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arXiv:2604.17412

Theory of Quantum Imaginary-Time Mpemba Effect

Yumeng Zeng, Jeongrak Son, Mile Gu, Xiao Yuan

quant-phSubmitted Apr 19, 2026• Announced Apr 21, 2026• 0 citations
arXivHTMLPDF

Abstract

Quantum imaginary-time evolution (QITE) is a fundamental framework for preparing ground and thermal states, yet its computational cost scales significantly with the evolution duration $τ$. Reducing this duration is critical for practical quantum advantage. Here, we establish a unified theoretical framework for the Mpemba effect in QITE -- a counterintuitive phenomenon where a state initially farther from the ground state relaxes to it faster than one initially closer. We derive a remarkably simple necessary and sufficient condition for the occurrence of this effect, showing it is uniquely determined by the population ratios of excited states to the ground state. For practical state preparation, we introduce a rigorous sufficient condition for the finite-time Mpemba effect, ensuring the crossing occurs before reaching a prescribed proximity threshold. Furthermore, we unveil unique dynamical features, including a multiple-crossing phenomenon in multi-level systems and simultaneous intersections for collinear initial states. Our results provide criteria for identifying favorable initial states in QITE and offer deep insights into the speed limit of quantum state preparation.

Comments
16 pages, 4 figures

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Quantum imaginary-time evolution (QITE) is a fundamental framework for preparing ground and thermal states, yet its computational cost scales significantly with the evolution duration τττ. Reducing this duration is critical for practical quantum advantage. Here, we establish a unified theoretical framework for the Mpemba effect in QITE -- a counterintuitive phenomenon where a state initially farther from the ground state relaxes to it faster than one initially closer. We derive a remarkably simple necessary and sufficient condition for the occurrence of this effect, showing it is uniquely determined by the population ratios of excited states to the ground state. For practical state preparation, we introduce a rigorous sufficient condition for the finite-time Mpemba effect, ensuring the crossing occurs before reaching a prescribed proximity threshold. Furthermore, we unveil unique dynamical features, including a multiple-crossing phenomenon in multi-level systems and simultaneous intersections for collinear initial states. Our results provide criteria for identifying favorable initial states in QITE and offer deep insights into the speed limit of quantum state preparation.
The Mpemba effect refers to the anomalous relaxation of a quantum state that, despite being initially farther from equilibrium, relaxes faster than a closer counterpart. Detecting such a quantum Mpemba effect typically requires full knowledge of the quantum state during its time evolution, which is an experimentally challenging task since state tomography becomes exponentially difficult as system size increases. This poses a significant obstacle in studying Mpemba effect in complex many-body systems. In this work, we demonstrate that this limitation can be overcome by identifying suitable observables that signal rapid relaxation. Moreover, as long as the system equilibrates to a known unique steady-state, it is possible to fully detect the occurrence of quantum Mpemba effect just by measuring the observable for known state preparations. Our approach thus significantly reduces experimental complexity and offers a practical route for observing the quantum Mpemba effect in complex and extended multi-qubit setups.
Various exotic phenomena emerge in nonequilibrium quantum many-body systems. The Mpemba effect, denoting the situation where a hot system freezes faster than a colder one, is a counterintuitive nonequilibrium phenomenon that has attracted enduring interest for more than half a century. In this Letter, we unveil a novel phenomenon of the Mpemba effect in the imaginary-time relaxation dynamics in quantum many-body systems, termed as the imaginary-time Mpemba effect (ITME). We propose a mechanism for the ITME rooted in the initial state's eigenbasis expansion, and we demonstrate its emergence in representative quantum lattice models. Using sign-free quantum Monte Carlo (QMC) simulations, we unequivocally establish the existence of the ITME across diverse interacting quantum systems. Crucially, given the widespread use of imaginary-time dynamics for ground-state calculations, the discovery of the ITME potentially provides a new pathway to accelerate quantum many-body simulations, particularly for QMC methods hindered by the sign problem.
