We report several technical approaches that significantly improve the performance of a vapor-cell atomic electrometer operating in the quasi-DC frequency domain ($\ll$ 1 kHz). With a very small active volume of approximately 11 mm$^3$ inside the vapor cell, we demonstrated a noise floor for electric field (E-field) sensitivity ranging from 0.2 to 7.7 mV/m$\sqrt{\rm Hz}$ for a frequency band of 1--100 Hz. Our work utilizes only a bare vapor cell for electrometry, without any metal parts or electrodes, to ensure minimal distortion of the measured E-field and to minimize the effective sensing volume for high spatial resolution. The E-field-sensitive atomic state (Rydberg state) is excited and read out optically, maximizing the simplicity of the system design and enabling the miniaturization of quasi-DC E-field sensors for potential applications, such as diagnostics of electronics without physical contact, communications in and below the super-low frequency (SLF) band, proximity detection, remote activity surveillance, tracing charge signatures, and research in bioscience and geoscience.
We report several technical approaches that significantly improve the performance of a vapor-cell atomic electrometer operating in the quasi-DC frequency domain (≪ 1 kHz). With a very small active volume of approximately 11 mm3 inside the vapor cell, we demonstrated a noise floor for electric field (E-field) sensitivity ranging from 0.2 to 7.7 mV/mHz for a frequency band of 1--100 Hz. Our work utilizes only a bare vapor cell for electrometry, without any metal parts or electrodes, to ensure minimal distortion of the measured E-field and to minimize the effective sensing volume for high spatial resolution. The E-field-sensitive atomic state (Rydberg state) is excited and read out optically, maximizing the simplicity of the system design and enabling the miniaturization of quasi-DC E-field sensors for potential applications, such as diagnostics of electronics without physical contact, communications in and below the super-low frequency (SLF) band, proximity detection, remote activity surveillance, tracing charge signatures, and research in bioscience and geoscience.
Rydberg-assisted atomic electrometry using alkali-metal atoms contained inside a vacuum environment for detecting external electric fields at frequencies below a few kilohertz has been quite challenging due to the low-frequency electric-field-screening effect that is caused by the alkali-metal atoms adsorbed on the inner surface of the container. We report a very slow electric-field-screening phenomenon with a time scale up to the order of seconds on a rubidium-vapor cell that is made of monocrystalline sapphire. Using this sapphire rubidium-vapor cell with an optically induced, internal bias electric field, we demonstrate vapor-cell-based, low-frequency atomic electrometry that responds to the electric field strength linearly. Limited by the given experimental conditions, this demonstrated atomic electrometer uses an active volume of 11mm3 and delivers a spectral noise floor of around 0.34mV/mHz and a 3-dB low cutoff frequency of around 770 Hz inside the vapor cell. This work investigates a regime of vapor-cell-based atomic electrometry that was seldom studied before, which may enable more applications that use atomic electric-field-sensing technology.
Rydberg-atom electric field sensing has shown great potential from near-DC to THz with state-of-the-art measurement metrics realized in sensitivity, phase extraction, multi-band receptivity, etc. While Rydberg-atom sensors have shown exceptional performance in the GHz regime, low-frequency operation has remained challenging because of electric-field-screening in conventional vapor cells, which suppresses externally applied fields. We overcome this limitation by combining auxiliary modulation and lock-in detection with a paraffin-coated vapor cell, and demonstrate an electrode-free, wideband method for sensing frequencies, ranging from 0.5 Hz to 10 kHz. Our work extends Rydberg-atom sensor range to VLF, ULF, SLF, ELF and sub-ELF frequency bands. In our method, high state-of-the-art sensitivities have been achieved - 819 μV/cm/Hz for 1 Hz, 33 μV/cm/Hz for 10 Hz, 10 μV/cm/Hz for 100 Hz and 2 μV/cm/Hz for 1 kHz.
Fields with frequencies below megahertz are challenging for Rydberg-atom-based measurements, due to the low-frequency electric field screening effect caused by the alkali-metal atoms adsorbed on the inner surface of the container. In this paper, we investigate electric field measurements in the ultralow frequency (ULF), very low frequency (VLF), and low frequency (LF) bands in a Cs vapor cell with built-in parallel electrodes. With optimization of the applied DC field, we achieve high-sensitive detection of the electric field at frequencies of 1 kHz, 10 kHz, and 100 kHz based on the Rydberg-atom sensor, with the minimum electric field strength down to 18.0 μV/cm, 6.9 μV/cm, and 3.0 μV/cm, respectively. The corresponding sensitivity is 5.7 μV/cm/Hz 1/2 , 2.2 μV/cm/Hz 1/2 , and 0.95 μV/cm/Hz 1/2 for the ULF, VLF, and LF fields, which is better than a 1-cm dipole antenna. Besides, the linear dynamic range of the Rydberg-atom sensor is over 50 dB. This work presents the potential to enable more applications that utilize atomic sensing technology in the ULF, VLF, and LF fields.
