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arXiv:2605.04588

Single-photon scattering by a giant molecule asymmetrically coupled to parallel waveguides

Ze-Quan Zhang, Guang-Zheng Ye, Wei-Xin Chen, Yong Li, Huaizhi Wu

quant-phSubmitted May 6, 2026• Announced May 7, 2026• 0 citations
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Abstract

We investigate single-photon scattering in a waveguide-QED setup, where a giant molecule composed of two frequency-detuned giant atoms is coupled to two parallel waveguides via multiple connection points. The competition between coherent atom--atom coupling and the effective decay rates dictates the splitting of a single resonance into a doublet in the transmission (reflection) spectra. By tailoring the asymmetry of the decay rates and the atomic detuning, one can engineer photon-path interference to optimize the transfer between waveguides; under chiral coupling conditions, this interference can be further harnessed to realize fully deterministic routing. In the non-Markovian regime, retardation effects can reshape the spectra and actively drive transitions between the weak- and strong-coupling regimes, converting an unsplit Markovian resonance into a clearly separated doublet, or conversely merging a split doublet back into a single resonance. For sufficiently long time delays, it further generates multiple resonances and avoided crossings, enriching the spectral response. Our results demonstrate how atomic detuning, decay-rate asymmetry, and non-Markovian retardation cooperate to provide versatile, interference-based control over single-photon routing in multi-port quantum networks.

Comments
12 pages, 7 figures

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We investigate single-photon scattering in a waveguide-QED setup, where a giant molecule composed of two frequency-detuned giant atoms is coupled to two parallel waveguides via multiple connection points. The competition between coherent atom--atom coupling and the effective decay rates dictates the splitting of a single resonance into a doublet in the transmission (reflection) spectra. By tailoring the asymmetry of the decay rates and the atomic detuning, one can engineer photon-path interference to optimize the transfer between waveguides; under chiral coupling conditions, this interference can be further harnessed to realize fully deterministic routing. In the non-Markovian regime, retardation effects can reshape the spectra and actively drive transitions between the weak- and strong-coupling regimes, converting an unsplit Markovian resonance into a clearly separated doublet, or conversely merging a split doublet back into a single resonance. For sufficiently long time delays, it further generates multiple resonances and avoided crossings, enriching the spectral response. Our results demonstrate how atomic detuning, decay-rate asymmetry, and non-Markovian retardation cooperate to provide versatile, interference-based control over single-photon routing in multi-port quantum networks.
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We investigate the single-photon scattering spectra in a giant-molecule waveguide quantum electrodynamics system, where a giant molecule consisting of two coupled giant atoms is connected to two waveguides via two separate sites, respectively. The phases of coupling strengths between the giant molecule and waveguides are considered. Using a real-space method, we obtain the exact analytical expressions for the single-photon scattering coefficients, which are valid both in the Markovian and non-Markovian regimes. It is shown that the transmission spectra strongly depend on phases, including the phases accumulated by photons traveling between coupling points and the phase difference between two coupled channels of the giant-molecule upper (lower) waveguide. Under the Markovian limit, we find that by selecting appropriate accumulated phases and local phase difference, targeted routing and asymmetrical scattering of photons can be achieved without breaking the symmetry in the coupling configuration between the giant molecule and waveguides. Moreover, all the optimal phase combinations for implementing single-photon routing have been summarized. In the non-Markovian regime, the scattering spectra show more complicated line shapes with multiple staggered peaks and dips. More interestingly, the scattering spectrum exhibits periodic changes during the transition from the Markovian to the non-Markovian regime, which makes one obtain a means to control photon routing in addition to phases. Our results may be useful in controlling and manipulating light-matter interactions involving giant atoms at the single-photon level.
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We study the coherent single-photon scattering in a one-dimensional waveguide coupled to a giant artificial molecule consisting of two coupled giant atoms. Since each giant atom couples to the waveguide via two coupling points, the couplings of the molecule with the waveguide have three different coupling configurations: the separated-, braided-, and nested-coupling cases. We obtain the exact expressions of the single-photon transmission and reflection amplitudes with the real-space approach. It is found that the behavior of the scattering spectra depends on the phase shift between two neighboring coupling points, the coupling configuration, and the coupling between the two giant atoms. Concretely, we study the photon scattering in both the Markovian and non-Markovian regimes, in which the photon propagating time between two neighboring coupling points is neglected and considered, respectively. Under the Markovian limit, the asymmetric Fano line shapes in different coupling configurations of the giant-molecule waveguide-QED system can be obtained by choosing proper phase shift, and the transmission window can be adjusted by the coupling strength between the two giant atoms in these three coupling configurations. In particular, multiple reflection peaks and dips in these configurations are revived in the non-Markovian regime. This paper will pave the way for the study of controllable single-photon devices based on the giant-molecule waveguide-QED systems.
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