Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Log inSign up
Challenges
Datasets
Workspaces
Papers
Discussions
Leaderboard
Blog
Job Board
Q3AS

© 2026 Aqora Quantum S.A.S.

TermsPrivacyLegal Notice

arXiv:2507.19128 · Physical Review A

Photon condensation from thermal sources and the limits of heat engines

Luísa Toledo Tude, Emily Haughton, Paul R. Eastham

Published Dec 10, 2025• 0 citations
arXivHTMLPDF

Abstract

The trapping and cooling of photon gases in microcavities has been used to create Bose-Einstein condensates. We investigate the conditions required for condensation in dye-filled microcavities, with photon populations created either by driving a transition of the dye, or by coupling the cavity modes to a thermal photon reservoir such as sunlight. We find that the threshold pump temperature, above which condensation appears, is determined by the second law of thermodynamics. The minimum achievable threshold is that of a reversible three-level heat engine, which we show arises in the dye-pumped case, and for pumping of the modes of a two-level cavity. For a many-level cavity condensation occurs at a similar but higher temperature. Our results show that photon condensates can be produced by pumping with incoherent thermal sources, opening possibilities for coherent light generation, energy harvesting, and experimental studies of quantum heat engines.

DOI
10.1103/6lyv-trfj

Related papers

Photon Bose-Einstein Condensation in a Dye-Filled Microcavity

Karindra Perrier

Bose-Einstein condensation (BEC) is the transition to a macroscopic occupation of the ground state of a system of bosonic particles. In 1995 the first experimental realization of BEC was achieved by condensing a dilute atomic gas [1,2]. It was long thought only massive particles could undergo BEC. However, in 2010 it was shown that photon BEC was achieved in an optical dye-filled microcavity [3]. In 2015, we became the second group to successfully repeat these experiments.\n\nBEC is a phase transition and thus it occurs at thermal equilibrium. To achieve a thermal photon gas the cavity is filled with a fluorescent dye solution. The dye molecules thermalize the photons by means of repeated absorption-emission cycles. We optically pump the cavity. With the pump we determine the number of photons absorbed by the dye, consequently defining a nonvanishing chemical potential. This ensures a conserved photon number. The photons are trapped by the harmonic potential induced by the concave cavity mirrors. Due to the cutoff energy determined by the cavity length, the trapped photons have a dispersion similar to that of a massive particle in a quantum harmonic oscillator. The cavity length is tuned such that the free spectral range is larger than the bandwidth of the dye. Therefore, only one longitudinal mode fits inside the cavity, making the photon gas effectively two-dimensional. We end up with a thermalized two-dimensional photon gas that has the eigenenergies of a quantum harmonic oscillator. The Bose-Einstein distribution function predicts a critical photon number. Pumping the thermal photon gas beyond this critical number will lead to photon BEC.\n\nWe measure the spectral- and spatial distributions of our two-dimensional photon gas. In both distributions we observe photon BEC. Results show the characteristics of a phase transition: the appearance of a sharp peak on top of the thermal cloud that coincides with a converging chemical potential to zero. Both the spectral- and spatial distribution are in agreement with the theoretical distribution of photons with an effective mass in a quantum harmonic oscillator. Expansion of the condensate has been measured. This could indicate nonlinear optical effects such as thermal lensing or repulsive photon-photon interactions.

•May 31, 2016•0 citations

Driven-dissipative Bose-Einstein condensation of just a few photons

Benjamin T. Walker

Through trapping light in a dye-filled optical microcavity, one can engineer a gapped band structure for photons, causing them to behave as massive bosons moving in two dimensions. Repeated absorption and emission by the dye can lead to a thermal distribution and Bose- Einstein condensation. In this thesis, I study photonic condensates beyond the equilibrium thermodynamic Bose-Einstein condensation limit in three ways. First, I describe a method for fine control of the trapping potential for light allowing for future study of thermalised light in box potentials and 1D potentials as well as others, expected to show quasi-condensation and possibly superfluid behaviour, rather than ideal Bose-Einstein condensation. Second, I show how this fabrication technique has been used to define tight trapping potentials with only a few thermally accessible energy levels. In these systems, dominance of the ground- state population and build-up of coherence occur at photon numbers less than ten, raising interesting questions about how to define condensation. I discuss these questions through the relevant chapter. Third, pulsed-pump experiments show interesting temporal dynamics including jitter in the formation time of a condensate after a pump pulse due to the stochastic nature of the emission processes involved. I show how the non-stationary two-time correlation function g(2)(t1, t2) is a powerful tool for characterising these temporal dynamics and I interpret the results in a more general framework of the evolution of a probability density function through an effective free energy landscape, driven by drift terms and stochastic forces.

