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arXiv:2601.09854

Multi-level quantum emitter in an optical waveguide: paradoxes and resolutions

Ben Lang

quant-phphysics.opticsSubmitted Jan 14, 2026• Announced Jan 16, 2026• 0 citations
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Abstract

We theoretically investigate the optical dipole interaction between a multi-level quantum system and a single-mode optical waveguide of any local polarisation. We investigate several paradoxical seeming situations, for example we find a situation in which there exist two non-orthogonal quantum states, each of which results in a photon flux in the opposite direction to the other. We show how, despite appearances, this does not break the unitary requirements of quantum mechanics. We also find that an isotropic quantum emitter can be either reflective or transmissive to light depending on the waveguide polarisation at the emitter location, indeed in the zero loss limit such a system changes from 100% transmission to 100% reflection due to an infinitesimal polarisation rotation. An example case for a four level system is also considered, which is found to operate as a non-destructive parity measurement of the photon number.

Comments
15 pages, 4 figures

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We theoretically investigate the optical dipole interaction between a multi-level quantum system and a single-mode optical waveguide of any local polarisation. We investigate several paradoxical seeming situations, for example we find a situation in which there exist two non-orthogonal quantum states, each of which results in a photon flux in the opposite direction to the other. We show how, despite appearances, this does not break the unitary requirements of quantum mechanics. We also find that an isotropic quantum emitter can be either reflective or transmissive to light depending on the waveguide polarisation at the emitter location, indeed in the zero loss limit such a system changes from 100% transmission to 100% reflection due to an infinitesimal polarisation rotation. An example case for a four level system is also considered, which is found to operate as a non-destructive parity measurement of the photon number.
Abstract We consider the reflection of a photon by a two-level system in a quasi-one-dimensional waveguide. The waveguide polarisation at the location of the two-level system and the transition dipole are key determinants of the physics, controlling of the phase and amplitude of the scattered light in both directions. In most cases full control is possible by tuning only one of these two degrees of freedom. In reverse, this enables unique characterisation of the dipole from measurements of the scattered light. Phase singularities occur where the reflection coefficient is zero, with the (hyper-)spherical parameter space determining the dynamics of these singularities.
Summary form only given. There has recently been great interest in chiral waveguides, where the polarisation of the forwards and backwards propagating light fields are oppositely circular at certain positions in space (C-points) [1]. This results in new phenomena, such as the one way emission of light from spin-transitions in quantum dots (QDs) or atoms (simulation, fig. b). The emitted photon's direction is determined by the spin state of the emitter.To date calculations on this topic have either been restricted to certain special cases, or have relied on simplifying “rate forwards/backwards” models [2]. Using a Green's function method we have generalised to the case of any polarisable dipole at a point supporting any polarisation. Several interesting physical effects arise here that could not have been predicted using the previous models. For example in the figure we show how perfect chiral behaviour can be recovered at points of elliptical polarisation by using equally elliptical dipoles stretched along the orthogonal axis. This may be realised in QDs with a vector magnetic field.We further generalise our approach to include the population state of a multi-level system. This allows us to calculate the dynamics of complicated multi-transition “quantum dipoles”, such as a Λ-system, recovering results consistent with experiment [3].
Waveguide quantum electrodynamics (waveguide QED) describes the interaction between an electromagnetic field confined to a one-dimensional waveguide with atom-like quantum emitters close by. The characteristics of these kinds of systems are the possibility for strong and even ultrastrong interactions between the photonic and atom-like systems, and practically infinite range interactions between the emitters. These properties are valuable for a wide range of quantum optical applications, like quantum communication, quantum networks and quantum metrology. In this thesis we focus on two challenges in quantum optics, namely the generation and scattering of multiphoton states. In the first part of this thesis we demonstrate how waveguide QED systems can be exploited for the generation of multiphoton states, in particular of single-mode Fock states and superpositions thereof as well as multi-mode photonic states with metrological applications. The basic setup for this goal is an ensemble of quantum emitters coupled to a waveguide. In the so-called atomic mirror configuration symmetric Dicke states (or a superposition thereof) decay superradiantly to the ground state and emit the desired multiphoton state, which can be efficiently collected at the ends of the waveguide. We propose various protocols for the preparation of these Dicke states in waveguide QED systems and characterize the emitted photonic state. It turns out that in the low excitation regime, that is, if the number of photons is much lower than the ensemble size, the photonic state is emitted into a single mode. This single-mode structure is fundamental to current proposals for applications in quantum metrology with optical interferometers. Outside the low excitation regime, a multi-mode photonic state is generated, for which the metrological capabilities were unknown. We were able to show that these states still lead to quantum-enhanced optical interferometry. In the second part of this thesis we