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arXiv:2605.27637

Projection operator onto spin-S eigenspaces of total and orbital angular momenta

M. I. Krivoruchenko

nucl-thquant-phSubmitted May 26, 2026• Announced May 28, 2026• 0 citations
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Abstract

The Frobenius covariant is used to construct a projection operator onto the spin-S eigenspaces associated with the squares of the total and orbital angular momenta. The covariant admits two equivalent representations: as a polynomial in powers of the scalar product of the spin and orbital angular momentum operators, and as a finite expansion in terms of their respective polarization operators. A correspondence is established with Villars' angular momentum projection, used in nuclear structure studies.

Journal reference
Pis'ma v Zh. Eksp. Teor. Fiz. 124, 166-170 (2026)
Comments
4 pages

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The Frobenius covariant is used to construct a projection operator onto the spin-S eigenspaces associated with the squares of the total and orbital angular momenta. The covariant admits two equivalent representations: as a polynomial in powers of the scalar product of the spin and orbital angular momentum operators, and as a finite expansion in terms of their respective polarization operators. A correspondence is established with Villars' angular momentum projection, used in nuclear structure studies.
The Frobenius covariant is used to construct a projection operator onto the spin-S eigenspaces associated with the squares of the total and orbital angular momenta. The covariant admits two equivalent representations: as a polynomial in powers of the scalar product of the spin and orbital angular momentum operators, and as a finite expansion in terms of their respective polarization operators. A correspondence is established with Villars’ angular momentum projection, used in nuclear structure studies.
Formulas are obtained which give the matrix representation, relative to a product basis, of the projection operator for the total angular momentum of a system. If the individual angular momenta are not too large, the matrix elements depend upon a small number of parameters, independent of the number of angular momenta coupled. Recurrence relations between elements and symmetry properties of elements are derived. These results enable one to perform the vector coupling of a large number of angular momenta in a relatively simple fashion. The connection between the matrix elements and vector coupling coefficients is discussed. Several important special cases are treated in detail.
Synopsis: General operator properties of angular momenta are recalled, and a physical motivation for adding them is given. The product and total angular momentum bases are defined. It is shown how to express one basis in terms of the other, and an explicit example of adding two spin 1/2 angular momenta is given. A further example consists of adding a general orbital angular momentum value to spin 1/2. These considerations are applied to perturbations in the hydrogen atom energy spectrum, where the correct choice for calculations is the total angular momentum basis.
Synopsis: General operator properties of angular momenta are recalled, and a physical motivation for adding them is given. ƒe product and total angular momentum bases are defined. It is shown how to express one basis in terms of the other, and an explicit example of adding two spin 1/2 angular momenta is given. A further example consists of adding a general orbital angular momentum value to spin 1/2. ƒese considerations are applied to perturbations in the hydrogen atom energy spectrum, where the correct choice for calculations is the total angular momentum basis.
The conventional method of constructing wave functions of pure angular momentum for a composite system is based on the idea of coupling the angular momenta of the constituents. Instead of this synthetic method, an analytical approach is here introduced. It is pointed out that an arbitrary trial wave function for the total system in a unique way must be resolvable into orthogonal components of pure angular momentum associated with different quantum numbers. A particular component can be selected by means of certain 'projection operators', which annihilate all components except the one desired. Such a projection operator is simply a product of commuting factors, each one of which annihilates a specific eigenfunction to the angular momentum under consideration. Physically this idea is of importance, since one can now start out from a rough model wave function based essentially on qualitative arguments, for instance of the independent-particle type, and then obtain a mathematically and physically much better trial function by selecting the particular component of the original function which has the correct symmetry type desired. The projection operators are studied in some detail both as products and in expanded form. The case of degenerate subspaces of the same angular momentum quantum numbers is discussed, and the problem of constructing an orthogonal subset of functions is solved by a simple elimination procedure; the connection with the conventional seniority idea is briefly discussed.