•May 1, 2020•0 citations

Bose-Einstein condensation of photons from the thermodynamic limit to small photon numbers

Robert A. Nyman, Benjamin T. Walker

Photons can come to thermal equilibrium at room temperature by scattering multiple times from a fluorescent dye. By confining the light and dye in a microcavity, a minimum energy is set and the photons can then show Bose–Einstein condensation. We present here the physical principles underlying photon thermalization and condensation, and review the literature on the subject. We then explore the ‘small’ regime where very few photons are needed for condensation. We compare thermal equilibrium results to a rate-equation model of microlasers, which includes spontaneous emission into the cavity, and we note that small systems result in ambiguity in the definition of threshold.

arXiv:1706.09645•Journal of Modern Optics•Nov 23, 2017•16 citations

Bose-Einstein condensation of photons in a 'white-wall' photon box

Jan Klaers, Julian Schmitt, Frank Vewinger +1 more

Bose-Einstein condensation, the macroscopic ground state occupation of a system of bosonic particles below a critical temperature, has been observed in cold atomic gases and solid-state physics quasiparticles. In contrast, photons do not show this phase transition usually, because in Planck's blackbody radiation the particle number is not conserved and at low temperature the photons disappear in the walls of the system. Here we report on the realization of a photon Bose-Einstein condensate in a dye-filled optical microcavity, which acts as a "white-wall" photon box. The cavity mirrors provide a trapping potential and a non-vanishing effective photon mass, making the system formally equivalent to a two-dimensional gas of trapped massive bosons. Thermalization of the photon gas is reached in a number conserving way by multiple scattering off the dye molecules. Signatures for a BEC upon increased photon density are: a spectral distribution that shows Bose-Einstein distributed photon energies with a macroscopically populated peak on top of a broad thermal wing, the observed threshold of the phase transition showing the predicted absolute value and scaling with resonator geometry, and condensation appearing at the trap centre even for a spatially displaced pump spot.

Journal of Physics Conference Series•Jan 10, 2011•1 citation

Thermalization and Gain Clamping in a Photon Bose-Einstein Condensate

M.J. Droste

A system of identical bosons can exhibit a state of matter in which the ground state is macroscopically occupied. This special state is called Bose-Einstein condensation, and was predicted by Satyendra Nath Bose and Albert Einstein in 1924. It took some time before physicists achieved this experimentally, but in 1995 it was done by Eric Cornell and Carl Wieman. Since photons are also bosonic particles, they should be able to achieve Bose-Einstein condensation in thermal equilibrium. However this is not as easy for photons as it is for atoms, since the number of photons depends on the temperature. But in 2010 the group of Martin Weitz in Bonn was able to produce a photon Bose-Einstein condensate. This was done using a dye-filled microcavity which is optically pumped. The same principles are used in our setup. Photons inside the cavity thermalize with a fluorescent dye through multiple absorption and emission cycles. The effectively two-dimensional photon gas is trapped by a harmonic potential induced by the shape of the cavity mirrors. This results in photons with eigenenergies of the quantum harmonic oscillator. The minimal energy is determined by the cutoff frequency, set by the cavity length. The thermalization of the photon gas depends on this cutoff frequency, and the total pump power. Jonathan Keeling and Peter Kirton developed a theoretical model describing this system and its thermalization, and simulated it in one dimension.\nWe simulate the same model, in two dimensions using radially averaged photon modes. Threshold for Bose-Einstein condensation is determined for different cutoff frequencies. Our results show good agreement with those of Keeling and Kirton, below, at and above threshold. Multimode condensation and gain clamping of the molecular excitation density are observed above threshold. Comparison with experimental data can only be done qualitatively since it currently is uncalibrated.

