Research on strongly correlated electron systems faces a fundamental challenge due to the complex nature of intrinsic many-body correlations. A key strategy to address this challenge lies in advancing experimental methods that can directly probe and elucidate the underlying many-body correlations. In this perspective article, we discuss the theoretically proposed coincidence detection techniques, which are designed to directly measure two-body correlations in various particle-particle and particle-hole channels, with momentum, energy, and/or spatial resolution. We also explore the prospects of these coincidence detection techniques for future theoretical and experimental developments. The successful implementation and refinement of these coincidence detection techniques promise to deliver powerful new approaches for unraveling long-standing puzzles in strongly correlated electron systems, such as the enigmatic mechanism of unconventional superconductivity and the long-sought quantum spin liquids. Furthermore, these coincidence detection techniques will offer powerful new methods to investigate novel phenomena like itinerant magnetism and electronic nematicity in quantum materials.
Research on strongly correlated electron systems faces a fundamental challenge due to the complex nature of intrinsic many-body correlations. A key strategy to address this challenge lies in advancing experimental methods that can directly probe and elucidate the underlying many-body correlations. In this perspective article, we discuss the theoretically proposed coincidence detection techniques, which are designed to directly measure two-body correlations in various particle-particle and particle-hole channels, with momentum, energy, and/or spatial resolution. We also explore the prospects of these coincidence detection techniques for future theoretical and experimental developments. The successful implementation and refinement of these coincidence detection techniques promise to deliver powerful new approaches for unraveling long-standing puzzles in strongly correlated electron systems, such as the enigmatic mechanism of unconventional superconductivity and the long-sought quantum spin liquids. Furthermore, these coincidence detection techniques will offer powerful new methods to investigate novel phenomena like itinerant magnetism and electronic nematicity in quantum materials.
Abstract It is one challenge to develop experimental techniques for direct detection of the many-body correlations of strongly correlated electrons, which exhibit a variety of unsolved mysteries. In this article, we present a post-experiment coincidence counting method and propose two post-experiment coincidence detection techniques, post-experiment coincidence angle-resolved photoemission spectroscopy and post-experiment coincidence inelastic neutron scattering. By coincidence detection of two photoelectric processes or two neutron-scattering processes, the post-experiment coincidence detection techniques can detect directly the two-body correlations of strongly correlated electrons in particle-particle channel or two-spin channel. The post-experiment coincidence detection techniques can be implemented upon the pulse -resolved angle-resolved photoemission spectroscopy or inelastic neutron scattering experimental apparatus with pulse photon or neutron source. When implemented experimentally, they will be powerful techniques to study the highly esoteric high-temperature superconductivity and the highly coveted quantum spin liquids.
In the study of strongly correlated electrons, one of the challenging core tasks is to develop the potential techniques for direct detection of the many-body correlations of strongly correlated electrons. The(γ,2e)photoemission technique has been developed to investigate the two-body correlations of the target correlated electrons. In this article, we will focus on this technique for the correlated electrons near the Fermi energy in condensed matter. The coincidence detection probability of the two emitted electrons in the(γ,2e)photoemission measurement is shown to be relevant to a two-body Bethe-Salpeter wave function, which describes the dynamical two-body correlations of the target correlated electrons near the Fermi energy. As the coincidence detection probability involves an electron-electron interaction matrix element, the arbitrary momentum and/or energy transfer due to this electron-electron interaction makes the(γ,2e)photoemission technique fail to reveal the inner-pair structures of the two-body Bethe-Salpeter wave function. However, the center-of-mass momentum and energy of the two-body Bethe-Salpeter wave function can be distinctly resolved. Thus, the(γ,2e)photoemission technique can provide the center-of-mass physics of the two-body correlations of the target correlated electrons. It will be one potential technique to study the center-of-mass physics of the Cooper pairs in superconductor.
