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arXiv:2602.19908

Heat flow through the quantum heat valve coupled to ohmic baths via a master equation approach

Antti Vaaranta, Marco Cattaneo, Paolo Muratore-Ginanneschi, Jukka Pekola

quant-phcond-mat.mes-hallSubmitted Feb 23, 2026• Announced Feb 24, 2026
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Abstract

We provide a theoretical model for the non-equilibrium steady state heat flow through a quantum heat valve. The model is based on a master equation approach, where the partial secular approximation has been carefully performed in order to obtain accurate results. Our study assumes an ohmic spectral density for the two thermal baths of the model. This is in contrast with previous treatments of the quantum heat valve, where the baths have been assumed as being structured with a peaked spectral density near the resonance frequency of the resonator. These studies have also taken the resonator to be a part of the open quantum system of interest, which results in double counting of the resonator, as the latter appears both in the spectral density of the bath and as a part of the open system. Although this model accounts for the observations in a satisfactory way, it raises issues regarding its physical interpretation. Our method solves this conceptual problem. We apply it to describe an experiment on a quantum heat valve, showing that it successfully captures the experimental results and improves upon the previous theoretical model, which suffered from the resonator double-counting issue. Our findings confirm that the careful application of the master equation approach, in particular when it comes to the secular approximation, is a useful tool for explaining realistic experimental setups.

Journal reference
J. Low Temp. Phys. 222, 93 (2026)
DOI
10.1007/s10909-026-03426-3

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We provide a theoretical model for the non-equilibrium steady state heat flow through a quantum heat valve. The model is based on a master equation approach, where the partial secular approximation has been carefully performed in order to obtain accurate results. Our study assumes an ohmic spectral density for the two thermal baths of the model. This is in contrast with previous treatments of the quantum heat valve, where the baths have been assumed as being structured with a peaked spectral density near the resonance frequency of the resonator. These studies have also taken the resonator to be a part of the open quantum system of interest, which results in double counting of the resonator, as the latter appears both in the spectral density of the bath and as a part of the open system. Although this model accounts for the observations in a satisfactory way, it raises issues regarding its physical interpretation. Our method solves this conceptual problem. We apply it to describe an experiment on a quantum heat valve, showing that it successfully captures the experimental results and improves upon the previous theoretical model, which suffered from the resonator double-counting issue. Our findings confirm that the careful application of the master equation approach, in particular when it comes to the secular approximation, is a useful tool for explaining realistic experimental setups.
In this paper we examine some foundational issues of a class of quantum engines where the system consists of a single quantum parametric oscillator, operating in an Otto cycle consisting of four stages of two alternating phases: the isentropic phase is detached from any bath (thus a closed system) where the natural frequency of the oscillator is changed from one value to another, and the isothermal phase where the system (now rendered open) is put in contact with one or two squeezed baths of different temperatures, whose nonequilibrium dynamics follows the Hu-Paz-Zhang (HPZ) master equation for quantum Brownian motion. The HPZ equation is an exact non-Markovian equation which preserves the positivity of the density operator and is valid for (1) all temperatures, (2) arbitrary spectral density of the bath, and (3) arbitrary coupling strength between the system and the bath. Taking advantage of these properties we examine some key foundational issues of theories of quantum open and squeezed systems for these two phases of the quantum Otto engines. This includes (1) the non-Markovian regimes for non-Ohmic, low-temperature baths, (2) what to expect in nonadiabatic frequency modulations, (3) strong system-bath coupling, as well as (4) the proper junction conditions between these two phases. Our aim here is not to present ways for attaining higher efficiency but to build a more solid theoretical foundation for quantum engines of continuous variables covering a broader range of parameter spaces that we hope are of use for exploring such possibilities.
We study the quantum dissipative dynamics of a particle coupled linearly to a set of two-level systems (the heat bath) via the master equation method, which we extract from the path integral formalism independently from the form of the bath spectral density. We compare our results with the standard models based on bosonic heat baths, showing their main differences and similarities. In particular, we study special forms for the spectral density of the bath which give results quite different from the standard models.
The Markovian dynamics of open quantum systems is typically described through Lindblad equations, which are derived from the Redfield equation via the full secular approximation. The latter neglects the rotating terms in the master equation corresponding to pairs of jump operators with different Bohr frequencies. However, for many physical systems this approximation breaks down, and thus a more accurate treatment of the slowly rotating terms is required. Indeed, more precise physical results can be obtained by performing the partial secular approximation, which takes into account the relevant time scale associated with each pair of jump operators and compares it with the time scale arising from the system-environment coupling. In this work, we introduce a general code for performing the partial secular approximation in the Redfield equation for structured open quantum systems. The code can be applied to a generic Hamiltonian of any multipartite system coupled to bosonic baths. Moreover, it can also reproduce the unified master equation, which captures the same physical behavior as the Redfield equation under the partial secular approximation, but is mathematically guaranteed to generate a completely positive dynamical map. Finally, the code can compute both the local and global version of the master equation for the same physical problem. We illustrate the code by studying the steady-state heat flow in a structured open quantum system composed of two superconducting qubits, each coupled to a bosonic mode, which in turn interacts with a thermal bath. The results in this work can be employed for the numerical study of a wide range of complex open quantum systems.
Abstract We investigate the classical problem of two resonantly interacting oscillators each of which is coupled to “its own” heat bath based on the effective Hamiltonian method and the quantum stochastic differential equation (in contrast to the well-known “global” and “local” approaches). We show that in the second order of the algebraic perturbation theory, each of the oscillators turns out to be also coupled to the “foreign” heat bath. We calculate the steady-state heat flows and prove that there is no heat flow from the cold heat bath to the hot one, as evidenced by some results of the local approach.
Abstract There is a current interest in quantum thermodynamics in the context of open quantum systems. An important issue is the consistency of quantum thermodynamics, in particular the second law of thermodynamics, i.e. the flow of heat from a hot reservoir to a cold reservoir. Here recent emphasis has been on composite system and in particular the issue regarding the application of local or global master equations. In order to contribute to this discussion we discuss two cases, namely as an example a single qubit and as a simple composite system two coupled qubits driven by two heat reservoirs at different temperatures, respectively. Applying a global Lindblad master equation approach we present explicit expressions for the heat currents in agreement with the second law of thermodynamics. The analysis is carried out in the Born–Markov approximation. We also discuss issues regarding the possible presence of coherences in the steady state.
We provide a comprehensive study of heat transport in periodically driven quantum systems using a master equation approach in the Floquet basis. Starting from the exact, formal expressions, we obtain, within the weak coupling regime of system-bath coupling, a generalized Floquet-Redfield master equation which does not involve Markovian or secular approximations and the corresponding formula for the heat current. From this approach we derive the standard, full secular master equation. Moreover, we present a master equation for the driven spin-boson model in the instantaneous eigenbasis. The different approaches are compared by applying them to the steady-state heat transport in the driven spin-boson model. An analytical solution is provided for the master equation in the instantaneous eigenbasis which reproduces the numerics and explains the features of the heat current as a function of the drive parameters.