We investigate a simple model exhibiting a prethermal phase, i.e., a metastable state that emerges before full thermalization, through the framework of quantum stochastic thermodynamics. We explore the effects of quantum coherence in the energy eigenbasis of the initial state of the system on the process of heat exchange with a bath, and their contribution to entropy production as quantified by a heat-exchange fluctuation theorem. Such a relation is derived using the end-point measurement scheme, a protocol that accounts for initial quantum coherence in the statistics of energy exchanges resulting from a nonequilibrium process. We compare these results with those obtained from the widely used two-point measurement scheme, which, by construction, fails to capture such quantum effects.
We investigate a simple model exhibiting a prethermal phase, i.e., a metastable state that emerges before full thermalization, through the framework of quantum stochastic thermodynamics. We explore the effects of quantum coherence in the energy eigenbasis of the initial state of the system on the process of heat exchange with a bath, and their contribution to entropy production as quantified by a heat-exchange fluctuation theorem. Such a relation is derived using the end-point measurement scheme, a protocol that accounts for initial quantum coherence in the statistics of energy exchanges resulting from a nonequilibrium process. We compare these results with those obtained from the widely used two-point measurement scheme, which, by construction, fails to capture such quantum effects.
A central open question in quantum thermodynamics is the identification of thermodynamic entropy away from equilibrium. Although thermodynamic entropy coincides with the von Neumann entropy for a Gibbs state at equilibrium, the thermodynamic role of quantum coherence generated during nonequilibrium evolution remains unclear. Here, we show that von Neumann entropy does not, in general, represent the thermodynamic entropy governing heat exchange in coherent nonequilibrium quantum systems. By integrating the resource theory of quantum coherence with thermodynamic principles, we develop a general framework for nonequilibrium quantum thermodynamics. We identify thermodynamic entropy with the energy entropy derived from energy-measurement statistics and introduce a dynamical temperature extending the equilibrium concept to nonequilibrium states. Consequently, we obtain an exact entropy-balance relation separating the entropy flux associated with heat exchange from the coherence-loss contribution to entropy production, establishing an operational connection between quantum coherence, heat flow, and total entropy change. Unlike approaches relying on equilibrium reference states or stationary Gibbs ensembles, our framework uses instantaneous dynamical quantities and remains valid throughout transient nonequilibrium evolution. It provides consistent dynamical definitions of temperature, work, heat, and free energy. Applying the formalism to an exactly solvable open quantum system, we show that the first and second laws hold throughout transient evolution and that equilibrium thermodynamics emerges dynamically in the weak-coupling long-time limit. Our results establish a unified framework for coherent nonequilibrium quantum thermodynamics and suggest opportunities for controlling heat dissipation through coherence engineering in quantum thermal technologies.
The standard approach to deriving fluctuation theorems fails to capture the effect of quantum correlation and coherence in the initial state of the system.Here, we overcome this difficulty and derive the heat-exchange-fluctuation theorem in the full quantum regime by showing that the energy exchange between two locally thermal states in the presence of initial quantum correlations is faithfully captured by a quasiprobability distribution.Its negativities, being associated with proofs of contextuality, are proxies of nonclassicality.We discuss the thermodynamic interpretation of negative probabilities and provide heat-flow inequalities that can only be violated in their presence.Remarkably, testing these fully quantum inequalities, at an arbitrary dimension, is no more difficult than testing traditional fluctuation theorems.We test these results on data collected in a recent experiment studying the heat transfer between two qubits and give examples for the capability of witnessing negative probabilities at higher dimensions.
We study the thermalization dynamics and thermodynamics of a qubit coupled to a structured, memory-carrying environment modeled as a single bosonic mode continuously thermalized by a Markovian bath. The competition between coherent qubit-mode coupling g and thermalization rate κ is controlled by the dimensionless ratio μ=g/κ, which drives a crossover between Markovian and strongly non-Markovian regimes. In the strongly non-Markovian limit, coherent energy exchange produces transient shortcuts to local thermalization, whereby the qubit approaches its thermal state long before global equilibration. In the opposite limit, we derive an original convolution master equation with an exponential memory kernel, which reduces to a thermal GKSL equation as μ→0. The crossover between the two regimes closely mirrors the underdamped-to-overdamped transition of a classical damped oscillator. From the thermodynamic side, we derive an original decomposition of the reduced entropy production in terms of qubit-ancilla mutual information and ancilla relative entropy, providing a quantitative fingerprint of non-Markovian corrections. We then extend this framework to the stochastic level via two monitoring protocols — Fock-state tracking and energy-exchange detection — constructing trajectory-level entropy productions and establishing fluctuation theorems tailored to each scheme. Together, these results demonstrate that a self-consistent stochastic thermodynamics can be formulated for non-Markovian open quantum systems under continuous monitoring.
