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arXiv:2602.12880 · APS Open Science

Shift of the Bose-Einstein condensation transition in the presence of a second atomic species

P. M. Gaspar, Vanderlei Salvador Bagnato, P. C. M. Castilho

Published Jun 24, 2026• 0 citations
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Abstract

Atomic interactions play an important role in the properties of ultracold atomic gases. In single-component bosonic systems, its effect is already present at the critical point for the Bose-Einstein condensate phase transition by shifting it to lower temperatures as a consequence of effective repulsion between the atoms. When considering atomic bosonic mixtures, interesting effects arise from the competition between intra- and interspecies interactions such as the miscible-immiscible phase transition and the particular case of self-bounded quantum droplets. In such a scenario, it is natural to expect that these interactions will also affect the critical point of each species composing the mixture. In this paper, we obtain semianalytical expressions for the critical temperature shift of the phase transition to a Bose-Einstein condensate in the presence of a second species considering the mean-field framework. We treat differently the cases in which the second species is above or below its own critical temperature and apply the obtained relations to the case of a Na 23 − K 39 bosonic mixture that can be realized in current running experimental setups. Our findings can be easily extended to other atomic mixtures.

DOI
10.1103/3gr1-mcmm

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Atomic interactions play an important role in the properties of ultracold atomic gases. In single-component bosonic systems, its effect is already present at the critical point for the Bose-Einstein condensate phase transition by shifting it to lower temperatures as a consequence of effective repulsion between the atoms. When considering atomic bosonic mixtures, interesting effects arise from the competition between intra- and interspecies interactions such as the miscible-immiscible phase transition and the particular case of self-bounded quantum droplets. In such a scenario, it is natural to expect that these interactions will also affect the critical point of each species composing the mixture. In this paper, we obtain semianalytical expressions for the critical temperature shift of the phase transition to a Bose-Einstein condensate in the presence of a second species considering the mean-field framework. We treat differently the cases in which the second species is above or below its own critical temperature and apply the obtained relations to the case of a Na 23 − K 39 bosonic mixture that can be realized in current running experimental setups. Our findings can be easily extended to other atomic mixtures.
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We discuss the mean-field theories obtained from the leading order in a large-NNN approximation for one- and two-component dilute Bose gases. For a one-component Bose gas, this approximation has the following properties: the Bose-Einstein condensation (BEC) phase transition is second order but the critical temperature Tc{T}_{c}Tc​ is not shifted from the noninteracting gas value T0{T}_{0}T0​. The spectrum of excitations in the BEC phase resembles the Bogoliubov dispersion with the usual coupling constant replaced by the running coupling constant which depends on both temperature and momentum. We then study two-component Bose gases with both inter- and intraspecies interactions and focus on the stability of the mixture state above Tc{T}_{c}Tc​. Our mean-field approximation predicts an instability from the mixture state to a phase-separated state when the ratio of the interspecies interaction strength to the intraspecies interaction strength (assuming equal strength for both species) exceeds a critical value. At high temperature this is a structural transition and the global translational symmetry is broken. Our work complements previous studies on the instability of the mixture phase in the presence of BEC.
The effects of miscibility in interacting two-component classical fluids are relevant in a broad range of daily applications. When considering quantum systems, two-component Bose–Einstein condensates provide a well-controlled platform where the miscible–immiscible phase transition can be completely characterized. In homogeneous systems, this phase transition is governed only by the competition between intra- and inter-species interactions. However, in more conventional experiments dealing with trapped gases, the pressure of the confinement increases the role of the kinetic energy and makes the system more miscible. In the most general case, the miscibility phase diagram of unbalanced mixtures of different atomic species is strongly modified by the atom number ratio and the different gravitational sags. Here, we numerically investigate the ground-state of a 23Na–39K quantum mixture for different interaction strengths and atom number ratios considering realistic experimental parameters. Defining the spatial overlap between the resulting atomic clouds, we construct the phase diagram of the miscibility transition which could be directly measured in real experiments.
The effects of atom numbers on the miscibility-immiscibility transition of a harmonically trapped population imbalanced binary Bose-Einstein condensate are investigated. In two-dimensional parameter space expanded by the strength of interspecies interaction and the ratio of atom numbers between two components, we have mapped out the ground-state phase diagrams for the ideal model without intraspecies interactions, and for the $^{23}\mathrm{Na}\text{\ensuremath{-}}^{23}\mathrm{Na}$ mixture and the $^{87}\mathrm{Rb}\text{\ensuremath{-}}^{87}\mathrm{Rb}$ mixture with experimentally accessible intraspecies scattering lengths, respectively. It is found that all the phase diagrams include the miscible, symmetric immiscible, and asymmetric immiscible phases, and there exists a tricritical point where those three different phases merge. Furthermore, the phase boundaries among those three phases show a strong dependence on the atom numbers of two components. These results can be observed in current experiments.
Multicomponent quantum gases are ideal platforms to study fundamental phenomena arising from the mutual interaction between different constituents. Particularly, due to the repulsive interactions between two species, the system may exhibit a phase separation. We develop a mean-field-based theory for a two-component Bose mixture, which is equivalent to the Hartree-Fock-Bogoliubov approximation, and derive analytical expressions for the phase boundary and miscibility. The majority of existing theories, which are valid only for weakly interacting Bose gases, predict that the phase boundary is determined by the criterion ${g}_{ab}\ensuremath{\leqslant}\sqrt{{g}_{aa}{g}_{bb}}$ (where gab{g}_{ab}gab​ is a coupling constant between the components aaa and bbb). We show that in the Bose-Einstein condensation phase ($T\ensuremath{\leqslant}{T}_{c}$) the system may remain in a stable and miscible phase also for larger values of gab{g}_{ab}gab​, depending on the gas parameter $\ensuremath{\gamma}$ and temperature.
The miscibility of two interacting quantum systems is an important testing ground for the understanding of complex quantum systems. Two-component Bose-Einstein condensates enable the investigation of this scenario in a particularly well controlled setting. In a homogeneous system, the transition between mixed and separated phases is fully characterized by a miscibility parameter based on the ratio of intra- to interspecies interaction strengths. Here we show, however, that this parameter is no longer the optimal one for trapped gases, for which the location of the phase boundary depends critically on atom numbers. We demonstrate how monitoring of damping rates and frequencies of dipole oscillations enables the experimental mapping of the phase diagram by numerical implementation of a fully self-consistent finite-temperature kinetic theory for binary condensates. The change in damping rate is explained in terms of surface oscillation in the immiscible regime, and counterflow instability in the miscible regime, with collisions becoming only important in the long time evolution.