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arXiv:2604.27749

Timescales for Deep and Full Thermalization

Tabea Herrmann, Felix Fritzsch, Arnd Bäcker

quant-phcond-mat.stat-mechSubmitted Apr 30, 2026• Announced May 1, 2026• 0 citations
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Abstract

Isolated quantum systems typically approach thermal equilibrium as described by the Eigenstate Thermalization Hypothesis (ETH). Going beyond this involves either higher order correlators (full thermalization) or the formation of state designs, i.e., the approach of moments of state ensembles after a projective measurement towards thermal equilibrium (deep thermalization). We compare these two extensions of ETH using extensive numerical studies within a paradigmatic model for chaotic many-body quantum dynamics. For this we find exponential relaxation for both extensions: For deep thermalization all moments relax with the same rate, which approximately equals the relaxation rate of the autocorrelation function captured by ETH. In contrast, higher order correlation functions in full thermalization approach equilibrium faster. This means that at higher orders full thermalization is faster than deep thermalization.

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Isolated quantum systems typically approach thermal equilibrium as described by the Eigenstate Thermalization Hypothesis (ETH). Going beyond this involves either higher order correlators (full thermalization) or the formation of state designs, i.e., the approach of moments of state ensembles after a projective measurement towards thermal equilibrium (deep thermalization). We compare these two extensions of ETH using extensive numerical studies within a paradigmatic model for chaotic many-body quantum dynamics. For this we find exponential relaxation for both extensions: For deep thermalization all moments relax with the same rate, which approximately equals the relaxation rate of the autocorrelation function captured by ETH. In contrast, higher order correlation functions in full thermalization approach equilibrium faster. This means that at higher orders full thermalization is faster than deep thermalization.
The Eigenstate Thermalization Hypothesis (ETH) is a standard tool to understand the thermalization properties of an isolated quantum system. Its generalization to higher order correlations of matrix elements of local operators, dubbed the full ETH, relates the ETH free cumulants to the corresponding thermal free cumulants in the thermodynamic limit. In this work, we numerically test the full ETH predictions using exact diagonalization of two integrable spin models: the Ising and the XXZ Heisenberg models. The differences from the behavior predicted by full ETH in chaotic systems are highlighted and contrasted along the way. We further study the out-of-time-ordered correlator (OTOC) through its approximate decomposition into contributions involving the second- and fourth-order ETH free cumulants. We find that, although the fourth-order contribution governs the late-time behavior of the OTOC in these integrable models, its dynamics differs significantly from that found in nonintegrable systems.
The eigenstate thermalization hypothesis (ETH) has been established as the general framework to understand quantum statistical mechanics. Only recently has the attention been paid to so-called full ETH, which accounts for higher-order correlations among matrix elements, and that can be rationalized theoretically using the language of free probability. In this work, we perform the first numerical investigation of the full ETH in physical many-body systems with local interactions by testing the decomposition of higher-order correlators into thermal free cumulants for local operators. We perform exact diagonalization on two classes of local nonintegrable (chaotic) quantum many-body systems: spin chain Hamiltonians and Floquet brickwork unitary circuits. We show that the dynamics of four-time correlation functions are encoded in fourth-order free cumulants, as predicted by ETH. Their dependence on frequency encodes the physical properties of local many-body systems and distinguishes them from structureless, rotationally invariant ensembles of random matrices.
Despite the unitary evolution of closed quantum systems, long-time expectation of local observables are well described by thermal ensembles, providing the foundation of quantum statistical mechanics. A promising route to understanding this quantum thermalization is the eigenstate thermalization hypothesis (ETH), which posits that individual energy eigenstates already appear locally thermal. Subsequent studies have extended this concept to the full ETH, which captures higher-order correlations among matrix elements through nontrivial relations. In this work, we perform a detailed exact-diagonalization study of finite-size corrections to these relations in the canonical ensemble. We distinguish two distinct sources of corrections: those arising from energy fluctuations, which decay polynomially with system size, and those originating from fluctuations within each energy window, which decay exponentially with system size. In particular, our analysis resolves the puzzle that, for certain observables, finite-size corrections exhibit anomalous growth with increasing system size even in chaotic systems. Our results provide a systematic and practical methodology for validating the full ETH in quantum many-body systems.
The eigenstate thermalization hypothesis (ETH) and the theory of linear response (LRT) are celebrated cornerstones of our understanding of the physics of many-body quantum systems out of equilibrium. While the ETH provides a generic mechanism of thermalization for states arbitrarily far from equilibrium, LRT extends the successful concepts of statistical mechanics to situations close to equilibrium. In our work, we connect these cornerstones to shed light on the route to equilibrium for a class of properly prepared states. We unveil that, if the off-diagonal part of the ETH applies, then the relaxation process can become independent of whether or not a state is close to equilibrium. Moreover, in this case, the dynamics is generated by a single correlation function, i.e., the relaxation function in the context of LRT. Our analytical arguments are illustrated by numerical results for idealized models of random-matrix type and more realistic models of interacting spins on a lattice. Remarkably, our arguments also apply to integrable quantum systems where the diagonal part of the ETH may break down.
The Eigenstate Thermalization Hypothesis (ETH) has played a key role in recent advances in the high energy and condensed matter communities. It explains how an isolated quantum system in a far-from-equilibrium initial state can evolve to a state that is indistinguishable from thermal equilibrium, with observables relaxing to almost time-independent results that can be described using traditional statistical mechanics ensembles. In this work we probe the limits of ETH, pushing it outside its prototypical applications in several directions. We design a qutrit lattice system with conserved quasilocal charge, in which we verify a form of generalized eigenstate thermalization. We also observe signatures of thermalization in states well outside microcanonical windows of both charge and energy, which we dub `generic ETH.'
The emergence of statistical mechanics from quantum dynamics is conventionally understood through quantum chaos, the Eigenstate Thermalization Hypothesis (ETH), and canonical typicality, which together explain the thermal behavior of local observables in quantum many-body systems. We provide a distinct mechanism in which, for a quantum many-body system under strong random perturbation, the chaotic behavior of the system's eigenvectors and a constraint on the total energy directly generate a canonical ensemble for the entire system. The canonical ensemble occurs as the first moment of the Porter-Thomas distribution of the system's chaotic eigenstates, and the constraint on the total energy sets the temperature in the ensemble. This yields canonically distributed expectation values without invoking ETH, a microcanonical ensemble, or a subsystem-bath partition for local and global observables. We numerically demonstrate the mechanism for the 1D transverse-field Ising model by showing canonically distributed eigenstate projectors and spin-spin correlators with distinctive temperature dependence of the correlation length. An implementation of this thermalization approach on a quantum computer can be utilized for thermal state preparation.