The study of strongly correlated materials remains one of the most challenging and active frontiers in condensed matter physics. In these systems, the intricate interplay between electrons' kinetic energy and their mutual Coulomb repulsion gives rise to a plethora of exotic phenomena, from high-temperature superconductivity to giant magnetoresistance, which cannot be explained by conventional one-electron theories. This necessitates the development and application of advanced theoretical and computational methods capable of capturing the essential physics of strong electronic correlations. A diverse array of numerical and analytical techniques has been developed to tackle the many-body problem. However, no single method serves as a panacea; each comes with its own set of strengths and weaknesses, and their domains of applicability vary significantly. The choice of an appropriate approximation is therefore highly dependent on the specific physical system and the scientific question at hand. Different problems may benefit from different, and sometimes complementary, methodological perspectives. This thesis focuses primarily on the application and development of local or quasi-local approaches. The rationale for this focus is rooted in the physical reality of many key correlated materials, such as transition metal oxides, heavy-fermion systems or molecular solids like alkali-doped fullerenes, where the local on-site electronic interaction is the dominant energy scale. By prioritizing the accurate treatment of local physics, these methods provide a robust and computationally efficient approximation for understanding a wide range of material properties. Recent experimental and theoretical advancements—spanning the rich physics of multiorbital compounds, the precise control over interactions in ultracold atomic gases, and the complex interplay in electron-phonon coupled systems—have created an urgent need for theoretical frameworks that can deliver reliable and rapid insights. The methods explored in this work are meant to address these challenges, offering a balance between accuracy and computational feasibility. Given the variety of topics addressed, from methodological developments to their application in diverse physical contexts, this thesis will try to be as detailed and self-contained as necessary, providing a clear exposition of the underlying concepts and technical aspects.
Abstract The detection and certification of entanglement and quantum correlations in materials is of fundamental and far‐reaching importance, and has seen significant recent progress. It impacts both the understanding of the basic science of quantum many‐body phenomena as well as the identification of systems suitable for novel technologies. Frameworks suitable to condensed matter that connect measurements to entanglement and coherence have been developed in the context of quantum information theory. These take the form of entanglement witnesses and quantum correlation measures. The underlying theory of these quantities, their relation to condensed matter experimental techniques, and their application to real materials are comprehensively reviewed. In addition, their usage in, e.g., protocols, the relative advantages and disadvantages of witnesses and measures, and future prospects in, e.g., correlated electrons, entanglement dynamics, and entangled spectroscopic probes, are presented. Consideration is given to the interdisciplinary nature of this emerging research and substantial ongoing progress by providing an accessible and practical treatment from fundamentals to application. Particular emphasis is placed on quantities accessible to collective measurements, including by susceptibility and spectroscopic techniques. This includes the magnetic susceptibility witness, one‐tangle, concurrence and two‐tangle, two‐site quantum discord, and quantum coherence measures such as the quantum Fisher information.
Entanglement, a key resource of emerging quantum technologies, describes correlations between particles that defy classical physics. It has been studied extensively on various platforms, but has remained elusive in electron microscopy. Transmission electron microscopes are well-established tools for materials characterisation with unparalleled spatial resolution. They provide control over the preparation and detection of high energy electrons, with largely unexploited potential in the study of many-body quantum correlations. Here, we demonstrate entanglement in electron-photon pairs generated via cathodoluminescence in a transmission electron microscope. Employing coincidence imaging techniques adapted from photonic quantum optics, we reconstruct both near- and far-field ``ghost'' images of periodic transmission masks. By measuring spatial and momentum correlations, we show a violation of the classical uncertainty bound: Δx−2Δk+2=0.502±0.047<1. Hence, we demonstrate entanglement in position and momentum -- the continuous variables at the base of most imaging methods, bridging the fields of electron microscopy and quantum optics. Our work paves the way for exploring quantum correlations in free-electron systems and their application to quantum-enhanced imaging techniques on the nanoscale.
High-temperature superconductivity, a fundamental topic in condensed matter physics, presents one of the critical scientific challenges of this century. The potential for breakthroughs in this field not only promises to reveal numerous novel quantum phenomena and deepen our understanding of quantum many-body physics but also to significantly drive advancements in experimental techniques, theories, and methodologies in probing correlated quantum systems. More importantly, as a non-perturbative quantum system, high-temperature superconductivity offers an ideal platform and a crucial driving force for systematically establishing non-perturbative quantum field theory. Currently, research on high-temperature superconductivity stands at a critical turning point. Achieving significant breakthroughs requires the development of cutting-edge detection technologies built upon novel concepts, the establishment of innovative theoretical frameworks and methodologies, and insightful elucidation of the physical pictures revealed by experimental findings. Such extensive exploration is vital for unveiling fundamental relationships and identifying the governing principles. By integrating these efforts, we can gain profound insights into the mechanisms of high-temperature superconductivity and significantly expand the horizons of quantum many-body theory.