Though the performance of room-temperature masers has improved over the last decade, relatively little attention has been paid to the optics used to pump the maser's gain medium. In this work, we investigate a novel multi-blade optical ``injector'' that permits more effective and more scaleable pumping. The reported work encompasses an interdisciplinary mix of conceptualization, simulation, crystal growth, fabrication, and microwave engineering. Our gain medium is pentacene dissolved as a solid solution with para-terphenyl (Pc:PTP) molecular crystal. We accurately determine this pentacene's molecular absorption cross-section as a function of wavelength. Ray-tracing is then used to assess how different designs of waveguide inject light into the Pc:PTP crystal. A multi-blade injector made of high-refractive-index glass (namely Ohara S-TIH6) is predicted to pump it more completely and uniformly than previous designs. Upon hand-fabricating such an injector and Bridgman-growing a crystal of 0.1% Pc:PTP over it, an experimental maser oscillator using this combined injector-crystal assembly is demonstrated. The performance and scaleability of multiblade injection vis-a-vis alternative strategies is analyzed.
Though the performance of room-temperature masers has improved over the last decade, relatively little attention has been paid to the optics used to pump the maser's gain medium. In this work, we investigate a novel multi-blade optical ``injector'' that permits more effective and more scaleable pumping. The reported work encompasses an interdisciplinary mix of conceptualization, simulation, crystal growth, fabrication, and microwave engineering. Our gain medium is pentacene dissolved as a solid solution with para-terphenyl (Pc:PTP) molecular crystal. We accurately determine this pentacene's molecular absorption cross-section as a function of wavelength. Ray-tracing is then used to assess how different designs of waveguide inject light into the Pc:PTP crystal. A multi-blade injector made of high-refractive-index glass (namely Ohara S-TIH6) is predicted to pump it more completely and uniformly than previous designs. Upon hand-fabricating such an injector and Bridgman-growing a crystal of 0.1% Pc:PTP over it, an experimental maser oscillator using this combined injector-crystal assembly is demonstrated. The performance and scaleability of multiblade injection vis-a-vis alternative strategies is analyzed.
Through their ability to achieve cryogenic levels of noise performance while operating at room temperature, optically-pumped, solid-state (OPSS) masers show great promise as quantum sensors, oscillators, and amplifiers. We here demonstrate maser oscillation in a microwave cavity containing a crystal of pentacene-doped para-terphenyl (ptc:ptp) pumped by a single, chip-scale LED. Here, unlike previous work, the size of the pump source does not dominate the size of the maser system as a whole. This miniaturization is achieved through invasive optical pumping in the form of a waveguide, the tip of which is embedded into the maser crystal. Using experimental measurements combined with microwave and optical simulations, we find that our approach offers at least a factor-of-2 enhancement in cooperativity over end-on optical excitation. We use our simulations to define a figure of merit for maser pumping efficiency, and conclude that there remains significant headroom to improve the performance of ptc:ptp masers through improved optical design.
We explore an approach for optically pumping a body of optically dense magnetic material. This challenge arises in time-resolved electron paramagnetic resonance (TREPR), triplet-based dynamic nuclear polarisation (DNP), and cavity QED. Crystals of pentacene-doped p-terphenyl were grown around variously shaped ends of optical waveguides, through which pump light could be injected deeply into the crystal. When incorporated into a maser as the gain medium, we found that, compared to conventional side-pumping, 11 times less pump beam intensity was needed to reach the masing threshold and 54 times more pulse energy could be absorbed by the gain medium without damage, resulting in a record peak output power of -5 dBm.
We present in this work a quasi-continuous-wave (cw) pentacene maser operating at 1.45 GHz in the Earth's magnetic field at room temperature with a duration of approximately 4 ms and an output power of up to $\ensuremath{-}25$ dBm. The maser is optically pumped by a cerium-doped yttrium-aluminum-garnet (YAG) (Ce:YAG) luminescent concentrator (LC), the wedge-shaped output of which is embedded inside a 0.1% pentacene-doped para-terphenyl (Pc:Ptp) crystal. The pumped crystal is located inside a ring of strontium titanate (STO) that supports a ${\mathrm{TE}}_{01\ensuremath{\delta}}$ mode of high magnetic Purcell factor. Combined with simulations, our results indicate that cw operation of pentacene masers at room temperature is perfectly feasible so long as excessive heating of the crystal is avoided.
Masers can deliver ultralow-noise amplification of microwave signals in medical imaging and deep-space communication, with recent research being rekindled through the discovery of gain media operating at room-temperature, eschewing bulky cryogenics that hindered their use. This work shows the discovery of 6,13-diazapentacene doped in para-terphenyl (DAP:PTP) as a maser gain medium that can operate at room-temperature, without an external magnetic field. With a maser output power of -10 dBm, it is on par with pentacene-doped para-terphenyl in masing power, while possessing compelling advantages such as faster amplification startup times, being pumped by longer wavelength light at 620 nm and greater chemical stability from nitrogen groups. Furthermore, the maser bursts from DAP:PTP allow one to reach the strong coupling regime for cavity quantum electrodynamics, with a high cooperativity of 182. The optical and microwave spin dynamics of DAP:PTP are studied in order to evaluate its capabilities as a maser gain medium, where it features fast intersystem crossing and an advantageously higher triplet quantum yield. The results pave the way for the future discovery of similar maser materials and help designate them as promising candidates for quantum sensors, optoelectronic devices and the study of cavity quantum electrodynamic effects at room-temperature.
Room-temperature MASERs (Microwave Amplification by Stimulated Emission of Radiation) are coherent sources that exploit stimulated emission to amplify electromagnetic waves at microwave frequencies. Here we report the first demonstration of an LED-pumped maser based on photo-excited triplet states of pentacene in p-terphenyl. The LED light is brightness enhanced and guided using a Cerium-doped Yttrium Aluminium Garnet luminescent crystal that uses light recycling to reach record luminance and power levels. We observe stable maser emission at 1.45 GHz using LED pumping at a much lower pump threshold power. This new maser is cost-effective, safe, and environmentally friendly, and hence ensures a wide variety of potential uses, including more sensitive magnetic resonance body scanners, quantum optical coherence tomography, advanced quantum computer components, portable atomic clocks, and better radio astronomy devices for deep space exploration.
Molecular room temperature masers have emerged as promising sources of coherent microwaves, but systematic comparisons of organic gain media under uniform conditions remain limited. This paper presents a characterization of two systems, pentacene doped para terphenyl (Pc:PTP, 1.45 GHz) and 6,13 diazapentacene doped para terphenyl (DAP:PTP, 1.478 GHz), examined at four concentrations, including a new 0.05 percent DAP:PTP sample. By evaluating L band masing media under identical conditions, optimal doping levels and gain materials for high power operation are identified. The optimized system produced room temperature continuous wave masing with a peak output of 2.34 mW (+3.69 dBm), marking the first milliwatt level emission from an organic maser. Spectral coherence times of 465 ns and coherence lengths up to 150 m were obtained. Coupling to a high Q cavity mode enables collective spin photon interactions, with Rabi oscillations revealing coherent ensemble dynamics. Frequency domain analysis shows normal mode splitting of 1.37 MHz for Pc:PTP and 2.14 MHz for DAP:PTP, confirming strong coupling. Cavity QED analysis yields cooperativities C* = 304-803 for Pc:PTP and 405-1071 for DAP:PTP, among the highest for organic systems. Quantitative metrics of signal to noise ratio, spectral coherence distance, and throughput demonstrate the potential of these masers for radar, secure communication, and quantum interface technologies.