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arXiv:2509.12706 · Physical review. B./Physical review. B

Systematic Schrieffer-Wolff transformation approach to Josephson junctions: Quasiparticle effects and Josephson harmonics

Ádám Bácsi, Teodor Iličin, Rok Žitko

Published Jan 13, 2026• 2 citations
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Abstract

We use the Schrieffer-Wolff transformation (SWT) to analyze Josephson junctions between superconducting leads described by the charge-conserving BCS theory. Starting from the single-electron tunneling terms, we directly recover the conventional effective Hamiltonian, $-E_J\cos\hatφ$, with an operator-valued phase bias $\hatφ$. The SWT approach has the advantage that it can be systematically extended to more complex scenarios. We show that if a Bogoliubov quasiparticle is present its motion couples to that of Cooper pairs, introducing correlated dynamics that reshape the energy spectrum of the junction. Furthermore, higher-order terms in the SWT naturally describe Josephson harmonics, whose amplitudes are directly related to the microscopic properties of the superconducting leads and the junction. We derive expressions that could facilitate tuning the ratio between the different harmonics in a controlled way.

DOI
10.1103/jfcl-7pzt

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•Aug 21, 2026•0 citations
We use the Schrieffer-Wolff transformation (SWT) to analyze Josephson junctions between superconducting leads described by the charge-conserving BCS theory. Starting from the single-electron tunneling terms, we directly recover the conventional effective Hamiltonian, −EJcos⁡φ^-E_J\cos\hatφ−EJ​cosφ^​, with an operator-valued phase bias φ^\hatφφ^​. The SWT approach has the advantage that it can be systematically extended to more complex scenarios. We show that if a Bogoliubov quasiparticle is present its motion couples to that of Cooper pairs, introducing correlated dynamics that reshape the energy spectrum of the junction. Furthermore, higher-order terms in the SWT naturally describe Josephson harmonics, whose amplitudes are directly related to the microscopic properties of the superconducting leads and the junction. We derive expressions that could facilitate tuning the ratio between the different harmonics in a controlled way.
We describe in this paper how the nonlinear Josephson inductance is the crucial circuit element for all Josephson qubits. We discuss the three types of qubit circuits, and show how these circuits use this nonlinearity in unique manners. We give a brief derivation of the BCS theory, highlighting the appearance of the macroscopic phase parameter. The Josephson equations are derived using standard first and second order perturbation theory that describe quasiparticle and Cooper-pair tunneling. An exact calculation of the Josephson effect then follows using the quasiparticle bound-state theory, and then expand upon this theory to describe quasiparticle excitations as transitions from the ground to excited bound states from nonadiabatic changes in the bias. Although quasiparticle current is typically calculated only for a constant DC voltage, the advantage to this approach is seen where we qualitatively describe quasiparticle tunneling with AC voltage excitations, as appropriate for the qubit state. This section describes how the Josephson qubit is typically insensitive to quasiparticle damping, even to the extent that a phase qubit can be constructed from microbridge junctions.
We have analyzed and proposed coupling mechanisms between Three Josephson Junction Flux Qubits (3JJQ). For this, we have developed a numerical method to extract the effective Hamiltonian of a system of coupled qubits via the Schrieffer-Wolff transformation (SWT). We then give a comprehensive introduction to the 3JJQ, and study it analytically by approximating its potential with a Harmonic well. With a clear understanding of the 3JJQs, we use the SWT to gain intuition about their effective dipolar interaction with the electromagnetic field, and use that intuition to propose and study analytically and numerically the capacitive coupling of two 3JJQs via a non-tunable capacitor, and the inductive coupling of two 3JJQs via a tunable Josephson Junction (dc-SQUID), showing that we are able to reproduce non-stoquastic Hamiltonians in the strong-coupling regime.
We investigate quasiparticle tunneling in a Cooper-pair box which is embedded in a superconducting ring to allow control of the total phase difference across the island. The phase affects the transition rate between different electron number parity states of the island, which can be observed in experiment by established means. The phase dependence also leads to what is known as the $\mathrm{cos}\ensuremath{\phi}$ term in the tunneling characteristics of classical Josephson junctions. This effect has remained controversial for decades; the proposed scheme opens an independent way to probe it.
Josephson junctions are the central nonlinear element of superconducting qubits, yet their standard description is reached through a chain of approximations. We propose a purely quantum-mechanical model of the junction, formulated directly in Hilbert space: a charged particle moves on a one-dimensional loop, and the junction is a point at which the wave function obeys self-adjoint boundary conditions, labelled by a coupling strength λλλ, which controls the transparency of the junction, and a phase jump δδδ, which plays the role of the superconducting phase difference. For a loop with a single junction we solve the spectral problem and show that the ground-state momentum expectation, identified with the supercurrent, factorises exactly as ⟨p^0⟩=Ic(δ,λ)sin⁡δ\langle\hat{p}_0\rangle = I_c(δ,λ)\sinδ⟨p^​0​⟩=Ic​(δ,λ)sinδ. For opaque junctions IcI_cIc​ becomes independent of δδδ and the first Josephson relation I=Icsin⁡δI=I_c\sinδI=Ic​sinδ is recovered; for strongly attractive coupling, where the ground state is bound to the junction, the sin⁡δ\sinδsinδ law is also recovered, but with an exponentially suppressed amplitude. For more transparent junctions, however, the model \emph{predicts} deviations from the pure sin⁡δ\sinδsinδ law: IcI_cIc​ acquires a dependence on δδδ already at order λ−2λ^{-2}λ−2, compatible with the higher Josephson harmonics recently found necessary to describe superconducting qubit spectra, and a fully transparent contact yields a current linear in δδδ. When the phase varies in time, a gauge transformation shows that the voltage drop across the junction is proportional to δ˙\dotδδ˙, so that the second Josephson relation emerges without being imposed. The boundary-condition approach thus reproduces both Josephson relations from first principles and predicts corrections to them, offering a route towards higher-fidelity models of superconducting qubits.
