Accessing the physical mechanisms behind non-Markovian phenomena in open quantum dynamics requires the study of the statistical properties of the joint system-environment dynamics. This is impossible at the level of the reduced dynamics of the open system alone as the latter is obtained by suitably eliminating the environment. The task is instead made possible by considering multi-time correlation functions involving observables of the open system, only: the open system-environment interactions turn them into global ones thus building up correlations between the two systems. Multi-time correlations form the basis of both the theory of quantum stochastic processes and of the Alicki-Lindblad-Fannes dynamical entropy (ALF entropy for short). This latter quantity provides for quantum systems a measure of the dynamical entropy production as the Kolmogorov-Sinai entropy does for classical systems. In the case of a collisional model whereby the dissipative dynamics of a finite-level system is obtained by its coupling to an infinite classical spin chain, the ALF entropy can be explicitly computed. It turns out to depend on the parameters characterizing the statistical properties of the environment and can be related to the activation and super-activation of memory effects in the open quantum system.
Accessing the physical mechanisms behind non-Markovian phenomena in open quantum dynamics requires the study of the statistical properties of the joint system-environment dynamics. This is impossible at the level of the reduced dynamics of the open system alone as the latter is obtained by suitably eliminating the environment. The task is instead made possible by considering multi-time correlation functions involving observables of the open system, only: the open system-environment interactions turn them into global ones thus building up correlations between the two systems. Multi-time correlations form the basis of both the theory of quantum stochastic processes and of the Alicki-Lindblad-Fannes dynamical entropy (ALF entropy for short). This latter quantity provides for quantum systems a measure of the dynamical entropy production as the Kolmogorov-Sinai entropy does for classical systems. In the case of a collisional model whereby the dissipative dynamics of a finite-level system is obtained by its coupling to an infinite classical spin chain, the ALF entropy can be explicitly computed. It turns out to depend on the parameters characterizing the statistical properties of the environment and can be related to the activation and super-activation of memory effects in the open quantum system.
The Alicki-Lindblad-Fannes dynamical (ALF) entropy measures the rate at which new information is gathered about a quantum system by inspecting its long-time evolution. We propose an extension of the ALF entropy to open quantum dynamics as a measure of back-flow of information from the environment. Such a proposal is stronger than the existing ones based only on the open system reduced dynamics. In the case of a qubit collisionally coupled to a classical spin chain, we obtain an exact expression for the open-system ALF entropy explicitly depending on the environment correlations. An extreme case shows how the information flow from environment to system corresponds to vanishing entropy production as for reversible finite quantum systems.
In the present Thesis we study the behavior of multi-time correlation functions and of thermodynamical quantities such as heat in open quantum systems undergoing an evolution generally affected by the presence of memory effects, i.e. non-Markovian. In the last decade, a large part of the scientific community in this field has dedicated its efforts to the understanding, precise definition and quantification of non-Markovianity in the quantum realm and now we have at our disposal several benchmark results and a plethora of different estimators that allow to determine the degree of non-Markovianity of a given dynamics. It comes therefore natural to investigate how other different dynamical quantities relate to such estimators also in order to understand the physical implications of memory effects on the statistics of observable quantities. In the first part of this work, a quantitative test of the violation of the so-called quantum regression theorem in presence of a non-Markovian dynamical regime is investigated. The quantum regression theorem represents a procedure that, whenever valid, allows to reconstruct two-time correlation functions of system's operators from the sole knowledge of the dynamics of mean values. It is worth stressing that two-time correlation functions are necessary in order to fully characterize the statistical properties of a quantum system, since they are able to catch aspects of the dynamics, such as fluorescence spectrum, in general not accessible looking at mean values. Despite their relevance however, obtaining two-time correlation functions often represents a formidable task, since the knowledge of the full "system+environment" dynamics is required, a generally too demanding request in the context of open quantum systems theory. The quantum regression theorem represents in this regard the easiest route to determine two-time correlation functions, this highlighting its importance. In this work we show that, in a pure-dephasing spin-boson model, the quantum regression theorem represents a stronger condition than non-Markovianity, in the sense that any presence of memory effects in the reduced dynamics inevitably results in violations to the former. These results have been published in [G.Guarnieri, A. Smirne, B. Vacchini, Phys. Rev. A 90, 022110 (2014)]. The second part of the Thesis is devoted to the characterization of heat ow at the microscopic level in open quantum systems, both finite and infinite dimensional. In particular we begin by studying the time behavior of its mean value in a non-Markovian dynamical regime, showing that, at variance with what happens in the Born-Markov semigroup limiting case, heat can backflow from the environment to the system. After providing a condition for the occurrence of such phenomenon and a measure for its amount for a given dynamics, the relationship with suitable non-Markovianity estimators is sought in two paradigmatic models, namely the spin-boson and the quantum brownian motion. The results, collected in [ G. Guarnieri, C. Uchiyama, B. Vacchini, Phys. Rev. A 93, 012118 (2016); G. Guarnieri, J. Nokkala, R. Schmidt, S. Maniscalco, B. Vacchini, Phys. Rev. A 94, 062101 (2016)], on the one hand allow for the identification of parameter-regions where the heat backflow is absent or maximum. On the other hand they show that the occurrence of heat backflow represents a stricter condition than non-Markovianity, in the sense that non-Markovianity allows for the observation of heat flowing back from the environment to the system and, vice versa, a Markovian dynamics prevents its occurrence. This Thesis concludes with the formulation of a new family of lower bounds to the mean dissipated heat in an environmental-assisted erasure-protocol scenario where Landauer's principle applies. As originally conceived for classical systems, this principle states that every irreversible erasure of information stored in a system inevitably carries along an amount of heat dissipated into the environment which is expended to perform the action. Within the framework recently put forward in [D. Reeb, M. M. Wolf, New J. Phys. 16, 103011 (2014)], which guarantees the validity of Landauer's principle in an open quantum systems scenario, we provide an asymptotically tight family of lower bounds to the dissipated heat which are also valid in the non-equilibrium setting. This construction is applied to an open system consisting of a three-level V-system, in which one transition is externally pumped by a laser field while the other is coupled through an XX-interaction to an environment consisting of a spin chain. Beside calculating all these quantities, an exact solution for the dynamics of such system is also provided. These results are collected in [G. Guarnieri, S. Campbell, J. Goold, S. Pigeon, M. Paternostro, B. Vacchini, in preparation].
