Many important quantities in quantum information science, such as entropy and entanglement, are non-linear functions of the density matrix and cannot be expressed as operator observables. Standard open-system approaches evolve only a single copy of the density matrix, making it impossible to track the dynamics of such quantities. A formalism proposed by some of the present authors addressed this challenge by evolving multiple virtual replicas, but was limited to the weak-coupling regime. Here, we extend this approach to strong coupling between a quantum system and classical environments. The resulting multi-replica master equation enables direct evaluation of entropy flow and related metrics in strongly hybridized quantum-classical systems. Our results show that quantum coherence and hybridization jointly suppress net entropy transfer, creating a thermodynamic bottleneck. This framework provides a general tool for studying entropy dynamics and guiding the design of more robust, resource-efficient quantum hardware.
Many important quantities in quantum information science, such as entropy and entanglement, are non-linear functions of the density matrix and cannot be expressed as operator observables. Standard open-system approaches evolve only a single copy of the density matrix, making it impossible to track the dynamics of such quantities. A formalism proposed by some of the present authors addressed this challenge by evolving multiple virtual replicas, but was limited to the weak-coupling regime. Here, we extend this approach to strong coupling between a quantum system and classical environments. The resulting multi-replica master equation enables direct evaluation of entropy flow and related metrics in strongly hybridized quantum-classical systems. Our results show that quantum coherence and hybridization jointly suppress net entropy transfer, creating a thermodynamic bottleneck. This framework provides a general tool for studying entropy dynamics and guiding the design of more robust, resource-efficient quantum hardware.
Abstract Many of the quantities that matter in quantum technology, e.g. entropy, entanglement, etc., cannot be associated with operator observables, because they depend non-linearly on the quantum state’s density matrix. The non-linearity provokes another bigger issue: Standard open-system equations evolve just one copy of that matrix, so we cannot track how such elusive quantities change. A recent formalism by Ansari and Nazarov sidestepped this by evolving multiple virtual replicas at once, but only in the weak-coupling regime. Here, we remove that limitation. Our generalized, multi-replicative master equation follows entropy flow and other vital metrics even when a quantum device interacts strongly with a classical environment. We show quantum coherence and hybridization jointly act to inhibit the net transfer of entropy, effectively introducing a “bottleneck” in the thermodynamic process. This sharper view of quantum–classical hybridization points the way toward more robust, resource-aware quantum hardware.
Currently, ‘time’ does not play any essential role in quantum information theory. In this sense, quantum information theory is underdeveloped similarly to how quantum physics was underdeveloped before Erwin Schrödinger introduced his famous equation for the evolution of a quantum wave function. In this review article, we cope with the problem of time for one of the central quantities in quantum information theory: entropy. Recently, a replica trick formalism, the so-called ‘multiple parallel world’ formalism, has been proposed that revolutionizes entropy evaluation for quantum systems. This formalism is one of the first attempts to introduce ‘time’ in quantum information theory. With the total entropy being conserved in a closed system, entropy can flow internally between subsystems; however, we show that this flow is not limited only to physical correlations as the literature suggest. The nonlinear dependence of entropy on the density matrix introduces new types of correlations with no analogue in physical quantities. Evolving a number of replicas simultaneously makes it possible for them to exchange particles between different replicas. We will summarize some of the recent news about entropy in some example quantum devices. Moreover, we take a quick look at a new correspondence that was recently proposed that provides an interesting link between quantum information theory and quantum physics. The mere existence of such a correspondence allows for exploring new physical phenomena as the result of controlling entanglement in a quantum device.
Considering von Neumann expression for reduced density matrix as thermodynamic entropy of a system strongly coupled to baths, we use nonequilibrium Green's function (NEGF) techniques to derive bath and energy resolved expressions for entropy, entropy production, and information flows. The consideration is consistent with dynamic (quantum transport) description and expressions reduce to expected forms in limiting cases of weak coupling or steady state. Formulation of the flows in terms of only system degrees freedom is convenient for simulation of thermodynamic characteristics of open nonequilibrium quantum systems. We utilize standard NEGF for derivations in noninteracting systems, Hubbard NEGF is used for interacting systems. Theoretical derivations are illustrated with numerical simulations within generic junction models.
Quantum systems are inherently open to their environment and thus they evolve under the influence of dissipation, decoherence and driving from external fields. This poses a significant theoretical challenge: how to track the dynamics of the system of interest while tracing out environmental degrees of freedom. Markovian master equations offer a longstanding solution to this problem, where under a series of assumptions the reduced density matrix of the system can be obtained. These flexible approaches provide a conceptually and numerically simple framework for describing complex many-body systems. However, the assumptions enforced by Markovian master equations create a gap in the availability of generic, simple, and analytical techniques capable of treating open quantum systems beyond the regimes of standard Markovian master equations. In this thesis, we introduce three studies addressing three regimes that are inaccessible to standard Markovian master equations and investigate their consequences in quantum thermodynamics-inspired applications. We begin by developing a Markovian embedding technique to tackle non-Markovian dynamics induced by the long correlation times of a qubit coupled to a structured environment. Subsequently, we propose an "effective" Hamiltonian theory enabling the study of equilibrium properties of strong coupling to a thermal reservoir through a dressed version of the Gibbs state. This framework can also be applied to address problems of equilibration, transport, quantum thermal machines, and quantum dynamics. Lastly, we showcase the importance of including non-secular terms in the quantum master equation, which results in a drastic separation of timescales leading to rich metastable dynamics. We apply this quantum master equation approach to temperature sensing in a nonequilibrium setting offering an alternative to standard equilibrium probes. Overall, this thesis contributes novel theoretical techniques for tackling open quantum systems beyond standard approximations with applications in quantum thermodynamics.
This paper presents a formal framework framing quantum decoherence as an information-theoretic phase transition at the quantum-to-classical boundary. We demonstrate that environment-induced superselection (einselection) can be characterized as a true dynamical phase transition where the system-environment coupling strength acts as a thermodynamic control parameter, and the suppression of off-diagonal density matrix elements functions as an order parameter analogous to magnetization in the Ising model. Using quantum mutual information, von Neumann entropy, and entanglement entropy, we track the operational flow of information from a quantum system into environmental degrees of freedom, demonstrating how a singular classical reality emerges via the redundant copying of pointer states into environmental fragments—a process governed by Quantum Darwinism. We analyze a simulated spin-boson model and random unitary circuits with tunable dissipation, extracting clear signatures of criticality including power-law scaling and diverging correlation times at a critical threshold . Crucially, we connect this behavior to recent advancements (2023–2025) in mixed-state topological order, establishing that decoherence-induced transitions map onto anyon condensation transitions within an errorfield double formulation. Finally, we explore the foundational implications of this framework: it sharpens the measurement problem via informational symmetry breaking, reframes observation as a high-decoherence thermodynamic limit, and introduces a Gödelian perspective by demonstrating that determining the critical threshold for arbitrary many-body environments is formally undecidable due to the non-computability of the spectral gap in the thermodynamic limit.
A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.