•Jan 1, 2018•0 citations

Thermalization and Effective Interactions in Photon Condensates

Charly Beulenkamp

The experimental realization of a Bose-Einstein condensate of photons, first achieved in 2010 at Bonn University, allowed for new ways to probe the properties of condensates. For thermal light in free space the chemical potential is zero and condensation is not possible. By confining light to a microcavity, the transverse degrees of freedom behave as massive bosons which can have nonzero chemical potential. The gas of thermal photons can be brought to thermalize with a fluorescent dye though absorption and emission cycles. By pumping the dye molecules with a laser, the chemical potential can be increased and the photons will condense. \nWe have built a setup with which we can spatially and spectrally resolve the photon distribution in such a dye-filled microcavity. This allows us to study the shape and occupation of the low energy transverse modes of the cavity. We use this to investigate the thermalization process of the photon gas. A rate equation model is presented and qualitatively compared to experimental data. We find that the photon gas is not in thermal equilibrium.\nWe also investigate effective photon-photon interactions by measuring the spatial extent of the condensate. We find an effective interaction in the form of thermal lensing. As the thermal lensing depends on the interaction between the photon gas and the dye, we find that the model used for thermalization can also make good predictions about effective photon-photon interactions.

•Jan 1, 2018•0 citations
The trapping and cooling of photon gases in microcavities has been used to create Bose-Einstein condensates. We investigate the conditions required for condensation in dye-filled microcavities, with photon populations created either by driving a transition of the dye, or by coupling the cavity modes to a thermal photon reservoir such as sunlight. We find that the threshold pump temperature, above which condensation appears, is determined by the second law of thermodynamics. The minimum achievable threshold is that of a reversible three-level heat engine, which we show arises in the dye-pumped case, and for pumping of the modes of a two-level cavity. For a many-level cavity condensation occurs at a similar but higher temperature. Our results show that photon condensates can be produced by pumping with incoherent thermal sources, opening possibilities for coherent light generation, energy harvesting, and experimental studies of quantum heat engines.
Bose-Einstein condensation (BEC) is the transition to a macroscopic occupation of the ground state of a system of bosonic particles. In 1995 the first experimental realization of BEC was achieved by condensing a dilute atomic gas [1,2]. It was long thought only massive particles could undergo BEC. However, in 2010 it was shown that photon BEC was achieved in an optical dye-filled microcavity [3]. In 2015, we became the second group to successfully repeat these experiments.\n\nBEC is a phase transition and thus it occurs at thermal equilibrium. To achieve a thermal photon gas the cavity is filled with a fluorescent dye solution. The dye molecules thermalize the photons by means of repeated absorption-emission cycles. We optically pump the cavity. With the pump we determine the number of photons absorbed by the dye, consequently defining a nonvanishing chemical potential. This ensures a conserved photon number. The photons are trapped by the harmonic potential induced by the concave cavity mirrors. Due to the cutoff energy determined by the cavity length, the trapped photons have a dispersion similar to that of a massive particle in a quantum harmonic oscillator. The cavity length is tuned such that the free spectral range is larger than the bandwidth of the dye. Therefore, only one longitudinal mode fits inside the cavity, making the photon gas effectively two-dimensional. We end up with a thermalized two-dimensional photon gas that has the eigenenergies of a quantum harmonic oscillator. The Bose-Einstein distribution function predicts a critical photon number. Pumping the thermal photon gas beyond this critical number will lead to photon BEC.\n\nWe measure the spectral- and spatial distributions of our two-dimensional photon gas. In both distributions we observe photon BEC. Results show the characteristics of a phase transition: the appearance of a sharp peak on top of the thermal cloud that coincides with a converging chemical potential to zero. Both the spectral- and spatial distribution are in agreement with the theoretical distribution of photons with an effective mass in a quantum harmonic oscillator. Expansion of the condensate has been measured. This could indicate nonlinear optical effects such as thermal lensing or repulsive photon-photon interactions.
Through trapping light in a dye-filled optical microcavity, one can engineer a gapped band structure for photons, causing them to behave as massive bosons moving in two dimensions. Repeated absorption and emission by the dye can lead to a thermal distribution and Bose- Einstein condensation. In this thesis, I study photonic condensates beyond the equilibrium thermodynamic Bose-Einstein condensation limit in three ways. First, I describe a method for fine control of the trapping potential for light allowing for future study of thermalised light in box potentials and 1D potentials as well as others, expected to show quasi-condensation and possibly superfluid behaviour, rather than ideal Bose-Einstein condensation. Second, I show how this fabrication technique has been used to define tight trapping potentials with only a few thermally accessible energy levels. In these systems, dominance of the ground- state population and build-up of coherence occur at photon numbers less than ten, raising interesting questions about how to define condensation. I discuss these questions through the relevant chapter. Third, pulsed-pump experiments show interesting temporal dynamics including jitter in the formation time of a condensate after a pump pulse due to the stochastic nature of the emission processes involved. I show how the non-stationary two-time correlation function g(2)(t1, t2) is a powerful tool for characterising these temporal dynamics and I interpret the results in a more general framework of the evolution of a probability density function through an effective free energy landscape, driven by drift terms and stochastic forces.