The Markovian evolution of an open quantum system is characterized by a positive entropy production, while the global entropy gets redistributed between the system and the environment degrees of freedom. Starting from these premises, we analyze the entropy variation of an open quantum system in terms of two distinct relations: the Clausius inequality, that provides an intrinsic bound for the entropy variation in terms of the heat absorbed by the system, and an extrinsic inequality, which instead relates the former to the corresponding entropy increment of the environment. By modeling the thermalization process with a Markovian collisional model, we compare and discuss the two bounds, showing that the latter is asymptotically saturated in the limit of large interaction time. In this regime not only the reduced density matrix of the system reaches an equilibrium configuration, but it also factorizes from the environment degrees of freedom. This last result is proven analytically when the system-bath coupling is sufficiently strong and through numerical analysis in the weak-coupling regime.
Abstract We consider a microscopic collision model, i.e., a quantum system interacts with a hierarchical environment consisting of an auxiliary system and a reservoir. We show how the non-Markovian character of the system is influenced by the coupling strength of system-auxiliary system and auxiliary system-reservoir, coherence of environment and initial system-environment correlations. And we study the non-Markovianity induced by coherence of environment from the perspective of energy, further the relationship between information backflow and energy flux is obtained. Then we study the effect of non-Markovianity on thermodynamic properties. By studying the entropy change of system especially that from heat exchanges with the environment, we reveal the essence of entropy change between positive and negative values during non-Markovian evolution is due to the contribution of heat flux induced by coherence. And compared with the case of Markovian dynamics, we observe that the entropy production decreases in some specific time intervals under non-Markovian dynamics induced by the coupling strength. And this is different to the case of non-Markovianity caused by initial system-environment correlation, that we show the possibility of positive entropy production during the whole dynamics.
This thesis investigates two thematic lines of research, both underpinned by non-Markovian system-reservoir interactions in quantum optics. The overarching focus is on modelling the open system dynamics in a non-perturbative fashion, broadly on - though not restricted to - instances when the environment is structured. A theory is developed by means of enlarging the open system over environmental degrees of freedom to include memory effects in its dynamics. This is achieved using an established technique that involves mapping a bosonic environment onto a 1D chain of harmonic oscillators. Within this setting, we apply a Heisenberg equation-of-motion approach to derive an exact set coupled differential equations for the open system and a single auxiliary oscillator of the chain. The combined equations are shown to have their interpretation rooted in a quantum Markov stochastic process. Including the auxiliary chain oscillator as part of the original system then enables us to obtain an exact master equation for the enlarged system, avoiding any need for the Born-Markov approximations. Our method is valid for a dissipative two-state system, with cases of multiple excitations and added driving discussed. Separately, we apply the framework of quantum Darwinism to an atom-cavity system, and, subsequently, to a more general multiple-environment model. In both cases, the time-dependent spread of correlations between the open system and fractions of the environment is analysed during the course of the decoherence process. The degree to which information is redundant across different fractions is checked to infer the emergence of classicality. In the second case, we go further and present a decomposition of information in terms of its quantum and classical correlations. A quantitative measure of redundancy is also studied with regard to its ability to witness non-Markovian behaviour. Besides fundamental interest, our results have application to quantum information processing and quantum technologies, keeping in mind the potential beneficial use of non-Markovian effects in reservoir engineering.
The dynamics of open quantum systems are often modeled by non-Markovian processes that account for memory effects arising from interactions with the environment. It is well known that the memory provided by the environment can be classical or quantum in nature. Remarkably, the quantumness of the memory can be witnessed locally by measurements on the open system alone, without requiring access to the environment. However, existing witnesses are computationally challenging for systems beyond qubits, which severely limits their practical applicability. In this work, we present a tractable criterion for quantum memory based on the von Neumann entropy, which is easily computable for systems of any dimension. Using this witness, we investigate the nature of memory in a class of physically motivated finite-dimensional qudit dynamics. Moreover, we demonstrate that this criterion is also suitable for detecting quantum memory in continuous-variable systems. As an illustrative example, we analyze non-Markovian Gaussian dynamics of a damped harmonic oscillator.