Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2603.06833

Operational impact of quantum resources in chemical dynamics

Julia Liebert, Gregory D. Scholes

quant-phphysics.chem-phSubmitted Mar 6, 2026• Announced Mar 10, 2026• 0 citations
arXivHTMLPDF

Abstract

Quantum coherence and other non-classical features are widely discussed in chemical dynamics, yet it remains difficult to quantify when such resources are operationally relevant for a given process and observable. While quantum resource theories provide a comprehensive framework for comparing free and resourceful settings, existing approaches typically rely on resource monotones or on performance bounds under free operations, and do not directly quantify the maximal influence a chosen resource can exert on a fixed chemical dynamics. Here, we introduce task specific, process level quantifiers that upper bound the largest change a quantum resource can induce in a target figure of merit. Central is a resource impact functional $\mathcal{C}_M(Λ)$, defined by comparing a state with its paired resource-free counterpart under the same quantum channel $Λ$, which admits an operational interpretation in binary hypothesis testing. We derive variation and time bounds that constrain how rapidly a resource can modify a target signal, providing resource-aware analogues of quantum speed limits. Moreover, we show that open system dynamics can be decomposed into free and resourceful components such that only the resourceful component contributes to $\mathcal{C}_M(Λ)$, thereby isolating the parts of a generator responsible for resource-induced changes in the observable. We illustrate the framework exemplary for energy transfer in a donor-acceptor dimer in two analytically solvable regimes. Our results provide a general toolbox for diagnosing and benchmarking quantum resource effects in molecular processes.

Related papers

Operational impact of quantum resources in chemical dynamics

Julia Liebert, Gregory D. Scholes

Quantum coherence and other non-classical features are widely discussed in chemical dynamics, yet it remains difficult to quantify when such resources are operationally relevant for a given process and observable. While quantum resource theories provide a comprehensive framework for comparing free and resourceful settings, existing approaches typically rely on resource monotones or on performance bounds under free operations and do not directly quantify the maximal influence a chosen resource can exert on a fixed chemical dynamics. Here, we introduce task specific, process level quantifiers that upper bound the largest change a quantum resource can induce in a target figure of merit. Central is a resource impact functional CM(Λ), defined by comparing a state with its paired resource-free counterpart under the same quantum channel Λ, which admits an operational interpretation in binary hypothesis testing. We derive variation and time bounds that constrain how rapidly a resource can modify a target signal, providing resource-aware analogues of quantum speed limits. Moreover, we show that open system dynamics can be decomposed into free and resourceful components such that only the resourceful component contributes to CM(Λ), thereby isolating the parts of a generator responsible for resource-induced changes in the observable. We illustrate the framework exemplarily for energy transfer in a donor-acceptor dimer in two analytically solvable regimes. Our results provide a general toolbox for diagnosing and benchmarking quantum resource effects in molecular processes.

The Journal of Chemical Physics•May 5, 2026•1 citation

Operational bounds and diagnostics for coherence in energy transfer

Julia Liebert, Gregory D. Scholes

Excitation energy transfer in light-harvesting aggregates is highly efficient, yet whether quantum coherence plays an operational role in transport remains debated. A central challenge is that coherence is usually inferred from spectroscopic signatures, whereas transport performance is assessed through specific observables and depends on both the open system dynamics and the initial state preparation. Here we develop a resource theoretic approach that quantifies the maximum change that initial site-basis coherence can induce in a chosen readout under fixed reduced dynamics. The central quantity is the resource impact functional, which yields state independent, readout specific bounds on coherence-induced changes in signals and transport figures of merit. We apply the framework to two models. For a donor-acceptor dimer, we analyse coherence sensitivity across coupling and bath-timescale regimes and bound trapping efficiency and average transfer time in terms of the impact functional. For a multi-site chain with terminal trapping, we derive rigorous criteria that distinguish population placement from sensitivity to initial state site-basis coherence. These include upper bounds on the largest advantage over incoherent preparations, necessary delocalization requirements for achieving a prescribed improvement, and a simple pairwise sufficient condition that can be checked from local information. For quasi-local reduced dynamics, we further obtain a Lieb-Robinson-type bound that constrains when coherence prepared in a distant region can influence a localized readout at finite times. Together, these results provide operational diagnostics and rigorous bounds for benchmarking coherence effects and for identifying regimes in which they are necessarily negligible or potentially relevant in excitonic transport models.