Quantum fluctuation theorems provide fundamental constraints on entropy production but rely on a trajectory-based description that becomes problematic in the presence of coherence and incompatible measurements. While deviations from standard fluctuation relations in quantum regimes are often attributed to coherence, the precise nonclassical mechanism underlying such effects remains under active discussion. In this work, we investigate contextual interference effects in nonequilibrium thermodynamics using a minimal analytically solvable two-qubit heat-exchange model with a phase-tunable partial-swap interaction. By employing a coherence-preserving Kirkwood–Dirac (KD) quasiprobability formulation of energy exchange, we identify a single correction term, [Formula: see text], that quantifies deviations from the conventional fluctuation-theorem symmetry. We show that this correction originates from interference between incompatible measurement contexts within the degenerate single-excitation subspace and vanishes both in the incoherent limit and at thermal equilibrium. The resulting expression is fully analytic, depends on experimentally tunable parameters, and explicitly connects entropy-current fluctuations to phase-sensitive coherence effects. Our results provide an operationally accessible signature of KD-interference contributions in quantum thermodynamics and demonstrate that coherence, when combined with measurement incompatibility, induces a well-defined correction to fluctuation relations. This establishes a minimal framework linking contextual interference and thermodynamic irreversibility and suggests experimentally feasible routes for probing such effects on current quantum platforms.
Exploiting the relative entropy of coherence, we isolate the coherent contribution in the energetics of a driven nonequilibrium quantum system. We prove that a division of the irreversible work can be made into a coherent and incoherent part. This provides an operational criterion for quantifying the coherent contribution in a generic nonequilibrium transformation on a closed quantum system. We then study such a contribution in two physical models of a driven qubit and kicked rotor. In addition, we also show that coherence generation is connected to the nonadiabaticity of a processes, for which it gives the dominant contribution for slow-enough transformations. The amount of generated coherence in the energy eigenbasis is equivalent to the change in diagonal entropy, and here we show that it fulfills a fluctuation theorem.
Thermodynamics is a phenomenological theory describing the energy conversion of work and heat. At its origins thermodynamics was developed in order to understand and improve heat engines. In conventional thermodynamics, however, only such processes are completely describable which are slow enough to keep the system of interest in an equilibrium state with its thermal environment at all times. On the contrary, all real physical processes are accompanied by non-equilibrium phenomena. These are mathematically described with the help of the irreversible entropy production, i.e. the dissipated work divided by the temperature of the bath. The second law of thermodynamics merely states that the irreversible entropy production is on average always positive. The modern trend of miniaturization, however, leads to smaller and smaller devices. On short length scales thermal noise as well as quantum fluctuations become important. Thus, usual thermodynamic quantities as work and heat acquire stochastic nature. Moreover, in the quantum regime a completely new theory had to be invented, since classical notions of work and heat are no longer valid. The present dissertation contributes to this prevailing field by the derivation of analytical expressions for the entropy production in open and closed quantum system far from thermal equilibrium. The theoretical treatment is motivated by an experimental point of view. The obtained results were derived from the reduced dynamics of the quantum mechanical system, which may be coupled to a thermal bath. To this end, it was dealt with methods and approaches of statistical physics, conventional thermodynamics, quantum information theory and the theory of open quantum systems. In this dissertation the most important physical systems are treated. First, an isolated system is considered before later on a heat bath is included. The limit of weak as well as of strong coupling are analyzed in detail. For isolated systems it turns out that a geometric approach is able to capture the thermodynamic properties, completely. To this end, the irreversible entropy production is sharply estimated from below by the angle between the real non-equilibrium state and the corresponding equilibrium one. Further, it is shown that the Heisenberg uncertainty relation for energy and time can be formulated more precisely in terms of that angle. As experimental system cold ion traps are introduced, in which the theoretical predictions can be verified. For weakly coupled systems, then, the irreversible entropy production is identified and a fluctuation theorem is derived by merely thermodynamic arguments. As experimental system we, again, propose the cold ion traps, where the heat bath can be simulated with the help of LASER light. In the limit of strong coupling a semiclassical description of the reduced quantum system is discussed. Again, an analytically exact expression for the entropy production and the corresponding fluctuation theorem is derived. A physical system, in which strong coupling to the environment can be analyzed, is given by Josephson junctions. This dissertation discusses the entropy production for isolated, weakly coupled, and overdamped quantum systems. For these physical regimes analytical relation are derived and experimental systems proposed, with which the predictions can be verified.