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arXiv:2510.15341

Generalized Boundary Conditions for the qBounce Experiment

Eric J. Sung, Benjamin Koch, Tobias Jenke, H. Abele, Denys I. Bondar

Published Oct 17, 2025• 0 citations
arXivHTMLPDF

Abstract

Discrepancies between theory and recent qBounce data have prompted renewed scrutiny of how boundary conditions are implemented for ultracold neutrons bouncing above a mirror in Earth's gravity. We apply the theory of self-adjoint extensions to the linear gravitational potential on the half-line and derive the most general boundary condition that renders the Hamiltonian self-adjoint. This introduces a single real self-adjoint parameter $λ$ that continuously interpolates between the Dirichlet case and more general (Robin-type) reflecting surfaces. Building on this framework, we provide analytical expressions for the energy spectrum, eigenfunctions, relevant matrix elements, and a set of sum rules valid for arbitrary $λ$. We show how nontrivial boundary conditions can bias measurements of $g$ and can mimic or mask putative short-range ''fifth-force''. Our results emphasize that enforcing self-adjointness-and modeling the correct boundary physics-is essential for quantitative predictions in gravitational quantum states. Beyond neutron quantum bounces, the approach is broadly applicable to systems where boundaries and self-adjointness govern the observable spectra and dynamics.

DOI
10.48550/arxiv.2510.15341

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Discrepancies between theory and recent qBounce data have prompted renewed scrutiny of how boundary conditions are implemented for ultracold neutrons bouncing above a mirror in Earth's gravity. We apply the theory of self-adjoint extensions to the linear gravitational potential on the half-line and derive the most general boundary condition that renders the Hamiltonian self-adjoint. This introduces a single real self-adjoint parameter λλλ that continuously interpolates between the Dirichlet case and more general (Robin-type) reflecting surfaces. Building on this framework, we provide analytical expressions for the energy spectrum, eigenfunctions, relevant matrix elements, and a set of sum rules valid for arbitrary λλλ. We show how nontrivial boundary conditions can bias measurements of ggg and can mimic or mask putative short-range ''fifth-force''. Our results emphasize that enforcing self-adjointness-and modeling the correct boundary physics-is essential for quantitative predictions in gravitational quantum states. Beyond neutron quantum bounces, the approach is broadly applicable to systems where boundaries and self-adjointness govern the observable spectra and dynamics.
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Observation of neutron gravitational quantum states En=mgzn{E}_{n}=mg{z}_{n}En​=mgzn​ in the peV energy range (z1{z}_{1}z1​ is about $10\text{ }\text{ }\ensuremath{\mu}\mathrm{m}$ in the vertical direction) in the experiment conducted at Laue-Langevin Institute, Grenoble, with ultracold neutrons was recently reported in a series of publications. The purpose of the present work is to analyze the experiment. The experimental apparatus is designed to measure a transmission function T(za)T({z}_{a})T(za​), namely, a horizontal flux of relatively fast neutrons ($k\ensuremath{\gg}{k}_{z}$ in wavelength terms) passing through a slit of variable height za{z}_{a}za​ of upper absorbing wall. The quantum states in question are defined by the so-called Airy functions, which are solutions to the stationary 1D equation for a neutron ``bouncing'' above the perfect mirror in a linear potential field. The Airy functions describe the quantum bouncer (QB), the concept of which is subject to theoretical study of toy 1D models of gravitationally bound particles in nonrelativistic quantum mechanics (QM). This is essentially different from the 3D nonstationary QM object, ``the running QB,'' investigated in the experiment. The authors assume that there is a connection between T(za)T({z}_{a})T(za​) and the probability density distribution P(z,za)P(z,{z}_{a})P(z,za​) for QB states. They devised the ``phenomenological model,'' in which the quantum pattern should be visible in the transmission curve. We argue, however, that the measured curve T(za)T({z}_{a})T(za​) is not sensitive to QB states. Instead, it is sensitive to dynamics of neutron horizontal transport inside the absorbing slit for neutrons of energy values about 105{10}^{5}105 times greater than eigenvalues En{E}_{n}En​. The latter are related to the neutron transverse mode kz{k}_{z}kz​ and cannot be termed ``energies of neutron gravitational quantum states.'' We conclude that the experiment setup and real conditions are not adequate to the claimed objective, and the methodology of measured data treatment is flawed. The authors' claim that ``neutron gravitational quantum states are observed'' is neither theoretically nor experimentally substantiated. Final, statistically significant results of the experiment are consistent with our physical reasoning that the experiment is not sensitive to ``neutron gravitational quantum states'' (in terms of Airy mode) and does not prove even their existence in rigorous quantum-mechanical terms.
We propose to apply Ramsey's method of separated oscillating fields to the spectroscopy of the quantum states in the gravity potential above a horizontal mirror. This method allows a precise measurement of quantum mechanical phaseshifts of a Schr\"odinger wave packet bouncing off a hard surface in the gravitational field of the Earth. Measurements with ultracold neutrons will offer a sensitivity to Newton's law or hypothetical short-ranged interactions, which is about 21 orders of magnitude below the energy scale of electromagnetism.
A theory of gravitational quantum states of ultracold neutrons in waveguides with absorbing/scattering walls is presented. The theory covers recent experiments in which the ultracold neutrons were beamed between a mirror and a rough scatterer/absorber. The analysis is based on a recently developed theory of quantum transport along random rough walls which is modified in order to include leaky (absorbing) interfaces and, more importantly, the low-amplitude high-aperture roughness. The calculations are focused on a regime where the direct transitions into the continuous spectrum above the absorption threshold dominate the depletion of neutrons from the gravitational states and are more efficient than the processes involving the intermediate states. The theoretical results for the neutron count are sensitive to the correlation radius (lateral size) of surface inhomogeneities and to the ratio of the particle energy to the absorption threshold in the weak-roughness limit. The main impediment for observation of the higher gravitational states is the ``overhang'' of the particle wave functions which can be overcome only by using scatterers with strong roughness. In general, strong roughness with high amplitude is preferable if one wants just to detect the individual gravitational states, while strong-roughness experiments with small amplitude and high aperture are preferable for the quantitative analysis of the data. We also discuss ways to further improve the accuracy of calculations and to optimize the experimental regime.