quant-pharXiv:2603.09748•Mar 11, 2026•0 citations

Operational bounds and diagnostics for coherence in energy transfer

Julia Liebert, Gregory D. Scholes

Excitation energy transfer in light-harvesting aggregates is highly efficient, yet whether quantum coherence plays an operational role in transport remains debated. A central challenge is that coherence is usually inferred from spectroscopic signatures, whereas transport performance is assessed through specific observables and depends on both the open system dynamics and the initial state preparation. Here, we develop a resource theoretic approach that quantifies the maximum change that initial site-basis coherence can induce in a chosen readout under fixed reduced dynamics. The central quantity is the resource impact functional, which yields state independent, readout specific bounds on coherence-induced changes in signals and transport figures of merit. We apply the framework to two models. For a donor-acceptor dimer, we analyze coherence sensitivity across coupling and bath-timescale regimes and bound trapping efficiency and average transfer time in terms of the impact functional. For a multi-site chain with terminal trapping, we derive rigorous criteria that distinguish population placement from sensitivity to initial state site-basis coherence. These include upper bounds on the largest advantage over incoherent preparations, necessary delocalization requirements for achieving a prescribed improvement, and a simple pairwise sufficient condition that can be checked from local information. For quasi-local reduced dynamics, we further obtain a Lieb-Robinson-type bound that constrains when coherence prepared in a distant region can influence a localized readout at finite times. Together, these results provide operational diagnostics and rigorous bounds for benchmarking coherence effects and for identifying regimes in which they are necessarily negligible or potentially relevant in excitonic transport models.

The Journal of Chemical Physics•Jun 9, 2026•1 citation

Accessible bounds for general quantum resources

Thomas R Bromley, Marco Cianciaruso, Sofoklis Vourekas +2 more

Abstract The recent development of general quantum resource theories has given a sound basis for the quantification of useful quantum effects. Nevertheless, the evaluation of a resource measure can be highly non-trivial, involving an optimisation that is often intractable analytically or intensive numerically. In this paper, we describe a general framework that provides quantitative lower bounds to any resource quantifier that satisfies the essential property of monotonicity under the corresponding set of free operations. Our framework relies on projecting all quantum states onto a restricted subset using a fixed resource non-increasing operation. The resources of the resultant family can then be evaluated using a simplified optimisation, with the result providing lower bounds on the resource contents of any state. This approach also reduces the experimental overhead, requiring only the relevant statistics of the restricted family of states. We illustrate the application of our framework by focusing on the resource of multiqubit entanglement and outline applications to other quantum resources.

arXiv:1802.04066•Journal of Physics A Mathematical and Theoretical•Jun 8, 2018•9 citations

The Structure of Higher-Order Quantum Resources with an Application to Coherence

Felix Ahnefeld, Thomas Theurer, Martin B. Plenio

We develop a general framework for higher-order quantum resources that treats the resourcefulness of quantum states, channels, and supermaps (also called processes) in a unified manner. By generalizing well-established concepts from resource theories of states and channels, we introduce and study supermap resource monotones and supermap distillation and dilution. As free supermaps, we consider free networks (supermaps that can be implemented with free channels), compatible supermaps (sets of supermaps closed under arbitrary composition), and maximally free superchannels. Specializing to approximate channel-to-channel conversions, we show that under mild assumptions, the conversion error with respect to the diamond distance and the worst-case infidelity coincide. We then apply the general framework to resource theories of dynamical coherence, where we establish the existence of largest sets of compatible supermaps. By characterizing these sets with semidefinite constraints, we show that they are strictly larger than the corresponding free networks but do not contain all maximally free superchannels. We finish by investigating the operational differences of these sets in one-shot channel distillation and dilution, providing solutions for both tasks in the parallel setting and for dilution in the adaptive setting.

