We explore the framework based on the Kirkwood-Dirac quasiprobability distribution to quantify the contribution of coherence to work extraction during generic, cyclic quantum evolutions. In particular, we focus on "anomalous processes," counterintuitive scenarios in which, due to the negativity of the quasiprobability distribution, work can be extracted even when individual processes are associated with energy gain. Applying this framework to qubits undergoing sequences of single- and two-qubit gate operations, we identify specific conditions under which such anomalous work exchanges occur. Furthermore, we analyze the quasiprobabilistic structure of deep quantum circuits and establish a compositional relation linking the work statistics of full circuits to those of their constituent gates. Our work highlights the role of coherence in the thermodynamics of basic elements of quantum computation and provides a foundation for systematically studying potential thermodynamic relevance of specific quantum circuits.
We explore the framework based on the Kirkwood-Dirac quasiprobability distribution to quantify the contribution of coherence to work extraction during generic, cyclic quantum evolutions. In particular, we focus on "anomalous processes," counterintuitive scenarios in which, due to the negativity of the quasiprobability distribution, work can be extracted even when individual processes are associated with energy gain. Applying this framework to qubits undergoing sequences of single- and two-qubit gate operations, we identify specific conditions under which such anomalous work exchanges occur. Furthermore, we analyze the quasiprobabilistic structure of deep quantum circuits and establish a compositional relation linking the work statistics of full circuits to those of their constituent gates. Our work highlights the role of coherence in the thermodynamics of basic elements of quantum computation and provides a foundation for systematically studying potential thermodynamic relevance of specific quantum circuits.
We employ the operational quasiprobability (OQ) as a work distribution, which reproduces the Jarzynski equality and yields the average work consistent with the classical definition. The OQ distribution can be implemented through two simple experimental settings: the end-point measurement and the two-point measurement. Using this framework, we demonstrate the explicit contribution of coherence to the work, which can be formulated by the second-law-type relation. In a two-level system, we show that nonjoint measurability, a generalized notion of measurement incompatibility, can increase the amount of extractable work beyond the classical bound imposed by jointly measurable measurements. We further prove that the real part of Kirkwood-Dirac quasiprobability (KDQ) and the OQ are equivalent in two-level systems, and they are non-negative for binary unbiased measurements if and only if the measurements are jointly measurable. In a three-level nitrogen-vacancy center system, the OQ and the KDQ exhibit different amounts of negativities while enabling the same work extraction, implying that the magnitude of negativity is not a faithful indicator of nonclassical work. These results highlight that coherence and nonjoint measurability play fundamental roles in the enhancement of work.
Gate-based quantum computers are an innovative tool for experimentally studying the core principles of quantum mechanics. This work presents the first observation of quantum anomalous heat flow between two qubits and investigates the role of mid-circuit measurements in this context. Using mid-circuit measurements, we designed quantum circuits that violate the semi-classical heat flow bound, witnessing negativities in the underlying Kirkwood-Dirac quasiprobability distribution, which indicates the presence of quantum correlations between the subsystems. Mid-circuit measurements, crucial for probing qubits during the experiment, enabled these observations but also introduced disturbances, such as energy leakage, leading to deviations from theoretical predictions. We modeled these noise effects, providing insight into the limitations of current mid-circuit measurement techniques.
In this tutorial, we present the definition, interpretation, and properties of some of the main quasiprobabilities that can describe the statistics of measurement outcomes evaluated at two or more times. Such statistics incorporate the incompatibility of the measurement observables and the state of the measured quantum system. We particularly focus on Kirkwood-Dirac quasiprobabilities and related distributions. We also discuss techniques to experimentally access a quasiprobability distribution, ranging from the weak two-point measurement scheme, to a Ramsey-like interferometric scheme and procedures assisted by an external detector. Once defined the fundamental concepts following the standpoint of joint measurability in quantum mechanics, we illustrate the use of quasiprobabilities in quantum thermodynamics to describe the quantum statistics of work and heat, and to explain anomalies in the energy exchanges entailed by a given thermodynamic transformation. On the one hand, in work protocols, we show how absorbed energy can be converted to extractable work and vice versa due to Hamiltonian incompatibility at distinct times. On the other hand, in exchange processes between two quantum systems initially at different temperatures, we explain how quantum correlations in their initial state may induce cold-to-hot energy exchanges, which are unnatural between any pair of equilibrium nondriven systems. We conclude the tutorial by giving simple examples where quasiprobabilities are applied to many-body systems: scrambling of quantum information, sensitivity to local perturbations, and quantum work statistics in the quenched dynamics of models that can be mapped onto systems of free fermions, for instance, the Ising model with a transverse field. Throughout the tutorial, we meticulously present derivations of essential concepts alongside straightforward examples, aiming to enhance comprehension and facilitate learning. Published by the American Physical Society 2024
A key concept in quantum thermodynamics is extractable work, which specifies the maximum amount of work that can be extracted from a quantum system. Different quantities are used to measure extractable work, the most prevalent of which are ergotropy and the difference between the non-equilibrium and equilibrium quantum free energies. Using the latter, we investigate the evolution of extractable work when an open quantum system undergoes a general quantum process described by a completely-positive and trace-preserving dynamical map. We derive a fundamental equation of thermodynamics for such processes as a relation between the distinct sorts of energy change in such a way that the first and the second law of thermodynamics are combined. We then identify the contributions from the reversible and irreversible processes in this equation and demonstrate that they are respectively responsible for the evolution of heat and extractable work of the open quantum system. Furthermore, we show how this correspondence between irreversibility and extractable work has the potential to provide a clear explanation of how the quantum properties of a system affect its extractable work evolution. Specifically, we establish this by directly connecting the change in extractable work with the change in standard quantifiers of quantum non-Markovianity and quantum coherence during a general quantum process. We illustrate these results with two examples.
We investigate the non-equilibrium work statistics originating from a sudden quench in a bosonic Josephson junction. In particular, by employing the Holstein-Primakoff approximation, the work statistics are analytically characterized in the weak-interaction regime, where the dynamics map onto a time-dependent quantum harmonic oscillator. For a junction initialized in the ground state of the pre-quench Hamiltonian, we demonstrate that the work statistics are governed by a negative binomial distribution, as occurs in fully-connected models driven across a critical point. Furthermore, we also consider initial superposition states containing quantum coherences in the energy basis. To characterize the corresponding work distributions, we employ Kirkwood-Dirac quasiprobabilities (KDQ). Even in the simplest case, when the junction is initialized in a superposition of the ground and second excited states, the KDQ distribution of work exhibits negative or complex values, reflecting non-classical features. Moreover, the coherence content of the initial state can be optimized to enhance the extractable work extracted from the quench, beyond classical bounds. Finally, we propose an experimental interferometric protocol to directly measure the characteristic function of the work distribution in experimentally accessible settings.
Abstract Gate‐based quantum computers are an innovative tool for experimentally studying the core principles of quantum mechanics. This work presents the first observation of quantum anomalous heat flow between two qubits and investigates the role of mid‐circuit measurements in this context. Using mid‐circuit measurements, we designed quantum circuits that violate the semi‐classical heat flow bound, witnessing negativities in the underlying Kirkwood‐Dirac quasiprobability distribution, which indicates the presence of quantum correlations between the subsystems. Mid‐circuit measurements, crucial for probing qubits during the experiment, enabled these observations but also introduced disturbances, such as energy leakage, leading to deviations from theoretical predictions. These noise effects were modeled, providing insight into the limitations of current mid‐circuit measurement techniques.