Nanoplasmonic modification of scintillation has so far been explored mainly in the weak-coupling regime, where changes in the local density of optical states enhance radiative recombination via Purcell-type rate engineering. By contrast, strong light-matter coupling generates hybrid states that modify emission dynamics beyond simple decay-rate acceleration, but its implications for scintillator nanocrystals (NCs) under ionizing radiation remain poorly understood. All of these effects are beneficial for near-infrared scintillators, which are typically slow and have low brightness. Here, we present a quantum-optical framework to investigate how near-infrared scintillator NCs coupled to nanoplasmonic antennas evolve from weak coupling toward strong light-matter coupling. We compare broad- and narrow-antenna platforms with single and periodic Au nanorods and benchmark them against conductive plasmonic antennas based on indium tin oxide and graphene. As representative emitters, we consider wide-band PbS NCs and narrow-band cubic Lu2O3:Er3+ scintillators. The calculations show that the onset of strong-coupling signatures is jointly governed by emitter dephasing and the antenna linewidth, with narrow-band emitters coupled to spectrally narrow antennas providing the most favorable conditions. Among the platforms considered, graphene gives the lowest threshold (g = 4 meV) for observable coherent exchange owing to its ultranarrow antenna linewidth (\k{appa} = 3.5 meV). These results identify near-infrared conductive nanoantennas, particularly graphene-based ones, as promising platforms for accessing hybrid scintillation regimes relevant to radiation detection.
Nanoplasmonic modification of scintillation has so far been explored mainly in the weak-coupling regime, where changes in the local density of optical states enhance radiative recombination via Purcell-type rate engineering. By contrast, strong light-matter coupling generates hybrid states that modify emission dynamics beyond simple decay-rate acceleration, but its implications for scintillator nanocrystals (NCs) under ionizing radiation remain poorly understood. All of these effects are beneficial for near-infrared scintillators, which are typically slow and have low brightness. Here, we present a quantum-optical framework to investigate how near-infrared scintillator NCs coupled to nanoplasmonic antennas evolve from weak coupling toward strong light-matter coupling. We compare broad- and narrow-antenna platforms with single and periodic Au nanorods and benchmark them against conductive plasmonic antennas based on indium tin oxide and graphene. As representative emitters, we consider wide-band PbS NCs and narrow-band cubic Lu2O3:Er3+ scintillators. The calculations show that the onset of strong-coupling signatures is jointly governed by emitter dephasing and the antenna linewidth, with narrow-band emitters coupled to spectrally narrow antennas providing the most favorable conditions. Among the platforms considered, graphene gives the lowest threshold (g = 4 meV) for observable coherent exchange owing to its ultranarrow antenna linewidth (\k{appa} = 3.5 meV). These results identify near-infrared conductive nanoantennas, particularly graphene-based ones, as promising platforms for accessing hybrid scintillation regimes relevant to radiation detection.
Near-infrared (NIR) emitters operating in the 650-900 nm range are highly attractive for imaging and sensing in turbid media; however, cadmium-free InP-based quantum dots (QDs) often suffer from limited brightness due to nonradiative pathways and inefficient photon outcoupling. In particular, heterostructured InP QDs can exhibit band alignments that induce partial spatial separation of charge carriers, leading to reduced electron-hole wavefunction overlap. This modifies intrinsic recombination dynamics and enhances the sensitivity of their emission to the surrounding photonic environment. Here, we investigate silver toroidal plasmonic nanoantenna dimers (Ag TPNDs) through finite-difference-time-domain (FDTD) simulations as a geometry-tunable platform for enhancing NIR emission of heterostructured InP-based QDs. The coupled toroidal geometry supports strongly confined bonding modes that generate intense nanogap hotspots, while its resonance can be systematically tuned through the toroid aspect ratio. By spectrally aligning the antenna response with QD emission bands (675-845 nm), we achieve large Purcell enhancements together with high quantum efficiencies, demonstrating efficient conversion of enhanced decay rates into radiative emission. We further show that nanometer-scale variations in emitter-antenna separation strongly modulate the radiative rates and spectral response. These results establish toroidal plasmonic nanodimers as a topology-driven platform for controlling emission in NIR quantum emitters and for advancing NIR nanophotonic applications.
Abstract In the light–matter strong coupling regime, the excited state of quantum emitters is inextricably linked to a photonic mode, leading to hybrid states that are part light and part matter. Recently, there has been a huge effort to realize strong coupling with nanoplasmonics, since it provides a versatile environment to study and control molecules in ambient conditions. Among the most promising designs are plasmonic nanocavities that confine light to unprecedentedly small volumes. Such nanocavities, though, support multiple types of modes, with different field profiles and radiative decay rates (bright and dark modes). Here, we show theoretically that the different nature of these modes leads to mode beating within the nanocavity and the Rabi oscillations, which alters the spatiotemporal dynamics of the hybrid system. By specifically designing the illumination setup, we decompose and control the dark and bright plasmon mode excitation and therefore their coupling with quantum emitters. Hence, this work opens new routes for dynamically dressing emitters, to tailor their hybrid states with external radiation.