quant-pharXiv:2609.40186•Oct 1, 2026•0 citations

Quantum dynamical resource theory under resource non-increasing framework

Si‐ren Yang, Chang‐shui Yu

We define the resource non-increasing (RNI) framework to study the dynamical resource theory. With this definition, we propose several potential quantification candidates under various free operation sets. For explicit demonstrations, we quantify the quantum dynamical coherence in the scenarios with and without post-selective measurements. Correspondingly, we show that the maximally incoherent operations (MIO) and the incoherent operations (IO) in the static coherence resource theory are free in the sense of dynamical coherence. We also provide operational meanings for the measures by the quantum discrimination tasks. Moreover, for the dynamical total coherence, we also present convenient measures and give the analytic calculation for the amplitude damping channel.

arXiv:2203.06561•Chinese Physics B•Nov 17, 2022•1 citation
Quantum coherence and other non-classical features are widely discussed in chemical dynamics, yet it remains difficult to quantify when such resources are operationally relevant for a given process and observable. While quantum resource theories provide a comprehensive framework for comparing free and resourceful settings, existing approaches typically rely on resource monotones or on performance bounds under free operations, and do not directly quantify the maximal influence a chosen resource can exert on a fixed chemical dynamics. Here, we introduce task specific, process level quantifiers that upper bound the largest change a quantum resource can induce in a target figure of merit. Central is a resource impact functional CM(Λ)\mathcal{C}_M(Λ)CM​(Λ), defined by comparing a state with its paired resource-free counterpart under the same quantum channel ΛΛΛ, which admits an operational interpretation in binary hypothesis testing. We derive variation and time bounds that constrain how rapidly a resource can modify a target signal, providing resource-aware analogues of quantum speed limits. Moreover, we show that open system dynamics can be decomposed into free and resourceful components such that only the resourceful component contributes to CM(Λ)\mathcal{C}_M(Λ)CM​(Λ), thereby isolating the parts of a generator responsible for resource-induced changes in the observable. We illustrate the framework exemplary for energy transfer in a donor-acceptor dimer in two analytically solvable regimes. Our results provide a general toolbox for diagnosing and benchmarking quantum resource effects in molecular processes.
Quantum coherence and other non-classical features are widely discussed in chemical dynamics, yet it remains difficult to quantify when such resources are operationally relevant for a given process and observable. While quantum resource theories provide a comprehensive framework for comparing free and resourceful settings, existing approaches typically rely on resource monotones or on performance bounds under free operations and do not directly quantify the maximal influence a chosen resource can exert on a fixed chemical dynamics. Here, we introduce task specific, process level quantifiers that upper bound the largest change a quantum resource can induce in a target figure of merit. Central is a resource impact functional CM(Λ), defined by comparing a state with its paired resource-free counterpart under the same quantum channel Λ, which admits an operational interpretation in binary hypothesis testing. We derive variation and time bounds that constrain how rapidly a resource can modify a target signal, providing resource-aware analogues of quantum speed limits. Moreover, we show that open system dynamics can be decomposed into free and resourceful components such that only the resourceful component contributes to CM(Λ), thereby isolating the parts of a generator responsible for resource-induced changes in the observable. We illustrate the framework exemplarily for energy transfer in a donor-acceptor dimer in two analytically solvable regimes. Our results provide a general toolbox for diagnosing and benchmarking quantum resource effects in molecular processes.
Excitation energy transfer in light-harvesting aggregates is highly efficient, yet whether quantum coherence plays an operational role in transport remains debated. A central challenge is that coherence is usually inferred from spectroscopic signatures, whereas transport performance is assessed through specific observables and depends on both the open system dynamics and the initial state preparation. Here we develop a resource theoretic approach that quantifies the maximum change that initial site-basis coherence can induce in a chosen readout under fixed reduced dynamics. The central quantity is the resource impact functional, which yields state independent, readout specific bounds on coherence-induced changes in signals and transport figures of merit. We apply the framework to two models. For a donor-acceptor dimer, we analyse coherence sensitivity across coupling and bath-timescale regimes and bound trapping efficiency and average transfer time in terms of the impact functional. For a multi-site chain with terminal trapping, we derive rigorous criteria that distinguish population placement from sensitivity to initial state site-basis coherence. These include upper bounds on the largest advantage over incoherent preparations, necessary delocalization requirements for achieving a prescribed improvement, and a simple pairwise sufficient condition that can be checked from local information. For quasi-local reduced dynamics, we further obtain a Lieb-Robinson-type bound that constrains when coherence prepared in a distant region can influence a localized readout at finite times. Together, these results provide operational diagnostics and rigorous bounds for benchmarking coherence effects and for identifying regimes in which they are necessarily negligible or potentially relevant in excitonic transport models.