Photons can come to thermal equilibrium at room temperature by scattering multiple times from a fluorescent dye. By confining the light and dye in a microcavity, a minimum energy is set and the photons can then show Bose–Einstein condensation. We present here the physical principles underlying photon thermalization and condensation, and review the literature on the subject. We then explore the ‘small’ regime where very few photons are needed for condensation. We compare thermal equilibrium results to a rate-equation model of microlasers, which includes spontaneous emission into the cavity, and we note that small systems result in ambiguity in the definition of threshold.
Bose-Einstein condensation, the macroscopic ground state occupation of a system of bosonic particles below a critical temperature, has been observed in cold atomic gases and solid-state physics quasiparticles. In contrast, photons do not show this phase transition usually, because in Planck's blackbody radiation the particle number is not conserved and at low temperature the photons disappear in the walls of the system. Here we report on the realization of a photon Bose-Einstein condensate in a dye-filled optical microcavity, which acts as a "white-wall" photon box. The cavity mirrors provide a trapping potential and a non-vanishing effective photon mass, making the system formally equivalent to a two-dimensional gas of trapped massive bosons. Thermalization of the photon gas is reached in a number conserving way by multiple scattering off the dye molecules. Signatures for a BEC upon increased photon density are: a spectral distribution that shows Bose-Einstein distributed photon energies with a macroscopically populated peak on top of a broad thermal wing, the observed threshold of the phase transition showing the predicted absolute value and scaling with resonator geometry, and condensation appearing at the trap centre even for a spatially displaced pump spot.
A system of identical bosons can exhibit a state of matter in which the ground state is macroscopically occupied. This special state is called Bose-Einstein condensation, and was predicted by Satyendra Nath Bose and Albert Einstein in 1924. It took some time before physicists achieved this experimentally, but in 1995 it was done by Eric Cornell and Carl Wieman. Since photons are also bosonic particles, they should be able to achieve Bose-Einstein condensation in thermal equilibrium. However this is not as easy for photons as it is for atoms, since the number of photons depends on the temperature. But in 2010 the group of Martin Weitz in Bonn was able to produce a photon Bose-Einstein condensate. This was done using a dye-filled microcavity which is optically pumped. The same principles are used in our setup. Photons inside the cavity thermalize with a fluorescent dye through multiple absorption and emission cycles. The effectively two-dimensional photon gas is trapped by a harmonic potential induced by the shape of the cavity mirrors. This results in photons with eigenenergies of the quantum harmonic oscillator. The minimal energy is determined by the cutoff frequency, set by the cavity length. The thermalization of the photon gas depends on this cutoff frequency, and the total pump power. Jonathan Keeling and Peter Kirton developed a theoretical model describing this system and its thermalization, and simulated it in one dimension.\nWe simulate the same model, in two dimensions using radially averaged photon modes. Threshold for Bose-Einstein condensation is determined for different cutoff frequencies. Our results show good agreement with those of Keeling and Kirton, below, at and above threshold. Multimode condensation and gain clamping of the molecular excitation density are observed above threshold. Comparison with experimental data can only be done qualitatively since it currently is uncalibrated.
The experimental realization of a Bose-Einstein condensate of photons, first achieved in 2010 at Bonn University, allowed for new ways to probe the properties of condensates. For thermal light in free space the chemical potential is zero and condensation is not possible. By confining light to a microcavity, the transverse degrees of freedom behave as massive bosons which can have nonzero chemical potential. The gas of thermal photons can be brought to thermalize with a fluorescent dye though absorption and emission cycles. By pumping the dye molecules with a laser, the chemical potential can be increased and the photons will condense. \nWe have built a setup with which we can spatially and spectrally resolve the photon distribution in such a dye-filled microcavity. This allows us to study the shape and occupation of the low energy transverse modes of the cavity. We use this to investigate the thermalization process of the photon gas. A rate equation model is presented and qualitatively compared to experimental data. We find that the photon gas is not in thermal equilibrium.\nWe also investigate effective photon-photon interactions by measuring the spatial extent of the condensate. We find an effective interaction in the form of thermal lensing. As the thermal lensing depends on the interaction between the photon gas and the dye, we find that the model used for thermalization can also make good predictions about effective photon-photon interactions.