The quantum Mpemba effect refers to the counterintuitive phenomenon in which a system initially farther from equilibrium relaxes faster than one prepared closer to it. Several mechanisms have been identified in open quantum systems to explain this behavior, including the strong Mpemba effect, non-Markovian memory, and initial system-reservoir entanglement. Here, we unveil a distinct mechanism rooted in the non-normal nature of the Liouvillian superoperator in Markovian dynamics. When the Liouvillian's eigenmodes are non-orthogonal, transient interference between decaying modes can induce anomalous early-time behavior-such as delayed thermalization or transient freezing-even though asymptotic decay rates remain unchanged. This differs fundamentally from strong Mpemba effects, which hinge on suppressed overlap with slow-decaying modes. We demonstrate this mechanism using a waveguide quantum electrodynamics model, where quantum emitters interact with the photonic modes of a one-dimensional waveguide. The directional and radiative nature of these couplings naturally introduces non-normality into the system's dynamics. As a result, certain initial states-despite being closer to equilibrium-can exhibit slower relaxation at short times. This work reveals a previously unexplored and universal source of Mpemba-like behavior in memoryless quantum systems, expanding the theoretical framework for anomalous relaxation and opening new avenues for control in engineered quantum platforms.
The quantum Pontus-Mpemba effect (QPME) is a counterintuitive phenomenon wherein a quantum system relaxes more rapidly through a two-step evolution protocol than through direct evolution under a symmetric Hamiltonian alone. In this protocol, the system first evolves under a symmetry-breaking Hamiltonian and then switches to a symmetric one. We demonstrate that QPME occurs under both real-time and imaginary-time dynamics with respect to U(1)U(1)U(1)-symmetry. Using tilted ferromagnetic initial states, we demonstrate that a transient asymmetric evolution significantly accelerates thermalization or convergence to the ground state for both real-time and imaginary-time evolutions, respectively. The effect is pronounced for small tilt angles, while larger tilts or antiferromagnetic initial states suppress it. Numerical evidence across different system sizes confirms the robustness of QPME, demonstrating its stability in the thermodynamic limit. This work extends the framework of nonequilibrium quantum phenomena to incorporate active state preparation, with direct implications for the implementation of quantum simulation.
The quantum Mpemba effect refers to the phenomenon of a quantum system in an initial state, far away from equilibrium, relaxing much faster than a state comparatively nearer to equilibrium. We experimentally demonstrate that this highly counterintuitive effect can occur naturally during the thermalization of quantum systems. Considering dipolar relaxation as the dominant decoherence process, we theoretically derive the conditions that can lead to the Mpemba effect in nuclear spins. After experimentally preparing nuclear spin states dictated by those conditions, we observe the occurrence of the Mpemba effect when they are left to thermalize without any external control. We also experimentally observe the genuine quantum Mpemba effect during thermalization of nuclear spins. Our results establish that both these effects are natural in thermalization of quantum systems, and may show up without the need for any bath engineering.
The quantum Mpemba effect (ME) in Markovian systems is conventionally explained by a smaller overlap between the initial state and the slowest decay mode (SDM). Such state, initially farther away from equilibrium or steady state, relaxes faster than closer ones, resulting to a crossing of their trajectories. This picture, by neglecting the transient dynamics, holds in the long-time limit. Here we experimentally observe multiple trajectory crossings (multi-ME) in the relaxation dynamics of a trapped ion. Such novel dynamics takes place in a unusual scenario where the initial state instead has a larger overlap with the SDM. We develop a theoretical framework based on relaxation speed to understand the multi-ME. We show that the initial relaxation speed is governed by the fastest decay mode, which together with the SDM overlap gives a phase diagram that reveals both the occurrence and the types of quantum ME observed in our experiment. Our study goes beyond the simple picture based on the long-time limit, tracks continuously the quantum ME dynamics, and establishes a comprehensive framework to describe the transient quantum relaxation.