exploring molecular phases of matter. Here we show that by programming tweezers, the dipolar interactions in an optical tweezer ladder could be tailored to implement a generalized Su-Schrieffer-Heeger model. Through calculating topological invariants, nonlocal string-order parameters, many-particle ground-state degeneracy, and entanglement spectrum, we demonstrate that this ladder at the single-particle level supports two different chiral topological phases and at the many-particle level features two different interacting topological phases and, respectively, possesses much richer topological edge states. We also discuss the detection of these topological phases and their robustness to systematic imperfections. Further generalization to a high dimension could offer opportunities for preparing diverse ultracold molecular topological phases.
We investigate the topological properties of one-dimensional weakly interacting topological insulators using bosonization. To do that we study the topological edge states that emerge at the edges of a model realized by a strong impurity or at the boundary between topologically distinct phases. In the bosonic model, the edge states are manifested as degenerate bosonic kinks at the boundaries. We first illustrate this idea on the example of the interacting Su-Schrieffer-Heeger (SSH) chain. We compute the localization length of the edge states as the width of an edge soliton that occurs in the SSH model in the presence of a strong impurity. Next, we examine models of two capacitively coupled SSH chains that can be either identical or in distinct topological phases. We find that weak Hubbard interaction reduces the ground-state degeneracy in the topological phase of identical chains. We then prove that, similarly to the noninteracting model, the degeneracy of the edge states in the interacting case is protected by chiral symmetry. We then study topological insulators built from two SSH chains with interchain hopping that represent models of different chiral symmetric universality classes. We demonstrate in bosonic language that the topological index of a weakly coupled model is determined by the type of interchain coupling, invariant under one of two possible chiral symmetry operators. Finally, we show that a general one-dimensional model in a phase with topological index $\ensuremath{\nu}$ is equivalent at low energies to a theory of at least $\ensuremath{\nu}$ SSH chains. We illustrate this idea on the example of an SSH model with longer-range hopping.
The realization and detection of topological phases with ultracold atomic gases is at the frontier of current theoretical and experimental research. Here, we identify cold atoms in optical ladders subjected to synthetic magnetic fields as readily realizable bridges between one-dimensional spin-orbit (time-reversal) topological insulators and two-dimensional quantum Hall insulators. We reveal three instances of their promising potential: (i) they realize spin-orbit coupling, with the left-right leg degree of freedom playing the role of an effective spin, (ii) their energy bands and eigenstates exactly reproduce the topological chiral edge modes of two-dimensional Chern insulators, and (iii) they can be tailored to realize a topological phase transition from a trivial to a topological insulating phase. We propose realistic schemes to observe the chiral and topological properties of ladder systems with current optical lattice-based experiments. Our findings open a door to the exploration of the physics of the edges of quantum Hall insulators and to the realization of spin-orbit coupling and topological superfluid phases with ultracold atomic gases.
Engineering synthetic dimensions, where the physics of additional spatial dimensions is simulated within the internal states of a quantum system, allows the realisation of phenomena not otherwise accessible in experiments. Ultracold ground-state polar molecules are an ideal platform to encode synthetic dimensions, offering access to large Hilbert spaces of long-lived internal states associated with the rotational and hyperfine degrees of freedom, that can be coupled together with microwave fields to simulate tunnelling. Here, to benchmark the advantages of ultracold molecules, we encode a 1D synthetic lattice in the rotational states of ultracold RbCs molecules and use it to investigate the well-known Su-Schrieffer-Heeger (SSH) model, a minimal model displaying topological properties. To probe the system, we perform spectroscopy using an auxiliary rotational state and study the time dynamics after deterministic state preparation. We demonstrate long coherence times, typically ~500 times the lattice tunnelling period, even for a synthetic lattice using 8 rotational states. Observations of dynamics at long times with full site-resolved readout of the synthetic dimension allow us to test the effects of chiral and non-chiral perturbations on the topologically protected edge states. Our work lays the foundation for further quantum simulations using the rich internal structure of molecules, including dipolar string phases in interacting samples of molecules, and adiabatic state preparation of many-body Hamiltonians.
Topologically protected edge states exactly at topological phase boundaries challenge the conventional belief that topological states must be associated with a bulk energy gap. Because periodically driven (Floquet) systems host unusually intricate topological phase boundaries, topological edge states can be prolific at such Floquet quantum criticality. Working on a class of chiral-symmetric, Floquet-driven Majorana fermion chains, we analytically and computationally show that the precise boundaries between different Floquet topological gapped phases can accommodate topological edge modes, including the so-called critical Majorana π modes. We also identify a general bulk-edge correspondence formula to predict and understand the emergence of topological edge modes at Floquet quantum criticality. Of direct interest to quantum simulation experiments, our work opens an avenue for exploring topological physics intrinsic to nonequilibrium phase boundaries. The authors develop a theoretical framework to characterize the topology and edge states at the nonequilibrium critical points of periodically driven (Floquet) quantum systems. The rule of bulk-edge correspondence applicable to both gapped and gapless Floquet topological phases in 1D chiral symmetric driven systems is proposed.