Excitation energy transfer in light-harvesting aggregates is highly efficient, yet whether quantum coherence plays an operational role in transport remains debated. A central challenge is that coherence is usually inferred from spectroscopic signatures, whereas transport performance is assessed through specific observables and depends on both the open system dynamics and the initial state preparation. Here, we develop a resource theoretic approach that quantifies the maximum change that initial site-basis coherence can induce in a chosen readout under fixed reduced dynamics. The central quantity is the resource impact functional, which yields state independent, readout specific bounds on coherence-induced changes in signals and transport figures of merit. We apply the framework to two models. For a donor-acceptor dimer, we analyze coherence sensitivity across coupling and bath-timescale regimes and bound trapping efficiency and average transfer time in terms of the impact functional. For a multi-site chain with terminal trapping, we derive rigorous criteria that distinguish population placement from sensitivity to initial state site-basis coherence. These include upper bounds on the largest advantage over incoherent preparations, necessary delocalization requirements for achieving a prescribed improvement, and a simple pairwise sufficient condition that can be checked from local information. For quasi-local reduced dynamics, we further obtain a Lieb-Robinson-type bound that constrains when coherence prepared in a distant region can influence a localized readout at finite times. Together, these results provide operational diagnostics and rigorous bounds for benchmarking coherence effects and for identifying regimes in which they are necessarily negligible or potentially relevant in excitonic transport models.
Abstract The recent development of general quantum resource theories has given a sound basis for the quantification of useful quantum effects. Nevertheless, the evaluation of a resource measure can be highly non-trivial, involving an optimisation that is often intractable analytically or intensive numerically. In this paper, we describe a general framework that provides quantitative lower bounds to any resource quantifier that satisfies the essential property of monotonicity under the corresponding set of free operations. Our framework relies on projecting all quantum states onto a restricted subset using a fixed resource non-increasing operation. The resources of the resultant family can then be evaluated using a simplified optimisation, with the result providing lower bounds on the resource contents of any state. This approach also reduces the experimental overhead, requiring only the relevant statistics of the restricted family of states. We illustrate the application of our framework by focusing on the resource of multiqubit entanglement and outline applications to other quantum resources.
We develop a general framework for higher-order quantum resources that treats the resourcefulness of quantum states, channels, and supermaps (also called processes) in a unified manner. By generalizing well-established concepts from resource theories of states and channels, we introduce and study supermap resource monotones and supermap distillation and dilution. As free supermaps, we consider free networks (supermaps that can be implemented with free channels), compatible supermaps (sets of supermaps closed under arbitrary composition), and maximally free superchannels. Specializing to approximate channel-to-channel conversions, we show that under mild assumptions, the conversion error with respect to the diamond distance and the worst-case infidelity coincide. We then apply the general framework to resource theories of dynamical coherence, where we establish the existence of largest sets of compatible supermaps. By characterizing these sets with semidefinite constraints, we show that they are strictly larger than the corresponding free networks but do not contain all maximally free superchannels. We finish by investigating the operational differences of these sets in one-shot channel distillation and dilution, providing solutions for both tasks in the parallel setting and for dilution in the adaptive setting.
We define the resource non-increasing (RNI) framework to study the dynamical resource theory. With this definition, we propose several potential quantification candidates under various free operation sets. For explicit demonstrations, we quantify the quantum dynamical coherence in the scenarios with and without post-selective measurements. Correspondingly, we show that the maximally incoherent operations (MIO) and the incoherent operations (IO) in the static coherence resource theory are free in the sense of dynamical coherence. We also provide operational meanings for the measures by the quantum discrimination tasks. Moreover, for the dynamical total coherence, we also present convenient measures and give the analytic calculation for the amplitude damping channel.