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arXiv:2512.14091

Group Theory and Representation Theory for Identical Particles

James Daniel Whitfield

quant-phSubmitted Dec 16, 2025• Announced Dec 17, 2025• 0 citations
arXivHTMLPDF

Abstract

Few, if any, applications of quantum technology are as widely known as the quantum simulation of quantum matter. Consequently, many interesting questions have been sparked at the intersection of condensed matter, quantum chemistry, and quantum computing. Given the common mathematical foundation of these subjects, we walk through the necessary group theory and representation theory serving as background in all of these fields. Our discussion will include a full development of the mathematics of identical particles and the mechanics of describing systems of identical particles in both first and second quantization schemes. This chapter is an offshoot of a larger work that provides a graduate-level introduction to quantum information science. This chapter is being released separately because it is not explicitly focused on quantum information. It has grown beyond a short digression into a full-fledged journey into the symmetries and representations of identical particles that we invite you, the reader, to join.

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his graduate-level text develops the aspects of group theory most relevant to physics and chemistry (such as the theory of representations) and illustrates their applications to quantum mechanics. The first five chapters focus chiefly on the introduction of methods, illustrated by physical examples, and the final three chapters offer a systematic treatment of the quantum theory of atoms, molecules, and solids.The formal theory of finite groups and their representation is developed in Chapters 1 through 4 and illustrated by examples from the crystallographic point groups basic to solid-state
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