We developed a weak-linked Josephson junction time-domain simulation tool based on the Bardeen-Cooper-Schrieffer (BCS) theory to account for the electrodynamics of Cooper pairs and quasiparticles in the presence of thermal noise. The model, based on Werthamer and Harris formalisms, allows us to describe the behavior of Josephson junctions for various current and/or voltage input waveforms, analog or digital, and for any operating temperature below the critical temperature of the superconducting materials. We show a good agreement between experimental and simulated IV curves of Josephson junctions, as well as a relative increase of the grey zone width of an SFQ balanced comparator between 4 and 20% due to the presence of quasiparticles, for McCumber parameters comprised between 0.1 and 1, respectively.
Superconducting circuits are one of the leading candidates for scalable quantum computation, owing to their long coherence time and compatibility with fabrication techniques. Despite their experimental success, the conventional theoretical framework for superconducting circuit quantisation relies on a semiclassical procedure that requantises the phenomenological Ginzburg-Landau order parameter, introducing the postulated canonical relations and leaving the microscopic origins of circuit parameters hidden. In the present thesis, we develop a rigorous and first-principles approach for the quantisation of superconducting circuits, directly grounded in Bardeen-Cooper-Schrieffer (BCS) theory for superconductivity, and extend this framework to investigate the dynamics of the superconducting Higgs amplitude mode. The central methodological contribution of this work is a projective approach, in which the full many-body electronic Hamiltonian of a superconducting system is projected onto a carefully constructed low-energy BCS Hilbert space, HBCS, spanned by phase parameterised BCS ground states. We systematically characterise the kinematic properties of this subspace, quantify the orthogonality and completeness of the phase basis via the BCS overlap and the projection error, and show that the effective dimensionality of the space is scaled as the square root of the number of single electronic modes. This approach does not impose a spontaneously broken symmetry so that it consistently describes quantised circuits that support superpositions of phases, and the canonical commutation relations between phase and number are derived from the underlying fermionic commutation properties, rather than imposed. This establishes the fully quantum mechanical foundation upon which the standard circuit quantisation approach implicitly rests. The projective formalism is subsequently applied to derive the effective Hamiltonian for superconducting circuit elements. For point-like elements, \eg, capacitive islands and Josephson junctions, projection of the fermionic Hamiltonian onto HBCS yields analytical expressions for the charging energy and the Josephson energy in terms of microscopic material parameters. The resulting Hamiltonian reproduces the standard Cooper-pair-box and transmon Hamiltonians, but now on an unambiguous microscopic footing. We further extend the approach to spatially distributed elements. Inductance is derived from the constitutive response to spatially varying phase torsion in a superconducting wire, yielding the lumped-element inductive energy from first principles. This analysis also identifies the emergent low-energy Hilbert space of the inductor. Combining the results, a complete microscopic derivation of the standard superconducting inductance-capacitance-junction (LCJ) circuit Hamiltonian is recovered. The final part of this thesis extends the projective methodology to the superconducting Higgs mode associated to the amplitude dynamics of the superconducting order parameter. A general BCS space parameterised by phase and gap amplitude is constructed, onto which we project the microscopic Hamiltonian. This yields a generalised eigenvalue problem governing the dynamics of the gap amplitude. The Higgs mode of a superconducting island is thereby shown to behave as a quantum harmonic oscillator. We derive the analytical expressions for the superconducting Higgs mass, spring constant, and oscillation frequency of the gap dynamics. While our results reveal a logarithmic correction to the Higgs frequency reported in previous literature, we numerically validate these results, and compute quantum anharmonic corrections to the Higgs frequency for higher excitations. This thesis proposes a novel, formal and quantitative circuit quantisation theory for superconducting circuits, based on which we explore the Higgs amplitude mode dynamics. The approach is capable of resolving the fundamental question about the compactness of superconducting phase and is extendable to cover quasiparticle contributions. This microscopic circuit theory equips us with a new tool to understand superconducting devices at a level of microscopic detail inaccessible to the standard semiclassical framework, paving the way for a principled treatment of quasiparticle losses and the exploration of exotic superconducting circuit elements.