Electrically tunable graphene plasmons are anticipated to enable strong light-matter interactions with resonant quantum emitters. However, plasmon resonances in graphene are typically limited to infrared frequencies, below those of optical excitations in robust quantum light sources and many biologically interesting molecules. Here we propose to utilize near fields generated by the plasmon-assisted nonlinear optical response of nanostructured graphene to resonantly couple with proximal quantum emitters operating in the near infrared. We show that the nonlinear near field produced by a graphene nanodisk can strongly excite and coherently control quantum states in two- and three-level atomic systems when the third harmonic of its plasmon resonance is tuned to a particular electronic transition. In the present scheme, emitter and plasmon resonances are nondegenerate, circumventing strong enhancement of spontaneous emission. We envision potential applications for the proposed nonlinear plasmonic coupling scheme in sensing and temporal quantum control.
Abstract Quantum antennas couple localized quantum emitters to optical modes that can be collected, routed, and used in larger photonic systems. Their performance depends on photon delivery as well as single-photon purity, coherence, and indistinguishability. This Review connects the physics of light-matter interaction with the design of quantum-photonic interfaces. We compare semiconductor quantum dots, color centers, two-dimensional and molecular emitters, and examine plasmonic, dielectric, hybrid, cavity-coupled, and waveguideintegrated antenna architectures. We discuss how emitter position, dipole orientation, spectral matching, and material loss govern radiative enhancement and quenching, then assess performance through efficiency, brightness, photon statistics, and coupling to useful optical modes. Electromagnetic and quantum-optical modeling are considered alongside fabrication, deterministic emitter placement, and experimental characterization. We further examine how arrays and metasurfaces extend control to collective emission and quantum wavefronts, and survey applications in single-photon generation, communication, networking, computing, sensing, imaging, and ranging. Across these settings, rapid decay and strong local fields produce system-level gains only when useful photon delivery improves without compromising quantum-state quality. Low-loss design, spectral stabilization, reproducible integration, and complete photon-budget reporting emerge as priorities for scalable quantum-antenna platforms.
Attempting to implement quantum information related applications utilizing atoms and photons, as they naturally form quantum systems supporting superposition states, hybrid quantum plasmonic systems emerged in the past as a platform to study and engineer light-matter interaction. This platform combines the unrivaled electromagnetic field localization of surface plasmon polaritons, boosting the light-matter coupling rate, with the tremendous integration potential of truly nanoscale structures, and both the significant emission rates of nanoantennas and photonic transmission velocities. In this work, a classical description of surface plasmon polaritons is combined with a light-matter interaction model based on a cavity quantum electrodynamical formalism. The resulting composite semi-classical method, introduced and described in this thesis, provides efficient and versatile means to simulate the dynamical behavior of radiative atomic transitions coupled to plasmonic cavity modes in the weak incoherent coupling regime. Both the emission into the far field and various dissipation mechanisms are included by expanding the model to an open quantum system. The variety of light-matter interaction applications that can be modeled with the outlined method is indicated by the four different exemplary scenarios detailed in the application chapter of this thesis. The classical description of localized surface plasmon polaritons is benchmarked by reproducing the experimental measurements of the molecular fluorescence manipulation through optical nanoantennas in a collaborative effort with experimental partners. Furthermore, in the weak light-matter coupling regime, the potential of achieving a higher nanoantenna functionality and simultaneously realizing more elaborate quantum dynamics is revealed by the three remaining applications. Each pivotally involving a bimodal nanoantenna and demonstrating different quantum optical phenomena, the implementation of cavity radiation mode conversion, non-classical cavity emission statistics, and non-classical cavity emission properties is shown and described in the application chapter.
Abstract Quantum nanophotonics places nanoscale structuring in direct dialogue with photonic quantum information—compressing functionality to the few-nanometre, few-femtosecond frontier while retaining energy efficiency, speed and room-temperature operation. We highlight nanoplasmonic cavity-QED architectures in which extreme mode confinement delivers strong coupling under ambient conditions, enabling ultrafast single-photon emission and near-field multipartite entanglement using industry-grade near-field transducers that nanofocus guided light at practical efficiencies. We set these advances against the arc from early plasmonic cQED proposals and single-emitter Purcell studies to modern time-domain measurements that resolve sub-picosecond polariton/Rabi dynamics—establishing a clear route from concept to device. In parallel, we point to low-loss, high-index Mie resonators whose spectrally sharp electric and magnetic modes afford narrow-band coherent control, filtering and radiation-pattern engineering, and which naturally co-integrate in hybrid metal–dielectric stacks that combine ultrastrong local coupling with low-loss routing and storage. Finally, we discuss quantum nanoplasmonic coherent perfect absorption (qnCPA)—a waveguide-fed, non-perturbing protocol that selectively prepares and protects plasmon–emitter dressed states via dissipation-assisted, unidirectional feeding. Together with macroscopic QED and quantum quasinormal-mode quantization, which regularize open, lossy resonators and clarify when loss can be a resource, these developments chart robust, chip-scale routes to room-temperature quantum technologies.