demonstrate how the scattering of multiphoton states on a single quantum emitter coupled to the waveguide can be used for testing the limits of the light-matter interaction strength. In particular, we investigate systems in the so-called ultrastrong coupling regime, where the coupling strength between the photonic and atom-like system is of the order of the emitter's transition energy. In this regime, many methods and approximations used in quantum optics, especially the Rotating Wave Approximation, break down and one needs to develop new analytical and numerical methods to study these systems. One approach is the so-called polaron Transformation. We show how this transformation can be applied for predicting the scattering amplitude of few photons scattering on the emitter. The comparison of these results with numerical simulations using matrix product states shows a good agreement for moderate coupling strengths. Both parts together show that waveguide QED systems are promising candidates for the generation of multiphoton states as well as for the investigation of fundamental limits probed through the scattering of multiphoton states. The latter also finds application in the implementation of photon-photon nonlinearities induced by the interaction with the quantum emitters. Apart from these and many other theoretical predictions, waveguide QED systems are also undergoing rapid progress in experiments. Therefore, we expect these kinds of systems to bring forth several advances in the field of quantum optics.
Engineering photon-photon interactions is fundamentally challenging because photons in vacuum do not interact with each other. While their interactions can be mediated using optical nonlinearities, these effects are negligible for individual photons. This thesis explores two topics related to optical nonlinearities in waveguides. In the first part, we perform a numerical simulation study of hollow core antiresonant reflecting optical waveguides (ARROWs) fabricated using standard lithographic techniques in the context of their suitability as a platform for on-chip photonic quantum information processing. We investigate the effects of the core size, the number of pairs of antiresonant layers surrounding the hollow core, and the refractive index contrast between cladding materials on propagation losses in the waveguide. Additionally, we explore the feasibility of integrating these waveguides with Bragg gratings and dielectric metasurface mirrors to form on-chip cavities, that when loaded with atomic ensembles could act as nonlinear optical devices controllable with single photons. \n \nThe second part of this thesis studies the application of a 3 level quantum emitter coupled to a directional optical waveguide to deterministically subtract a single photon from a propagating optical pulse. Subtracting a single photon from a light state is one of the most fundamental operations with important applications in quantum information processing. However, current methods to subtract a photon such as using a low reflectivity beam splitter suffer from inherently low success probabilities as well as a strong dependence on the number of photons in the input. We explore implementing this single photon subtraction operation in our proposed system when the optical input is a continuous wave coherent state, coherent pulsed state containing a finite number of photons, or a Fock state.
We propose and theoretically investigate a model to realize cascaded optical nonlinearity with few atoms and photons in one-dimension (1D). The optical nonlinearity in our system is mediated by resonant interactions of photons with two-level emitters, such as atoms or quantum dots in a 1D photonic waveguide. Multi-photon transmission in the waveguide is nonreciprocal when the emitters have different transition energies. Our theory provides a clear physical understanding of the origin of nonreciprocity in the presence of cascaded nonlinearity. We show how various two-photon nonlinear effects including spatial attraction and repulsion between photons, background fluorescence can be tuned by changing the number of emitters and the coupling between emitters (controlled by the separation).
Realising a platform for efficiently guiding and manipulating light at the singlephoton level lies at the heart of optical quantum information processing. In this thesis we aid in the pursuit of this goal by analysing few-photon transport properties in photonic devices while keeping in mind possible applications and experimental challenges. We especially focus on single and two-photon transport properties in one-dimensional waveguides coupled to (artificial) atoms modelled as two and three-level emitters. We begin by introducing key concepts relevant for this thesis and then explain how to model such waveguide geometries. We show how directional-dependent coupling between a waveguide and a localized quantum system can be modelled from a chain of harmonic oscillators by allowing the system to couple to more than one site. Using the input-output formalism and scattering matrix theory we determine a general form for the single and two-photon S-matrices for a waveguide coupled to a two-level system. We also explain how to engineer a quantum optical Fanoresonance waveguide geometry and calculate how this modifies the S-matrices, the few-photon scattering probabilities, and the scattered output spectra. We show that the nonlinear effects in such a system generates highly correlated directional scattering probabilities. We device a protocol that can generate maximal entanglement between two spectrally distinct solid-state emitters by the use of multi-photon scattering. The results also reveal a rich structure for multi-photon states interacting with non-identical emitters. As a final investigation, we quantify how spectral diffusion in quantum dots affects finite-width single and two-photon scattering. Single-photon scattering probabilities are described by a simple convolution but this is not the case for a two-photon state scattering off a two-level emitter. We show that the effect of spectral wandering depletes the nonlinear scattering properties, but that it affects co and counter-propagating output probabilities differently.