We demonstrate the measurement of super low-frequency electric field using Rydberg atoms in an atomic vapor cell with inside parallel electrodes, thus overcoming the low-frequency electric-field-screening effect at frequencies below a few kHz. Rydberg electromagnetically induced transparency (EIT) spectra involving 52 D 5/2 state is employed to measure the signal electric field. An auxiliary DC field is applied to improve the sensitivity. A DC Stark map is demonstrated, where the utilized 52 D 5/2 exhibits m j = 1/2, 3/2, 5/2 Stark shifts and splittings. The m j = 1/2 state is employed to detect the signal field because of its larger polarizability than that of m j = 3/2, 5/2. Also, we show that the strength of the spectrum is dependent on the angle between the laser polarizations and the electric field. With optimization of the applied DC field to shift the m j = 1/2 Rydberg energy level to a high sensitivity region and the laser polarizations to obtain the maximum m j = 1/2 signal, we achieve the detection of the signal electric field with a frequency of 100 Hz down to 214.8 µ V/cm with a sensitivity of 67.9 µ V cm −1 Hz −1/2 , and the linear dynamic range is over 37 dB. Our work extends the measurement frequency of Rydberg sensors to super low frequency with high sensitivity, which has the advantages of high sensitivity and miniaturization for receiving super low frequency.
Fields with frequencies below megahertz are challenging for Rydberg-atom-based measurements, due to the low-frequency electric field screening effect that is caused by the alkali-metal atoms adsorbed on the inner surface of the container. In this paper, we investigate on electric fields measurements in the ULF, VLF and LF bands in a Cs vapor cell with built-in parallel electrodes. With optimization of the applied DC field, we achieve high-sensitive detection of the electric field at frequencies of 1kHz, 10kHz and 100kHz based on Rydberg-atom sensor, with the minimum electric field strength down to 18.0μV/cm, 6.9μV/cm and 3.0μV/cm, respectively. The corresponding sensitivity is 5.7 μV/cm/{\sqrt{Hz}}, 2.2μV/cm/{\sqrt{Hz}} and 0.95μV/cm/{\sqrt{Hz}} for ULF, VLF and LF fields, which is better than 1-cm dipole antenna. Besides, the linear dynamic range of Rydberg-atom sensor is over 50 dB. This work presents the potential to enable more applications that utilize atomic sensing technology in ULF, VLF and LF fields.
Research of hot atomic vapor systems has a long history. Recently, much-improved technologies, such as lasers, microwaves and digital/analog control systems, have led to exciting progress in this reviving field. Due to its cryogenic-free and vacuum-free deployment potential, room-temperature and quantum-enabled sensing devices using gaseous atoms have become a popular research topic, and engineering such devices has received considerable attention. Proof-of-principle experiments have been performed demonstrating new ideas such as quantum-enhanced motion sensors, next-generation magnetometers, Rydberg enabled microwave sensors, etc. This thesis focuses on my work related to electromagnetic-field sensing using Rydberg atoms in vapor cells, where Rydberg atoms are excited and detected by electromagnetically induced transparency (EIT) spectroscopy. I first investigate the detection of strong magnetic fields (sim 1~T) in the Paschen-Back regime. The diamagnetic (quadratic) response of the Rydberg levels makes the atoms sensitive to small fluctuations in field strength on a large background. By implementing an isotope-mixed cell, we demonstrate that accurate measurement, within a relative uncertainty of pm0.12%. Many Rydberg-enabled radio frequency and microwave sensing applications require a capability of zeroing or intentional tuning of small DC electric fields inside the vapor cell. For this purpose, I explore an in-situ DC electric-field sensing and tuning method without using any bulk or thin film electrodes. I find that the photoelectric effect on the vapor cell walls (with invisible, atomic Rb aggregate layers covering the surfaces) can generate tuning fields up to 0.8~V/cm, with an inhomogeneity of about 2%. The spatial distribution of these fields can be directly monitored by quadratic Stark shifts of the Rydberg atoms. This work may inspire new approaches for DC-field control in miniaturized, metal-free atomic vapor-cell devices. Like many other quantum measurements on hot gaseous samples, short interaction time and other technical decoherence processes are the major factors which limit the precision and, in certain cases, the accuracy of the metrological results. In order to study these effects in the context of EIT, I performed an EIT experiment using a Lambda-type quantum system consisting of the hyperfine ground states and the first excited electronic state of the Rb atoms contained in a buffer-gas-free thermal vapor cell without anti-relaxation coating. Technical line-broadening effects due to inhomogeneity of stray magnetic fields, laser frequency jitter, transverse beam intensity distribution, interaction time distribution, and atom-wall/impurity gas collisions are studied. Experimental results and numerical simulations are compared. These results provide crucial information and quantitative insights for vapor cell sensor design. The development of compact and multi-functional spectroscopy vapor cells is widely considered to be a critical engineering step towards manufacturing field-deployable sensors for real life applications. My R&D efforts towards fabrication of glass spectroscopy cells with integrated, highly-conductive silicon components are presented in the last part of my thesis. I explored various technical challenges and successfully developed a proof-of-principle prototype from scratch. The device allows the application of electric fields inside the cell for particle trapping and for tuning Rydberg transitions. Further, the highly-conductive silicon components enable microwave polarization filtering for microwave sensing applications, plasma-physics studies, etc. Preliminary experimental/technical data and simulations are presented. In summary, in my thesis I report on a comprehensive study of several spectroscopic and field sensing applications of Rydberg and ground-state atoms in vapor cells, as well as forays into novel methods to engineer vapor cells with embedded electrodes.